Fluid bed direct contact steam generator system and process

• US 8,551,200 B2
• Filed: 08/28/2009
• Issued: 10/08/2013
• Est. Priority Date: 08/28/2008
• Status: Expired due to Fees

• Current Assignee: Ex-Tar Technologies Inc.
• Original Assignee: Ex-Tar Technologies Inc.
• Inventors: Betzer Tsilevich, Maoz
• Primary Examiner(s): MERKLING, MATTHEW J
• Application Number:
  US12/549,702
• Publication Number:
  US 20100050517A1
• Time in Patent Office: 1,502 Days
• Field of Search: 48/61, 481/279, 481/271, 481/97.R, 481/983, 48/76, 48/77, 48/78, 48/63, 48/64, 482/03, 482/10, 482/12, 482/15, 60 3953- 3955, 60 39461- 39465, 607/75
• US Class Current: 48/197.R
• CPC Class Codes: F22B 1/1853 coming in direct contact with water in bulk or in sprays
• CPC Class Codes: F22B 31/0007 with combustion in a fluidized bed fluidized bed apparatus per se B01J8/00; fluidized bed combustors F23C10/00
• CPC Class Codes: F23G 2202/30 in a pressurised chamber
• CPC Class Codes: F23G 7/008 for liquid waste waste oil F23G7/05, waste liquors F23G7/04, sludges F23G7/001
• CPC Class Codes: F23L 7/002 Supplying water
• CPC Class Codes: Y02E 20/34 Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Abstract

The present invention is a method and system for vertically producing a steam and combustion gas mixture, typically used in enhanced oil recovery processes. The system is a fluid bed up-flow combustor system, including a vertical vessel with fours sections. In a first section, fuel, oxidizer, and possibly water are supplied to the high pressure combustor at a combustion section of a vertical vessel. The combustion gas from the first section flows to a second section for steam generation, where low quality water is injected and turned into steam. Next, the third section is a homogenizer vessel, where any remaining water drops are converted to steam and solid particles and discharged from the vessel. The fourth section located at the bottom of the vessel is a fluid bed, receiving and processing the falling solids from the combustion and the steam generation sections.

Claims

1. A method for vertically producing a steam and combustion gas mixture, the method comprising:

mixing a carbon or hydrocarbon fuel and an oxidation gas containing oxygen;

combusting the mixture at a controllable pressure and temperature so as to convert the fuel to a flowing gas and solid byproducts, said solid byproducts being in a solid or a liquid form;

mixing liquid water into the flowing gas, said liquid water having suspended and dissolved solids and organics and being injected in an amount such that said liquid water is converted into steam while reducing the combustion gas temperature for generating produced gas;

converting liquids to gas and solids so as to generate steam and solid waste;

injecting a portion of said produced gas at a temperature lower than the combustion gas temperature through a fluid bed section below the combustion so as to increase the heat exchange duration and to cool combustion solid particles where the injected produced gas is injected below the combustion; and

discharging the produced steam, gas and solid mixture.

2. The method of claim 1, wherein said carbon or hydrocarbon fuel is selected from a group consisting of coal, pet-coke, asphaltin, vacuum residuals or untreated crude oil in a slurry form;

wherein said liquid water is selected from a group consisting of tailing pond water with levels of TSS, TDS and organics, brackish water, and sewage effluent water;

wherein said oxidation gas is selected from a group consisting of oxygen, oxygen-enriched air and air in stoichiometric ratio; and

wherein the produced gas injected through said fluid bed section is at a temperature range of between 150°

C. and 500°

C.

3. The method of claim 1, further comprising:

incorporating a heat exchanger to use up to 45% of generated combustion heat to generate a super-heated steam and gas mixture from the steam and gas mixture.

4. The method of claim 1, wherein a temperature of the steam and solid waste in the step of converting are between 150°

C. and 500°

C., the pressure being between 103 kpa and 10,000kpa.

5. The method of claim 1, wherein an up-flow velocity of the produced gas injected through said fluid bed section is in a range of between 0.2 m/s and 6 m/s.

6. The method of claim 1, further comprising:

flowing the discharged gas to a first cyclone solid separation so as to produce a lean gas flow, recycling the lean gas flow, and directing the lean gas flow back to the fluid bed section.

7. The method of claim 1, wherein the solid mixture is processed by a dry solids separation unit, the method further comprising the step of:

removing solids from the gas flow for disposal.

8. The method of claim 1, the method further comprising:

washing the gas by mixing the gas and steam with saturated water of a saturated temperature at the particular pressure so as to produce a saturated wet steam and combustion gas mixture, scrubbing any remaining solids from the gas, separating a liquid phase from the gas phase, and recycling water of the liquid phase with the scrubbed solids back to the fluid bed section.

9. The method of claim 7, further comprising:

adding limestone slurry to the liquid water in a vessel where the lime reacts with sulfur while generating a gypsum solid.

10. The method of claim 9, further comprising:

heating the steam and gas mixture in a heat exchanger with a gas phase from the step of combusting, the heated gas and steam mixture being solids-free and super-heated dry steam and gas mixture.

11. A method for producing a pressurized steam mixture for enhanced oil recovery comprising:

combusting a mixture of fuel and oxidation gas under controllable pressures and temperatures to generate combustion gases;

mixing the combustion gases with liquid having suspended solids in a vertical pressurized vessel to directly generate a mixture of combustion gas and steam from the liquid water;

evaporating the liquid water with the combustion gas mixture to leave the solids in a dry form and to reduce a temperature of the combustion gas;

recycling a portion of the generated combustion gas and steam mixture to a bottom of the vertical pressurized vessel to generate combustion gas steam fluid bed up-flow gas;

transferring the combustion gases to a dry-solid separator unit; and

removing dry solids from the dry-solid separator unit.

12. The method of claim 11, further comprising:

transferring the combustion gas mixture to a steam generation and wash vessel;

washing the combustion gas mixture in the steam generation and wash vessel with water at a saturated temperature and pressure; and

scrubbing any remaining solids from the combustion gas mixture to form a clean steam and gas mixture for injection into an underground formation for the enhanced oil recovery.

13. The method of claim 11, further comprising:

transferring the combustion gas mixture to a counter flow direct contact vessel;

mixing the combustion gas mixture with process water;

recovering heat from the combustion gas mixture and condensing steam to water while heating the liquid water to a temperature in the range of between 70°

C.- 90°

C. for an oil sand extraction facility for oil recovery.