Apparatus, system, and method for generating a gas from solid reactant pouches

• US 8,357,214 B2
• Filed: 06/08/2009
• Issued: 01/22/2013
• Est. Priority Date: 04/26/2007
• Status: Expired due to Fees

• Current Assignee: Molly Alonso
• Original Assignee: Trulife Incorporated (Trulife)
• Inventors: Patton, John Madison, Anderson, Howard
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US12/480,099
• Publication Number:
  US 20090304558A1
• Time in Patent Office: 1,324 Days
• Field of Search: 48/61, 481/20, 481/74, 422/239, 422/211, 422/234, 422/236, 422/625, 422/626, 422/630
• US Class Current: 48/61
• CPC Class Codes: B01J 2208/00106 by indirect heat exchange
• CPC Class Codes: B01J 2208/00371 gaseous
• CPC Class Codes: B01J 2208/00752 Feeding
• CPC Class Codes: B01J 2208/00761 Discharging
• CPC Class Codes: B01J 2208/00814 the particulate material being provides in prefilled containers
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 2203/066 with fuel cells
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: H01M 8/04201 Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An apparatus, system, and method are disclosed for generating a gas. One or more liquid permeable pouches each define a cavity that contains a solid anhydrous reactant, such as a chemical hydride. A reaction chamber made of a heat, chemical and/or pressure resistant material receives the one or more pouches from a pouch feeder that transfers the one or more pouches into the reaction chamber successively at a feed rate. One or more liquid sources inject a liquid reactant into the reaction chamber so that the liquid reactant contacts a portion of the one or more pouches. The one or more liquid sources inject the liquid reactant at an injection rate that corresponds to the feed rate. A gas outlet releases a gas, such as hydrogen, oxygen, ammonia, borazine, nitrogen, or a hydrocarbon, that is produced by a reaction between the solid reactant and the liquid reactant.

Claims

1. An apparatus to generate a gas, the apparatus comprising:

one or more liquid permeable pouches, each of the pouches defining a cavity comprising a solid anhydrous reactant;

a reaction chamber comprising a heat and pressure resistant material, the reaction chamber configured to receive the one or more pouches and a liquid reactant;

one or more reactant inlets configured to join the liquid reactant and the one or more pouches such that the liquid reactant contacts at least a portion of the one or more pouches; and

a gas outlet configured to release gas produced by a reaction comprising the solid anhydrous reactant and the liquid reactant.

2. The apparatus of claim 1, wherein the one or more reactant inlets comprise one or more liquid sources configured to inject the liquid reactant into the reaction chamber such that the liquid reactant contacts at least a portion of the one or more pouches, the one or more liquid sources injecting the liquid reactant at an injection rate.

3. The apparatus of claim 2, wherein the one or more reactant inlets transfer the one or more pouches into the reaction chamber successively at a feed rate corresponding to the injection rate.

4. The apparatus of claim 1, wherein the one or more liquid permeable pouches comprise a heat diffusion layer disposed adjacent to the solid anhydrous reactant such that the heat diffusion layer transfers heat from the solid anhydrous reactant.

5. The apparatus of claim 1, wherein the liquid reactant comprises a liquid selected from the group consisting of water, alcohols, and peroxides.

6. The apparatus of claim 1, wherein the produced gas comprises hydrogen and the solid anhydrous reactant comprises a chemical hydride and an anhydrous activating agent.

7. The apparatus of claim 1, wherein the produced gas comprises oxygen and the solid anhydrous reactant is selected from the group consisting of chlorates, perchlorates, superoxides, and ozonides.

8. The apparatus of claim 1, wherein the produced gas is selected from the group comprising ammonia, borazine, nitrogen, and hydrocarbons.

9. An apparatus to generate a gas, the apparatus comprising:

one or more liquid permeable pouches, each of the pouches defining a cavity comprising a solid anhydrous reactant;

a reaction chamber comprising a heat and pressure resistant material, the reaction chamber configured to receive the one or more pouches and a liquid reactant;

a pouch feeder configured to transfer the one or more pouches into the reaction chamber successively at a feed rate;

one or more liquid sources configured to inject the liquid reactant into the reaction chamber such that the liquid reactant contacts at least a portion of the one or more pouches, the one or more liquid sources injecting the liquid reactant at an injection rate corresponding to the feed rate; and

a gas outlet configured to release a gas produced by a reaction comprising the solid anhydrous reactant and the liquid reactant.

10. The apparatus of claim 9, wherein the transfer of the one or more pouches by the pouch feeder and the injection of the liquid reactant by the one or more liquid sources are both initiated by a single actuator.

11. The apparatus of claim 9, wherein the transfer of the one or more pouches by the pouch feeder and the injection of the liquid reactant by the one or more liquid sources are independently initiated.

12. The apparatus of claim 9, wherein the pouch feeder comprises one or more rollers, wherein at least one of the rollers is configured to press excess liquid from the one or more pouches in response to a substantial completion of the reaction in at least a portion of the one or more pouches.

13. The apparatus of claim 9, wherein the one or more pouches further comprise a protective covering and further wherein the pouch feeder is configured to puncture the protective covering.

14. The apparatus of claim 13, wherein the one or more liquid sources are configured to inject the liquid reactant into the protective covering through the pouch feeder and the protective covering comprises a water impermeable high temperature thin film plastic.

15. The apparatus of claim 9, wherein the one or more pouches are foldably coupled to each other in series.

16. The apparatus of claim 9, wherein the one or more pouches are independent of each other and the pouch feeder is configured to load each of the pouches separately.

17. The apparatus of claim 9, wherein the one or more pouches further comprise one or more alignment structures and the pouch feeder is configured to receive the one or more alignment structures.

18. The apparatus of claim 9, wherein the reaction chamber is removable.

19. A system to generate hydrogen, the system comprising:

a pouch source configured to store an unused portion of one or more liquid permeable pouches, each of the pouches defining a cavity comprising a solid anhydrous chemical hydride;

a reaction chamber comprising a heat and pressure resistant material, the reaction chamber configured to receive the one or more pouches and a liquid reactant;

a pouch feeder configured to transfer the one or more pouches from the pouch source into the reaction chamber successively at a feed rate;

one or more liquid sources configured to inject the liquid reactant into the reaction chamber such that the liquid reactant contacts at least a portion of the one or more pouches, the one or more liquid sources injecting the liquid reactant at an injection rate corresponding to the feed rate;

a hydrogen outlet configured to release hydrogen gas produced by a reaction comprising the solid anhydrous chemical hydride and the liquid reactant; and

a used pouch storage configured to receive a used portion of the one or more pouches from the reaction chamber.

20. The system of claim 19, further comprising a second reaction chamber configured to receive a portion of the one or more pouches from the pouch feeder and a portion of the liquid from the one or more liquid sources.

21. The system of claim 19, wherein the pouch source and the used pouch storage occupy a single chamber.

22. The system of claim 19, further comprising a cooling system disposed in substantially direct contact with the reaction chamber, the cooling system comprising a heat-sink and a fan.

23. The system of claim 19, further comprising a hydrogen filtration module configured to remove contaminants from the hydrogen gas, to remove liquids from the hydrogen gas, and to send the liquids to the one or more liquid sources, wherein the hydrogen filtration module is removable and replaceable.