Electronic devices including transparent conductive coatings including carbon nanotubes and nanowire composites, and methods of making the same

• US 8,609,975 B2
• Filed: 09/06/2012
• Issued: 12/17/2013
• Est. Priority Date: 03/04/2010
• Status: Expired due to Fees

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Veerasamy, Vijayen S.
• Primary Examiner(s): Fang, Shane
• Application Number:
  US13/604,867
• Publication Number:
  US 20120327024A1
• Time in Patent Office: 467 Days
• Field of Search: 345/173, 345/174, 200/512, 977/953, 136/256
• US Class Current: 136/243
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: F25D 21/04 Preventing the formation of frost or condensate
• CPC Class Codes: F25D 29/00 Arrangement or mounting of control or safety devices
• CPC Class Codes: G06F 2203/04103 Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices
• CPC Class Codes: G06F 3/045 using resistive elements, e.g. a single continuous surface or two parallel surfaces put in contact
• CPC Class Codes: H01B 1/04 mainly consisting of carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01L 31/035227 the quantum structure being quantum wires, or nanorods carbon nanotubes H10K85/211
• CPC Class Codes: H05K 1/09 Use of materials for the conductive, e.g. metallic pattern
• CPC Class Codes: H05K 2201/026 Nanotubes or nanowires
• CPC Class Codes: H05K 2201/0323 Carbon
• CPC Class Codes: H10K 30/821 comprising carbon nanotubes
• CPC Class Codes: H10K 71/30 Doping active layers, e.g. electron transporting layers
• CPC Class Codes: H10K 85/1135 Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
• CPC Class Codes: H10K 85/225 comprising substituents
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

Certain example embodiments of this invention relate to large-area transparent conductive coatings (TCCs) including carbon nanotubes (CNTs) and nanowire composites, and methods of making the same. The σ_dc/σ_opt ratio of such thim films may be improved via stable chemical doping and/or alloying of CNT-based films. The doping and/or alloying may be implemented in a large area coating system, e.g., on glass and/or other substrates. In certain example embodiments, a CNT film may be deposited and then doped via chemical functionalization and/or alloyed with silver and/or palladium. Both p-type and n-type dopants may be used in different embodiments of this invention. In certain example embodiments, silver and/or other nanowires may be provided, e.g., to further decrease sheet resistance. Certain example embodiments may provide coatings that approach, meet, or exceed 90% visible transmission and 90 ohms/square target metrics.

Claims

1. A touch panel subassembly, comprising:

a glass substrate;

a first transparent, conductive CNT-based layer provided, directly or indirectly, on the glass substrate;

a deformable foil, the deformable foil being substantially parallel and in spaced apart relation to the glass substrate; and

a second transparent, conductive CNT-based layer provided, directly or indirectly, on the deformable foil, wherein at least one of the first and second CNT-based layers is doped with an n-type and/or p-type dopant.

2. The touch panel subassembly of claim 1, wherein the first and/or second CNT-based layer(s) is patterned.

3. The touch panel subassembly of claim 2, further comprising:

a plurality of pillars located between the deformable foil and the glass substrate, and

at least one edge seal at the periphery of the subassembly.

4. The touch panel subassembly of claim 3, wherein the deformable foil is a PET foil.

5. The touch panel subassembly of claim 1, wherein the first and/or second CNT-based layer(s) has/have a sheet resistance of less than 500 ohms/square.

6. The touch panel subassembly of claim 1, wherein the first and/or second CNT-based layer(s) has/have a sheet resistance of less than 300 ohms/square.

7. A touch panel apparatus, comprising:

the touch panel subassembly of claim 1; and

a display connected to a surface of the substrate of the touch panel subassembly opposite the deformable foil.

8. The touch panel apparatus of claim 7, wherein the display is an LCD display.

9. The touch panel apparatus of claim 8, wherein the touch panel apparatus is a capacitive touch panel apparatus.

10. The touch panel apparatus of claim 8, wherein the touch panel apparatus is a resistive touch panel apparatus.

11. The touch panel subassembly of claim 1, further comprising silver nanowire products synthesized by reducing silver nitrate in the presence of PVP in ethylene glycol, directly or indirectly, on the substrate, the silver nanowire products providing a long-distance charge transport to reduce the number of carbon nanotube junctions that otherwise would be present if the silver nanowire products were not formed.

12. The touch panel subassembly of claim 1, wherein the first and/or second CNT-based layer(s) include(s) porosity-reducing Pd nucleated growths from a PdCl₂ solution at junctions therein.

13. The touch panel subassembly of claim 1, wherein at least one of the first and second CNT-based layers is alloyed and/or otherwise metalized with:

palladium, silver, or both palladium and silver.

14. The touch panel subassembly of claim 1, further comprising a layer comprising zinc-doped tin oxide interposed between the glass substrate and the first CNT-based layer, the first CNT-based layer being conformal with respect to the layer comprising zinc-doped tin oxide.

15. The touch panel subassembly of claim 1, wherein:

the first CNT-based layer comprises a first solution-deposited film including first meshes of silver nanowires located substantially uniformly across a major surface of the substrate, the first meshes including first porous areas, at least some of the first porous areas being at least partially filled with first CNT bundles, and/or

the second CNT-based layer comprises a second solution-deposited film including second meshes of silver nanowires located substantially uniformly across a major surface of the deformable foil, the second meshes including second porous areas, at least some of the second porous areas being at least partially filled with second CNT bundles.

16. The touch panel subassembly of claim 1, wherein at least one of the first and second CNT-based layers comprises a solution-deposited composite film with silver nanowires and carbon nanotubes.

17. The touch panel subassembly of claim 16, wherein:

the silver nanowires form random, substantially non-bundled meshes throughout the film, the meshes being electrically structured to provide long-distance charge transport paths and remove resistive carbon nanotube junctions that otherwise would exist within current paths through the film, and

carbon nanotube bundles are shaped and arranged to provide charge collection sites in porous areas of the meshes and transport charge to correspondingly located meshes.

18. The touch panel subassembly of claim 17, wherein the carbon nanotube bundles have resistances of approximately 5-9 kΩ

/μ

m and wherein remaining junctions have resistances of approximately 20-40kΩ

/μ

m.

19. The touch panel subassembly of claim 16, wherein the first and second CNT-based layers each have an RMS roughness of no more than about 10 nm.