Method of producing coated textile, more particularly synthetic leathers

• US 8,449,944 B2
• Filed: 12/12/2007
• Issued: 05/28/2013
• Est. Priority Date: 12/22/2006
• Status: Expired due to Fees

• Current Assignee: BASF SE
• Original Assignee: BASF SE
• Inventors: Schuette, Markus, Malz, Hauke, Szarvas, Laszlo
• Primary Examiner(s): CAMERON, ERMA C
• Application Number:
  US12/520,129
• Publication Number:
  US 20090311929A1
• Time in Patent Office: 1,994 Days
• Field of Search: None
• US Class Current: 427/341
• CPC Class Codes: D06N 3/14 with polyurethanes
• CPC Class Codes: Y10T 442/20 Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Abstract

A process for the production of coated textiles, a textile substrate being coated or impregnated with a solution (I) comprising polyurethane, and the polyurethane then being precipitated in or on the textile substrate, wherein polyurethane dissolved in ionic liquid is used as solution (I).

Claims

1. A process for the production of coated textiles, wherein a textile substrate is coated or impregnated with a solution (I) comprising polyurethane, and thereafter, the polyurethane is precipitated in or on the textile substrate, wherein polyurethane dissolved in ionic liquid is solution (I).

2. The process according to claim 1, wherein the solution (I) is produced by preparing the polyurethane in the ionic liquid.

3. The process according to claim 1, wherein the solution (I) is produced by dissolving polyurethane in ionic liquids.

4. The process according to claim 1, wherein the solution (I) comprises thermoplastic polyurethane.

5. The process according to claim 1, wherein the polyurethane is formed by the reaction of (a) isocyanate with (b) compounds reactive toward isocyanates and having a molecular weight of from 500 g/mol to 10 000 g/mol and (c) chain extenders.

6. The process according to claim 5, wherein the polyurethane is a thermoplastic polyurethane.

7. The process according to claim 1, wherein the ionic liquid is at least one member selected from the group consisting of 1-ethyl-3-methylimidazolium methanesulfonate, 1-ethyl-2,3-dimethylimidazolium ethylsulfate, 1-ethyl-3-methylimidazolium diethylphosphate and 1-ethyl-3 methylimidazolium chloride.

8. The process according to claim 1, wherein the textile substrate is a woven fabric, knitted fabric or nonwoven based on natural or synthetic fibers.

9. The process according to claim 1, wherein the textile substrate is a nonwoven.

10. The process according to claim 1, wherein the polyurethane is precipitated in a bath comprising water.

11. A coated textile obtained by the process according to claim 1.

12. The coated textile according to claim 11, wherein the coated textile comprises ionic liquid.

13. The coated textile according to claim 11, wherein the coated textile is imitation leather.

14. The process according to claim 1, wherein the polyurethane is formed by the reaction of (a) isocyanate with (b) compounds reactive toward isocyanates and having a molecular weight of from 500 g/mol to 10 000 g/mol, (c) chain extenders, and in the presence of at least one of (d) a catalyst and (e) an assistant.

15. The process according to claim 1, wherein said solution (I) comprises said polyurethane and said ionic liquid in a weight ratio of 20:

1 to 1;

10.

16. The process according to claim 1, wherein said solution (I) comprises said polyurethane and said ionic liquid in a weight ratio of 4:

1 to 2;

1.

17. The process according to claim 1, wherein said ionic liquid has a melting point of −

50 to 150°

C.

18. The process according to claim 1, wherein said ionic liquid has a melting point of −

20 to 120°

C.

19. A process for the production of coated textiles, comprising coating a textile substrate with a solution (I), and thereafter

precipitating the polyurethane in the textile substrate, wherein

solution (I) comprises at least one polyurethane dissolved in the presence of at least one ionic liquid.

20. The process according to claim 19, further comprising forming solution (I) by reacting in the presence of at least one ionic liquid:

(a) at least one isocyanate;

(b) at least one compound reactive toward isocyanates and having a molecular weight of from 500 g/mol to 10 000 g/mol; and

(c) at least one chain extender.