Highly electrically conductive transparent layer with a metal grid having optimized electrochemical resistance

• US 8,411,348 B2
• Filed: 10/22/2007
• Issued: 04/02/2013
• Est. Priority Date: 11/03/2006
• Status: Active Grant

• Current Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Inventors: Valentin, Emmanuel, Dubrenat, Samuel, Jousse, Didier, Kim, Se-Jong, Steers, Emilie, Giron, Jean-Christophe, Letocart, Philippe
• Primary Examiner(s): Lester, Evelyn A.
• Application Number:
  US12/513,178
• Publication Number:
  US 20100132988A1
• Time in Patent Office: 1,989 Days
• Field of Search: 359265-275
• US Class Current: 359/266
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/1077 containing polyurethane
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 2001/1536 additional, e.g. protective, layer inside the cell
• CPC Class Codes: Y10T 29/49124 On flat or curved insulated base, e.g., printed circuit, etc.

Abstract

An electroconductive layer (2) designed to be combined with a substrate having a glass function, said layer (2) being composed of a metal grid (9), characterized in that the metal grid (9) consists of a pure metal and in that it is coated with at least one electrochemical protection layer (10), especially a metal layer or a metal nitride layer.

Claims

1. An electrochemical/electrically controllable device having variable optical and/or energy properties comprising at least one carrier substrate, at least one electroactive layer, at least one lower electrode, and at least one upper electrode, wherein the at least one electroactive layer is between the lower electrode and the upper electrode, wherein the lower electrode and/or the upper electrodes comprises at least one electroconductive layer comprising a metal grid that consists of a pure metal which is coated with at least one electrochemical protection layer, wherein the electrochemical protection layer is based on a material selected from group consisting of titanium, gold, platinum and palladium, said material optionally being nitrided, the electrochemical protection layer being combined with at least one barrier layer based on a metal oxide, wherein the metal oxide is selected from the group consisting of zinc oxide, zinc oxide doped with another metal selected from the family of the following metals:

Al, Ga, B, and Sc, tin-doped indium oxide and antimony-doped tin oxide.

2. The electrochemical/electrically controllable device as claimed in claim 1, wherein the pure material is selected from the group consisting of silver, copper, zinc, aluminum, nickel, chromium and a nickel-chromium alloy.

3. The electrochemical/electrically controllable device as claimed in claim 1, wherein the thickness of the grid ranges from 1 to 15 μ

m.

4. The electrochemical/electrically controllable device as claimed in claim 1, wherein the grid has a periodic or aperiodic structure representing a light occultation of 15 to 25%.

5. The electrochemical/electrically controllable device as claimed in claim 1, wherein the thickness of the electrochemical protection layer ranges from 10 to 100 nm.

6. The electrochemical/electrically controllable device as claimed in claim 5, wherein the thickness of the electrochemical protection layer ranges from 25 to 75 nm.

7. The electrochemical/electrically controllable device as claimed in claim 1,wherein the thickness of the barrier layer ranges from 40 to 400 nm.

8. The electrochemical/electrically controllable device as claimed in claim 7, wherein the thickness of the barrier layer ranges from 60 to 300 nm.

9. The electrochemical/electrically controllable device as claimed in claim 1, wherein the grid is deposited on a second barrier layer.

10. The electrochemical/electrically controllable device as claimed in claim 1, wherein the resistivity of the electroconductive layer ranges from 0.01 ohms/□

to 1 ohms/□

.

11. The electrochemical/electrically controllable device as claimed in claim 1,wherein the grid possesses electrical conductivity properties before and after heat treatment.

12. A method of making the device as claimed in claim 1, comprising:

placing the electroconductive layer as an electrode of an electrochemical/electrically controllable device having variable optical and/or energy properties, or as an active layer in an electrochemical and/or electrically controllable device having variable optical and/or energy properties.

13. A glazing, comprising the device as claimed in claim 1.

14. The glazing as claimed in claim 13, wherein the glazing is an architectural glazing, a panel for equipping internal partitions, windows or roofs of a transport vehicle, a display screen, a computer screen, a television screen, a projection screen, a touch-sensitive screen, a spectacle, a camera lens, a solar panel protector, or an illuminating surface.

15. The electrochemical/electrically controllable device as claimed in claim 1, wherein the thickness of the grid ranges from 2 and 8 μ

m.