Controlled-transparency electrochromic device

• US 8,289,609 B2
• Filed: 04/15/2010
• Issued: 10/16/2012
• Est. Priority Date: 04/16/2009
• Status: Active Grant

• Current Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Inventors: Lamine, Driss, Valentin, Emmanuel, Dubrenat, Samuel
• Primary Examiner(s): Martinez, Joseph P
• Application Number:
  US12/922,351
• Publication Number:
  US 20110043885A1
• Time in Patent Office: 915 Days
• Field of Search: 359265-275
• US Class Current: 359/266
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10376 Laminated safety glass or glazing containing metal wires
• CPC Class Codes: B32B 17/10513 Electrochromic layer
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/1077 containing polyurethane
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: Y10T 29/49169 Assembling electrical component directly to terminal or elongated conductor

Abstract

The present invention relates to an electrochromic device comprising:

• • at least one partition (12) that separates the surface of the upper electrode (9) into two regions isolated from each other, namely a free region (9a) and an active region;
  • at least one partition (5) that separates the surface of the lower electrode (4) into two regions electrically isolated from each other, namely a free region (4a) and an active region (4b);
  • at least one free region (9a) of the upper electrode (9) receives a first current-supply connector (15) soldered to the active zone (4b) of the lower electrode (4); and
  • the active area (9b) of the upper electrode (9) is in electrical contact with the connection means (20, 21a) connected to a second current-supply connector (21) electrically isolated from the free zone (9a) connected to the lower electrode (4).

Claims

1. An electrochromic device having controlled transmission or reflection of at least one electrically controllable active area (CDEF), comprising, on a carrier substrate, a multilayer stack comprising at least, in succession:

a layer forming a lower electrically conductive electrode;

various functional layers, at least one of which is an electrochromic layer; and

a layer forming an upper electrically conductive electrode, in which device;

at least one selective partition passes through the upper electrode and the various layers separating the upper electrode from the lower electrode without passing through the lower electrode, the at least one selective partition dividing at least one surface of the upper electrode into two regions electrically isolated from each other, namely a free region and an active region containing the active area (CDEF);

at least one total partition passes through the upper electrode and the various layers separating the upper electrode from the substrate, the at least one total partition dividing at least one surface of the lower electrode into two regions electrically isolated from each other, namely a free region and an active region containing the active area (CDEF);

at least one free region of the upper electrode receives a first current-supply connector soldered to the active region of the lower electrode; and

the active region of the upper electrode is in electrical contact with a connection unit connected to a second current-supply connector, which is electrically isolated from the free region connected to the lower electrode.

2. The device as claimed in claim 1, wherein the total partition divides the surface of the upper electrode into two regions, namely a second free region and an active region containing the active area (CDEF), the second current-supply connector being placed into the second free region of the upper electrode.

3. The device as claimed in claim 1, wherein the connection unit comprises an array of fine electrically conducting parallel wires.

4. The device as claimed in claim 1, wherein transparent insulating bands are placed between the free regions of the upper electrode and the second current-supply connectors between which connectors the wires are placed.

5. The device as claimed in claim 1, wherein the connection unit comprises a metal frame, placed on the periphery of the active region.

6. The device as claimed in claim 1, wherein the connection unit is supported by a transparent support.

7. The device as claimed in claim 6, wherein the support comprises a lamination interlayer.

8. The electrochromic device as claimed in claim 1, wherein the current-supply connector soldered to the lower electrode is placed onto several free regions of the upper electrode, and an electrical isolation element is provided between said second current-supply connector and the surface of the upper electrode.

9. The electrochromic device as claimed in claim 8, wherein the isolation element is a thin electrically insulating sheet.

10. The device as claimed in claim 1, wherein the carrier substrate comprises a glazing and, optionally, is made of glass or plastic.

11. The device as claimed in claim 1, wherein the solder joint between the current-supply connector and the lower electrode is ultrasonically soldered.

12. The device as claimed in claim 11, wherein the current-supply connector is placed onto the entire periphery of the upper electrode.

13. The device as claimed in claim 1, wherein at least one of the electrodes comprises at least one indium tin oxide (ITO) layer.

14. The device as claimed in claim 1, wherein the free regions, defined by the total partitions and the selective partitions, are located on the periphery of said device.

15. The device as claimed in claim 14, wherein the substrate is rectangular shaped and in that the selective partitions and the total partitions are respectively produced so as to be parallel with opposed sides of the substrate.

16. The device as claimed in claim 1, wherein the total partitions and the selective partitions are respectively perpendicular.

17. An electrochromic glazing, comprising the device as claimed in claim 1.

18. An architectural, automotive, mirror, display, signage, or camera shutter glazing comprising the glazing as claimed in claim 17.

19. A process for fabricating an electrochromic device having controlled transmission or reflection of at least one electrically controllable active area, comprising, on a carrier substrate, a multilayer stack comprising at least, in succession;

an electrically conductive layer forming a lower electrode;

various functional layers at least one of which is an electrochromic layer; and

an electrically conductive layer forming an upper electrode, the process comprising;

(A) depositing in succession, onto at least part of the surface of the substrate, the electrically conductive layer forming the lower electrode, the various functional layers and the electrically conductive layer forming the upper electrode;

(B) producing, starting from the upper electrode, at least one selective partition that passes through the upper electrode as well as the other layers separating the upper electrode from the lower electrode without passing through the latter, each selective partition dividing at least the surface of the upper electrode into two regions electrically isolated from each other, namely a free region and an active region containing the active area (CDEF);

(C) producing, starting from the upper electrode, at least one total partition that passes through the upper electrode as well as the layers which separate the upper electrode from the substrate, each total partition dividing at least the surface of the lower electrode into two regions electrically isolated from one another, namely a free region and an active region;

(D) soldering a current-supply connector to the free region of the upper electrode and to the active region of the lower electrode located in line with the latter; and

(E) placing at least one connection unit, which is electrically connected to a current-supply connector, in electrical contact with the active region of the upper electrode.

20. The process as claimed in claim 19, wherein said solder joint is ultrasonically soldered.

21. The process as claimed in claim 19, wherein at least one of the total and selective partitions is produced by a laser beam.

22. The process as claimed in claim 19, further comprising

producing several electrochromic devices having controlled transmission or reflection of at least one electrically controllable active area (CDEF), comprising, on a carrier substrate, a multilayer stack comprising at least, in succession:

a layer forming a lower electrically conductive electrode;

various functional layers, at least one of which is an electrochromic layer; and

a layer forming an upper electrically conductive electrode,

in which device;

at least one selective partition passes through the upper electrode and the various layers separating the upper electrode from the lower electrode without passing through the lower electrode, the at least one selective partition dividing at least the surface of the upper electrode into two regions electrically isolated from each other, namely a free region and an active region containing the active area (CDEF);

at least one total partition passes through the upper electrode and the various layers separating the upper electrode from the substrate, the at least one total partition dividing at least the surface of the lower electrode into two regions electrically isolated from each other, namely a free region and an active region containing the active area (CDEF);

at least one free region of the upper electrode receives a first current-supply connector soldered to the active region of the lower electrode; and

the active region of the upper electrode is in electrical contact with a connection unit connected to a second current-supply connector, which is electrically isolated from the free region connected to the lower electrode,

on the same carrier substrate, and, once said devices are completed, cutting the carrier substrate and all the layers deposited thereon so as to constitute specific devices.