Method for bonding a tantalum structure to a cobalt-alloy substrate

• US 8,608,049 B2
• Filed: 10/10/2007
• Issued: 12/17/2013
• Est. Priority Date: 10/10/2007
• Status: Active Grant

• Current Assignee: Zimmer Incorporated (Zimmer Biomet Holdings, Inc.)
• Original Assignee: Zimmer Incorporated (Zimmer Biomet Holdings, Inc.)
• Inventors: Hippensteel, Gregory M., Peek, Lawrence F., Anderson, Jeffrey P., Gorhe, Devendra, Allen, Steve M.
• Primary Examiner(s): D'Aniello, Nicholas P
• Application Number:
  US11/870,205
• Publication Number:
  US 20090098310A1
• Time in Patent Office: 2,260 Days
• Field of Search: 228/193, 228/194, 228/262.1, 228/262.71, 428/660, 428/613
• US Class Current: 228/194
• CPC Class Codes: A61F 2/30767 Special external or bone-contacting surface, e.g. coating for improving bone ingrowth
• CPC Class Codes: A61F 2002/3092 having an open-celled or open-pored structure
• CPC Class Codes: A61F 2002/30929 having at least two superposed coatings
• CPC Class Codes: A61F 2310/00029 Cobalt-based alloys, e.g. Co-Cr alloys or Vitallium
• CPC Class Codes: A61F 2310/00544 Coating made of tantalum or Ta-based alloys
• CPC Class Codes: B23K 20/02 by means of a press ; Diffusion bonding B23K20/001, B23K20/04 take precedence
• CPC Class Codes: B23K 20/16 with interposition of special material to facilitate connection of the parts, e.g. material for absorbing or producing gas
• CPC Class Codes: B23K 20/233 without ferrous layer
• CPC Class Codes: B23K 2103/08 Non-ferrous metals or alloys
• CPC Class Codes: B23K 2103/18 Dissimilar materials
• CPC Class Codes: B23K 2103/26 Alloys of Nickel and Cobalt and Chromium
• CPC Class Codes: Y10T 428/12479 Porous [e.g., foamed, spongy, cracked, etc.]
• CPC Class Codes: Y10T 428/12806 Refractory [Group IVB, VB, or VIB] metal-base component

Abstract

A method for bonding a porous tantalum structure to a substrate is provided. The method comprises providing a substrate comprising cobalt or a cobalt-chromium alloy; an interlayer consisting essentially of at least one of hafnium, manganese, niobium, palladium, zirconium, titanium, or alloys or combinations thereof; and a porous tantalum structure. Heat and pressure are applied to the substrate, the interlayer, and the porous tantalum structure to achieve solid-state diffusion between the substrate and the interlayer and between the interlayer and the porous tantalum structure.

Claims

1. A method for bonding a porous tantalum structure to a substrate, comprising:

providing a substrate comprising cobalt or a cobalt-chromium alloy;

providing a preformed solid sheet consisting essentially of a metal or a metal alloy, said metal or metal alloy including at least one of hafnium, manganese, niobium, palladium, zirconium, titanium, or alloys or combinations thereof, said preformed solid sheet having a top surface and a bottom surface;

providing a porous tantalum structure;

applying heat and pressure to the substrate and the preformed solid sheet for a time sufficient to achieve solid-state diffusion between the substrate and the bottom surface of the preformed solid sheet; and

applying heat and pressure to the preformed solid sheet and the porous tantalum structure for a time sufficient to achieve solid-state diffusion between the top surface of the preformed solid sheet and the porous tantalum structure, wherein the preformed solid sheet of metal defines an interlayer between the substrate and the porous tantalum structure,

wherein said applying heat and pressure to the substrate and the preformed solid sheet and said applying heat and pressure to the preformed solid sheet and the porous tantalum structure occur concurrently.

2. The method of claim 1, wherein said preformed solid sheet is press formed onto the substrate so as to conform to the substrate prior to said applying heat and pressure to the substrate and the preformed solid sheet.

11. The method of claim 1, further comprising conforming the preformed solid sheet to the substrate prior to applying said heat and pressure to the substrate and the preformed solid sheet.

12. The method of claim 1, wherein the e preformed solid sheet is pre-shaped to conform to the substrate.

13. The method of claim 1, wherein the preformed solid sheet is at least about 0.016 inches thick.

14. The method of claim 1, wherein the preformed solid sheet is at least about 0.020 inches thick.

15. The method of claim 1, wherein the preformed solid sheet is about 0.016 inches thick to about 0.020 inches thick.

19. The method of claim 1, wherein said applying heat and pressure to the preformed solid sheet and the porous tantalum structure includes applying a pressure that is at least 200 psi but less than the compressive yield strength of the porous tantalum structure.

3. A method for bonding a porous tantalum structure to a substrate, comprising:

providing a substrate comprising cobalt or a cobalt-chromium alloy;

providing a porous tantalum structure;

providing a preformed solid sheet having a top surface and a bottom surface, said preformed solid sheet consisting essentially of a metal or a metal alloy, said metal or metal alloy including at least one of hafnium, manganese, niobium, palladium, zirconium, titanium, or alloys or combinations thereof;

forming an assembly which includes positioning the preformed solid sheet between the substrate and the porous tantalum structure such that the bottom surface of the preformed solid sheet contacts the substrate and the top surface of the preformed solid sheet contacts the porous tantalum structure; and

applying heat and pressure to the assembly for a time sufficient to concurrently achieve solid-state diffusion between the substrate and the bottom surface of the preformed solid sheet and solid-state diffusion between the top surface of the preformed solid sheet and the porous tantalum structure.

4. The method of claim 3, wherein the preformed solid sheet conforms to the surface of the substrate prior to applying said heat and pressure.

5. The method of claim 3, wherein the preformed solid sheet is at least about 0.016 inches thick.

6. The method of claim 3, wherein said applying heat and pressure includes applying at least approximately 200 psi to the assembly.

7. The method of claim 3, wherein said applying heat and pressure includes applying a pressure that is less than a compressive yield strength of the porous tantalum structure.

8. The method of claim 3, wherein said applying heat and pressure includes heating to less than about 1000°

C. in a vacuum environment.

9. The method of claim 3, wherein the preformed solid sheet has a thickness of at least about 0.016 inches and said applying heat and pressure includes applying a pressure of at least about 200 psi and heating the assembly to at least about 540°

C. for at least one hour.

16. The method of claim 3, wherein the preformed solid sheet is pre-shaped to conform to the substrate.

18. The method of claim 3, wherein said preformed solid sheet is press formed onto the substrate so as to conform to the substrate prior to said applying heat and pressure to the assembly.

10. A method for bonding a porous tantalum structure to a substrate, comprising:

providing a substrate comprising cobalt or a cobalt-chromium alloy;

providing a preformed solid sheet having a top surface, a bottom surface and a thickness of at least about 0.016 inches, said preformed solid sheet consisting essentially of a metal or a metal alloy, the metal or metal alloy including at least one of hafnium, manganese, niobium, palladium, zirconium, titanium, or alloys or combinations thereof;

providing a porous tantalum structure;

forming an assembly which includes positioning the preformed solid sheet as an interlayer between said substrate and said porous tantalum structure, wherein the bottom surface of the preformed solid sheet contacts the substrate and the top surface of the preformed solid sheet contacts the porous tantalum structure;

applying a pressure of at least about 200 psi to the assembly; and

heating the assembly to at least about 540°

C. for at least one hour to concurrently achieve solid-state diffusion between the substrate and the preformed solid sheet and between the preformed solid sheet and the porous tantalum structure.

17. The method of claim 10, wherein said positioning includes conforming the preformed solid sheet to the substrate.