Structure and method for creating surface texture of compliant coatings on piezo ink jet imaging drums

• US 8,377,316 B2
• Filed: 04/30/2009
• Issued: 02/19/2013
• Est. Priority Date: 04/30/2009
• Status: Active Grant

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Pan, David H., Freeman, T. Edwin
• Primary Examiner(s): OLSEN, ALLAN W
• Application Number:
  US12/432,868
• Publication Number:
  US 20100279078A1
• Time in Patent Office: 1,391 Days
• Field of Search: None
• US Class Current: 216/8
• CPC Class Codes: C09D 5/28 for wrinkle, crackle, orange-peel, or similar decorative effects
• CPC Class Codes: G03F 7/0046 with perfluoro compounds, e.g. for dry lithography G03F7/0048 takes precedence
• CPC Class Codes: G03F 7/0233 characterised by the polymeric binders or the macromolecular additives other than the macromolecular quinonediazides
• CPC Class Codes: G03F 7/0236 Condensation products of carbonyl compounds and phenolic compounds, e.g. novolak resins
• CPC Class Codes: G03F 7/0752 in non photosensitive layers or as additives, e.g. for dry lithography
• CPC Class Codes: G03F 7/11 having cover layers or intermediate layers, e.g. subbing layers G03F7/091 - G03F7/093, B41N3/03 take precedence
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

This is structure and method for providing a textured surfaced that can be used in a plurality of systems including ink jet printing. In ink jet printing, the textured surface of this invention controls ink drawback and significantly improves image quality. The textured surface has an average roughness, R_a, of about 0.2 to 1.5 microns, a texture density of about 10⁴-10⁷ pits per cm², a texture size of about 0.5-5 microns, and a texture depth of about 0.5-10 microns.

Claims

1. A method of producing an imaging surface for an imaging system useful for inkjet printing, comprising:

providing a metallic substrate, the imaging surface comprising the metallic substrate;

coating said metallic substrate with an elastomer layer having a chemically-reactive filler or base mixed therewith;

etching said coating with an effective concentration of an acid reactive with the filler or base exposed at the surface of the coating, thereby providing reaction products including water-soluble salt at the surface of the coating; and

forming pits in the coating surface by washing the surface with an aqueous liquid to remove said reaction products, thereby producing a elastomer coated aluminum drum having a textured surface with an average roughness, Ra, of from about 0.2 to about 1.5 microns, a texture density of about 10⁴ to about 10⁷ pits per cm², each such pit having an opening of from about 0.5 to about 5 microns, and a depth of from about 0.5 to about 10 microns.

2. The method of claim 1 wherein the metallic substrate is a rigid material selected from the group consisting of aluminum, anodized aluminum, iron phosphate, nickel, copper, zinc, stainless steel, and combinations and mixtures thereof.

3. The method of claim 1 wherein said elastomer is selected from the group consisting of a fluorelastomer, poly (tetrafluorethlylene), silicone rubber, nitrile butyl rubber, polyurethane elastomer, and combinations and mixtures thereof.

4. The method of claim 1 wherein said base is selected from the group consisting of MgO, Ca(OH)₂, CaCO₃, K₂CO₃, and combinations and mixtures thereof.

5. The method of claim 1 wherein said acid is selected from the group consisting of acetic acid, phosphoric acid, hydrochloric acid, sulfuric acid, nitric acid, and combinations and mixtures thereof.

6. The method of claim 1 wherein said acid is acetic acid.

7. The method of claim 1 wherein an aluminum drum is provided as said metallic substrate,

said coating step comprising coating said drum with a mixture comprising a fluoroelastomer and a base filler, the base filler comprising a material selected from the group consisting of MgO, Ca(OH)₂, and CaCO₃ and mixtures thereof;

said etching comprising etching said coating with acetic acid to form thereby a water soluble salt of said MgO, Ca(OH)₂, or CaCO₃; and

removing said salt by washing the coating surface with water.

8. A fusing surface structure of an elastomeric coating on an imaging surface comprising a metallic substrate that is configured to receive an application of a thin film of a release fluid, said surface being a pitted surface comprising the following characteristics:

an average roughness, R_a, of from about 0.2 to about 1.5 microns;

a texture density of from about 10⁴ to about 10⁷ pits per cm²;

each said pit having an opening of a size from about 0.5 to about 5 microns, and a depth of from about 0.5 to about 10 microns.