Electrochromic display module and composition with improved performance

• US 8,432,601 B2
• Filed: 05/01/2009
• Issued: 04/30/2013
• Est. Priority Date: 05/01/2009
• Status: Expired due to Fees

• Current Assignee: S. A. Gemalto
• Original Assignee: Gemalto SA (Thales SA)
• Inventors: Webb, Steven Paul, Brestovansky, Dennis, Berry, Craig Richard, Kingery, John Russell
• Primary Examiner(s): Jones, James
• Application Number:
  US12/434,379
• Publication Number:
  US 20100277788A1
• Time in Patent Office: 1,460 Days
• Field of Search: 359/265, 359/267
• US Class Current: 359/265
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 1/161 Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 2001/164 the electrolyte is made of polymers

Abstract

An electrochromic display module employing a unique combination of architecture and electrochromic composition to provide an extended life to the module. The architecture may involve the use of an extended seal about a perimeter of a display portion where the composition is located. In this manner, the rate of solvent leakage from the composition may be substantially reduced. Additionally, the electrochromic composition itself may make use of particular low volatility solvents and constituent combinations so as to discourage the amount particle generation therein. Ultimately, an electrochromic display module having a useful life of more than about 3 years may be provided.

Claims

1. An electrochromic display device comprising an electrochromic composition, said composition comprising:

electro-active ink, a sulfone solvent, wherein at least about 50% of said solvent remains in the composition for a duration of at least about 3 years; and

particles generated in the composition, said particles remaining less than about 150 microns in size for a duration of at least about 3 years.

2. The electrochromic display device of claim 1 further comprising a pixel of a given modulation depth said pixel configured to retain more than about 40% of the given modulation depth for a duration of at least about 3 years.

16. The electrochromic display device of claim 1, wherein said solvent having a volatility of less than about 0.03 torr at about 20°

C.

3. An electrochromic display device comprising an electrochromic composition, said composition comprising:

a solvent having characteristics of a volatility of less than about 0.03 torr at about 20°

C. and at least about a 3 year maintainability of at least about 50% retention relative the composition, and particles generated in the composition having a characteristic of less than about 150 microns in size for a duration of at least about 3 years.

4. The electrochromic display device of claim 3 further comprising:

a display portion for accommodating said electrochromic composition at a surface of a backplane substrate of the device; and

a seal extending from a side of the display portion at a perimeter thereof to beyond about 0.12 inches across the backplane substrate for isolating said electrochromic composition thereat.

5. The electrochromic display device of claim 4 wherein said seal is disposed across a majority of the backplane substrate.

6. The electrochromic display device of claim 3 wherein the solvent is a sulfone.

7. The electrochromic display device of claim 3 wherein the solvent comprises at least about 25% of said electrochromic composition for a duration of at least about 3 years.

15. The electrochromic display device of claim 3 further comprising a pixel of a given modulation depth said pixel configured to retain more than about 40% of the given modulation depth for a duration of at least about 3 years.

8. An electrochromic composition for an electronic display, the composition comprising a substantially soluble polymer solubilized in an electrochemically stable solvent having a volatility of less than about 0.03 torr at about 20°

C. and wherein the solvent is sulfone.

9. The electrochromic composition of claim 8 wherein the solvent and solubilizable polymer are of a character allowing at least about 25 wt % of the polymer to remain dissolved in the solvent for a duration of at least about 24 hours at about room temperature.

10. The electrochromic composition of claim 8 wherein the sulfone is tetramethylene sulfone.

11. The electrochromic composition of claim 8 further comprising generated particles, a substantial majority thereof having a size of less than about 150 microns.

12. The electrochromic composition of claim 8 wherein the polymer is 100,000 molecular weight polyethylene oxide.

13. The electrochromic composition of claim 8 wherein said polymer comprises between about 10% and about 15% of the composition and said solvent comprises between about 30% and about 50% of the initial composition.

14. The electrochromic composition of claim 8 comprising less than about 0.5% fumed silica pouring agent.

17. An electrochromic display device comprising an electrochromic composition, said composition comprising:

electro-active ink,

a solvent,

a display portion for accommodating said electrochromic composition at a surface of a backplane substrate of the device, and

a seal extending from a side of the display portion at a perimeter thereof to beyond about 0.12 inches across the backplane substrate for isolating said electrochromic composition thereat.

18. The electrochromic display device of claim 17 wherein said solvent having characteristics of a volatility of less than about 0.03 torr at about 20°

C. and at least about a 3 year maintainability of at least about 50% retention relative the composition; and

further comprising

particles generated in the composition having a characteristic of at least about a 3 year size limitation of less than about 150 microns.