Monitoring of frying oil quality using combined optical interrogation methods and devices

• US 8,257,976 B2
• Filed: 03/02/2009
• Issued: 09/04/2012
• Est. Priority Date: 03/04/2008
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Wei, Ai-Ping, Sabade, Milind Balwant, Mahmoodi, Abolghassem B.
• Primary Examiner(s): Alexander, Lyle
• Assistant Examiner(s): Gerido, Dwan A
• Application Number:
  US12/920,514
• Publication Number:
  US 20110059532A1
• Time in Patent Office: 1,282 Days
• Field of Search: 436/61, 436/60, 422/69, 422/68.1, 422/420, 422/82.05
• US Class Current: 436/61
• CPC Class Codes: G01N 21/643 non-biological material
• CPC Class Codes: G01N 21/78 producing a change of colour
• CPC Class Codes: G01N 31/22 using chemical indicators G01N31/02 takes precedence
• CPC Class Codes: G01N 33/03 Edible oils or edible fats

Abstract

Herein are disclosed methods and devices for optically monitoring multiple parameters of an oil sample. In one embodiment, the methods and devices can be used for determining the quality of cooking or flying oil in terms of the free fatty acid content and total polar compound content of the oil. The methods use an optical absorbtive/reflective property in evaluating the free fatty acid content, and use optical fluorescence in evaluating the total polar compound content, with both measurements using a single sampling substrate and a single measuring device.

Claims

1. A method of optically monitoring multiple parameters of an oil sample, the method comprising the steps of:

providing an oil-absorbent sampling substrate;

wherein the sampling substrate contains a plurality of first test zones comprising a first optical property that is responsive to a first parameter of the oil, and at least one second test zone comprising a second optical property that is responsive to a second parameter of the oil;

contacting the oil with the sampling substrate such that a sample of the oil is brought into contact with at least a portion of each of the first test zones and at least a portion of the at least one second test zone;

interrogating the first test zones by a first optical method so as to receive a set of first signals from the first test zones;

combining the set of first signals from the first test zones into a combined signal;

correlating the combined signal with the first parameter of the oil;

interrogating the at least one second test zone by a second optical method so as to receive a second signal,

wherein the second optical method is different from the first optical method; and

,

correlating the second signal with the second parameter of the oil.

2. The method of claim 1 wherein combining the set of first signals comprises summing the first signals together into an integrated signal.

3. The method of claim 1 wherein the interrogating of the first test zones and the interrogating of the at least one second test zone are performed by the same interrogation device.

4. The method of claim 1 wherein the interrogating of the first test zones is performed by the use of a separate light source/photodetector pair for each of the first test zones.

5. The method of claim 1, wherein the first parameter comprises the free fatty acid content of the oil, wherein the second parameter comprises the total polar compound content of the oil, and wherein the method further comprises the step of reporting an indication of the oil quality of the oil, wherein the indication is associated with the free fatty acid content of the oil and with the total polar compound content of the oil.

6. The method of claim 1 wherein the interrogating of the first test zones comprises measurement of reflectance.

7. The method of claim 6 wherein the first test zones each comprise an indicator whose optical absorbtive/reflective properties are responsive to the first parameter of the oil.

8. The method of claim 7 wherein the indicator is an acid-base indicator.

9. The method of claim 1 wherein the first parameter comprises the free fatty acid content of the oil.

10. The method of claim 9, wherein the method includes the additional step of reporting an indication of the oil quality of the oil, wherein the indication is associated with the free fatty acid content of the oil.

11. The method of claim 1 wherein the second parameter comprises the total polar compound content of the oil.

12. The method of claim 11, wherein the method includes the additional step of reporting an indication of the oil quality of the oil, wherein the indication is associated with the total polar compound content of the oil.

13. The method of claim 1 wherein the interrogating of the at least one second test zone comprises measurement of fluorescence.

14. The method of claim 13 wherein the measurement of fluorescence comprises measurement of autofluorescence.

15. The method of claim 14 wherein the oil sample does not comprise a fluorescent indicator additive.

16. A system for measuring at least two parameters of an oil sample;

the system comprising;

an oil-absorbent sampling substrate,

wherein the sampling substrate contains a plurality of first test zones comprising a first optical property that is responsive to a first parameter of the oil, and at least one second test zone comprising a second optical property that is responsive to a second parameter of the oil; and

,

an optical interrogation device,

wherein the device comprises means to interrogate each of the first test zones of the sampling substrate by a first optical mechanism and receive a set of first signals therefrom, and to means to interrogate the at least one second test zone of the sampling substrate by a second, different optical mechanism and receive a second signal therefrom,

wherein the device further comprises means to combine the set of first signals from the first test zones into a combined signal, and means to correlate the combined signal with the first parameter of the oil; and

,

wherein the device further comprises means to correlate the second signal with the second parameter of the liquid sample.

17. The system of claim 16 wherein the first parameter is the free fatty acid content of the oil and the second parameter is the total polar compound content of the oil.

18. The system of claim 17 wherein the device is configured to report a first indication of the oil quality of the oil, wherein the first indication is associated with the free fatty acid content of the oil;

and, wherein the device is also configured to report a second indication of the oil quality of the oil, wherein the second indication is associated with total polar compound content of the oil.

19. The system of claim 17 wherein the device is further configured to report an indication of the oil quality of the oil, wherein the indication is associated with the free fatty acid content of the oil and with the total polar compound content of the oil.

20. The system of claim 17 wherein the first optical mechanism is reflectance and the second optical mechanism is fluorescence.

21. The system of claim 20 wherein the device comprises a separate lig source/photodetector pair for the interrogation of each first test zone of the plurality of first test zones, and wherein the device comprises an additional light source/photodetector pair for the interrogation of the at least one second test zone.

22. The system of claim 21 wherein the device is configured such that the plurality of first test zones, and the at least one second test zone, can be all interrogated without moving the sampling substrate and the interrogation device relative to each other.

23. The system of claim 22 wherein the device is at least one of a hand-held device, a portable device, or a countertop device.