Rearview mirror assemblies with anisotropic polymer laminates

• US 8,545,030 B2
• Filed: 07/01/2009
• Issued: 10/01/2013
• Est. Priority Date: 07/12/2004
• Status: Active Grant

• Current Assignee: Gentex Corporation
• Original Assignee: Gentex Corporation
• Inventors: Anderson, John S., Tonar, William L., Luten, Henry A., Neuman, George A., Dozeman, Gary J., Morgan, Tammy G.
• Primary Examiner(s): NGUYEN, THONG Q
• Application Number:
  US12/496,620
• Publication Number:
  US 20090296190A1
• Time in Patent Office: 1,553 Days
• Field of Search: 359603-607, 359265-267, 35948501-48603
• US Class Current: 359/604
• CPC Class Codes: B32B 2255/00 Coating on the layer surface
• CPC Class Codes: B32B 2307/41 Opaque
• CPC Class Codes: B32B 2307/416 Reflective
• CPC Class Codes: B32B 2307/42 Polarizing, birefringent, filtering
• CPC Class Codes: B32B 2307/704 Crystalline
• CPC Class Codes: B32B 2307/706 Anisotropic
• CPC Class Codes: B32B 2307/748 Releasability
• CPC Class Codes: B32B 2551/08 Mirrors
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 27/06 as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/283 comprising polysiloxanes
• CPC Class Codes: B32B 27/286 comprising polysulphones; polysulfides
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: G02B 27/28 : for polarising used in stereoscopes G02B30/25
• CPC Class Codes: G02B 5/3058 : comprising electrically conductive elements, e.g. wire grids, conductive particles
• CPC Class Codes: G02B 5/3083 : Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001
• CPC Class Codes: G02F 1/133509 : Filters, e.g. light shielding masks
• CPC Class Codes: G02F 1/133536 : Reflective polarizers G02F1/13362 takes precedence
• CPC Class Codes: G02F 1/133548 : Wire-grid polarisers
• CPC Class Codes: G02F 1/1339 : Gaskets; Spacers; Sealing of cells
• CPC Class Codes: G02F 1/13439 : characterised by their electrical, optical, physical properties; materials therefor; method of making
• CPC Class Codes: G02F 1/137 : characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
• CPC Class Codes: G02F 1/13756 : the liquid crystal selectively assuming a light-scattering state G02F1/1334, G02F1/13718 take precedence
• CPC Class Codes: G02F 1/155 : Electrodes
• CPC Class Codes: G02F 1/157 : Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 1/161 : Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 2201/44 : Arrangements combining different electro-active layers, e.g. electrochromic, liquid crystal or electroluminescent layers
• CPC Class Codes: Y10T 156/10 : Methods of surface bonding and/or assembly therefor

Abstract

Anisotropic film laminates for use in image-preserving reflectors such as rearview automotive mirror assemblies, and related methods of fabrication. A film may comprise an anisotropic layer such as a light-polarizing layer and other functional layers. The film having controlled water content is heated under omnidirectional pressure and vacuum to a temperature substantially equal to or above a lower limit of a glass-transition temperature range of the film so as to be laminated to a substrate. The laminate is configured as part of a mirror structure so as to increase contrast of light produced by a light source positioned behind the mirror structure and transmitted through the mirror structure towards a viewer. The mirror structure is devoid of any extended distortion and is characterized by SW and LW values less than 3, more preferably less than 2, and most preferably less than 1.

Claims

1. A variable reflectance mirror system having a front, for use in a rearview mirror assembly having a light source adapted to transmit light of a first polarization through the mirror system towards the front, the mirror system comprising:

a first substrate having a first electrode disposed on a surface thereof;

a second substrate having a second electrode disposed on a surface thereof, the first and second substrates placed in a spaced-apart relationship to define a gap therebetween;

an electro-optic medium deployed in the gap, the electro-optic medium characterized by transmittance changing in response to a voltage difference applied between the first and second electrodes;

a reflective polarizer including an anisotropic film, the reflective polarizer disposed between the second substrate and the light source such that

the light emitted by the light source passes through the reflective polarizer, and where the reflective polarizer is configured to reflect light of a second polarization, the second polarization being orthogonal with respect to the first polarization, and

an optical distortion, caused by a surface distortion representing said reflective polarizer, when measured from the front is characterized by one or more of

(a) curvature units of ONDULO phase-shifting deflectometry that quantify surface distortions and that do not exceed about 0.04, and

(b) an optical power value, measured in reflection, that does not exceed 1,000 millidiopters.

2. A mirror system according to claim 1, wherein

said optical distortion is characterized by one or more of (ai) said curvature units not exceeding 0.02, and (bi) said optical power value not exceeding 500 millidiopters.

3. A mirror system according to claim 1, wherein

said optical distortion is characterized by one or more of (ai) said curvature units not exceeding 0.01, and (bi) said optical power value not exceeding 250 millidiopters.

4. A mirror system according to claim 1, wherein the anisotropic film is birefringent.

5. A mirror system according to claim 1, wherein the anisotropic film is part of a laminate disposed within the mirror system.

6. A mirror system according to claim 1, further comprising a superstrate and wherein the anisotropic film is laminated between the second substrate and said superstrate.

7. A mirror system according to claim 6, wherein the mirror system includes an optical thin-film coating configured to increase an overall reflectance of the mirror system, the optical thin-film coating disposed on at least one of the second substrate and the superstrate.

8. A mirror system according to claim 6, wherein the superstrate is releasably adhered to the anisotropic film.

9. A mirror system according to claim 6, wherein the light source is adapted as said superstrate of the laminate.

10. A mirror system according to claim 6, further comprising an opacifying layer adjacent to a surface of one of the second substrate and superstrate, the opacifying layer substantially completely covering the surface outside of a transflective zone of the mirror system.

11. A mirror system according to claim 10, wherein the opacifying layer is characterized by a graded thickness.

12. A variable reflectance mirror system having a front, for use in a rearview mirror assembly having a light source transmitting light of a first polarization through the mirror system towards the front, the mirror system comprising:

an optical element having a proximal side and a distal side, said optical element configured to reflect ambient light incident upon the proximal side; and

a laminate including an anisotropic plastic film structure, the anisotropic plastic film structure adapted to substantially transmit light of the first polarization and substantially reflect light of a second polarization, the second polarization being orthogonal to the first polarization, the anisotropic plastic film structure configured between the distal side of the optical element and the light source to

enable the light emitted by the light source to pass through the laminate, and

realize a surface distortion of said mirror system that has a corresponding optical distortion which, when measured from the front,

is characterized by one or more of (a) curvature units, of ONDULO phase-shifting deflectometry, that quantify surface distortions and that do not exceed 0.04, and (b) an optical power value that quantifies surface distortions of the mirror system in reflection and that does not exceed 1,000 millidiopters.

13. A mirror system according to claim 12, wherein the optical element includes at least one of an electro-optic medium and an optical prism.

14. A mirror system according to claim 12, further comprising a superstrate such that the anisotropic film structure is laminated between the optical element and said superstrate.

15. A mirror system according to claim 14, wherein the light source is adapted as the superstrate of the laminate.

16. A mirror system according to claim 12, further comprising

a superstrate, and

an opaque reflectance-enhancement optical thin-film layer disposed adjacently to a surface of one of the optical element and the superstrate, said reflectance-enhancing layer substantially completely covering the surface outside of a transflective area of said mirror system such that a ratio of a first value to the second value exceeds 0.5,

wherein the first value represents an amount of light transmitted from the light source through the mirror system towards the front and the second value represents an amount of said ambient light reflected by said optical element.

17. A mirror system according to claim 16, wherein said optical distortion is characterized by one or more of (ai) said curvature units not exceeding 0.02, and (bi) said optical power value not exceeding 500 millidiopters.

18. A mirror system according to claim 12, further comprising one or more of an interior illumination assembly, a voice activated system, a trainable transceiver, a microphone, a compass system, a digital sound processing system, a highway toll booth interface, a telemetry system, a moisture sensor, a global positioning system, a vehicle vision system, a wireless communication interface, a camera, a transflective reflector, a navigation system, a turn signal, and an adaptive cruise control system.

19. A mirror system according to claim 12, wherein the laminate is a stand-alone element.

20. A mirror system according to claim 12, wherein the light source includes a display.

21. A mirror system according to claim 12, wherein the optical element includes a multi-zone reflector having transflective and opaque zones.

22. A mirror system according to claim 21, further comprising a superstrate and an opacifying layer disposed on a surface of one of the optical element and the superstrate substantially outside of a transflective zone of the multi-zone reflector, the opacifying layer characterized by a non-uniform thickness, the transflective zone transmitting light from the light source towards the front.

23. A mirror system according to claim 22, wherein said opacifying layer includes one or more of Cr, Al, Ag, Rh, Pd, Au, Ru, Stainless Steel, Pt, Ir, Mo, W, Ti, Cd, Co, Cu, Fe, Mg, Os, Sn, W, Zn, and alloys or combinations thereof.

24. An optical element for increasing a contrast of light generated by a light source and transmitted through a mirror system of an automotive rearview mirror assembly, the optical element comprising:

an optical substrate having a surface; and

a layered structure adhered to the surface, the layered structure including an anisotropic layer substantially transmitting light of a first polarization and substantially reflecting light of a second polarization that is orthogonal to the first polarization, the layered structure characterized by a range of glass transition temperatures,

an optical distortion of said optical element, corresponding to a surface distortion of said optical element and measured from the front, which optical distortion is characterized by one or more of (a) curvature units, of ONDULO phase-shifting deflectometry, that quantify surface distortions and that do not exceed 0.04, and (b) an optical power value that quantifies surface distortions of the mirror system in reflection and that does not exceed 1,000 millidiopters, and

wherein a contrast ratio, defined by light transmitted from said light source through the mirror system and ambient light reflected by said optical element, is greater than 1.

25. An optical element according to claim 24, wherein said contrast ratio is greater than 2.

26. An optical element according to claim 24, wherein said optical distortion is characterized by one or more of (ai) said curvature units not exceeding 0.02, and (bi) said optical power value not exceeding 500 millidiopters.

27. An optical element according to claim 24, wherein said optical distortion is characterized by one or more of (ai) said curvature units not exceeding about 0.01, and (bi) said optical power value not exceeding 250 millidiopters.

28. An optical element according to claim 24, further comprising at least one of a first layer and a second layer disposed adjacent the surface, the first layer configured to render the surface substantially opaque and the second layer configured to increase the reflectance of the optical element.

29. An optical element according to claim 24, wherein a magnitude of color, measured in reflectance of light incident from CIE standard D65 illuminant onto said optical element, does not exceed 15.