Surface modification of hydrophobic and/or oleophobic coatings

• US 8,691,331 B2
• Filed: 02/09/2009
• Issued: 04/08/2014
• Est. Priority Date: 02/09/2009
• Status: Active Grant

• Current Assignee: Essilor Laboratories of America Incorporated (EssilorLuxottica SA)
• Original Assignee: Newton Michael Tarleton, Prashant D. Santan
• Inventors: Santan, Prashant D., Tarleton, Newton Michael
• Primary Examiner(s): Yang, Jie
• Application Number:
  US12/322,930
• Publication Number:
  US 20100201940A1
• Time in Patent Office: 1,884 Days
• Field of Search: 427/164, 427/165
• US Class Current: 427/164
• CPC Class Codes: G02B 1/043 Contact lenses
• CPC Class Codes: G02C 7/02 Lenses; Lens systems ; Methods of designing lenses
• CPC Class Codes: Y10T 428/31 Surface property or characteristic of web, sheet or block

Abstract

A hydrophobic and/or oleophobic coating system having a reversibly reduced hydrophobicity. A hydrophobic and/or oleophobic coating is applied to and is bonded or otherwise strongly adhered to a substrate, such as an optical lens. The coating has sufficient thickness to provide a weakly adhered, excess portion that is mechanically removable. The excess portion of the hydrophobic and/or oleophobic coating has a surface that is modified to reduce hydrophobicity, such as by ion bombardment. The hydrophobicity of the coating is restored by mechanical removal of the excess portion of the coating.

Claims

1. A method for making an ophthalmic lens having a hydrophobic and/or oleophobic coating with reversibly reduced hydrophobicity, comprising the steps of:

providing an optical lens;

applying a hydrophobic and/or oleophobic coating to the optical lens, the hydrophobic and/or oleophobic coating adhered to the optical lens and having a thickness greater than about 10 nm and having an excess portion of the coating that is mechanically removable from the optical lens, the excess portion of the coating having a surface; and

modifying the surface by ion bombardment to reduce hydrophobicity.

2. The method of claim 1, wherein the hydrophobic and/or oleophobic coating is applied in a thickness of at least about 20 nm.

3. The method of claim 1, wherein the hydrophobic and/or oleophobic coating is applied in a thickness of about 30 nm.

4. The method of claim 1, wherein the surface is modified to reduce hydrophobicity to a water contact angle of about 110 degrees or less.

5. The method of claim 1, wherein the surface is modified to reduce hydrophobicity to a water contact angle of about 105 degrees or less.

6. The method of claim 1, wherein the surface is modified to reduce hydrophobicity to a water contact angle of about 100 degrees or less.

7. The method of claim 1, wherein the optical lens has an anti-reflective coating and the hydrophobic and/or oleophobic coating is adhered to the anti-reflective coating.

8. The method of claim 1, further comprising the steps of:

ink marking the modified surface; and

mechanically removing the modified surface.

9. The method of claim 8, wherein the modified surface is mechanically removed using a solvent.

10. The method of claim 9, wherein the solvent is selected from the group consisting of:

isopropyl alcohol, methanol, ethanol, acetone and combinations thereof.

11. The method of claim 1, further comprising the steps of:

edging the optical lens; and

mechanically removing the modified surface.

12. The method of claim 11, wherein the modified surface is mechanically removed using a solvent.

13. The method of claim 12, wherein the solvent is selected from the group consisting of:

isopropyl alcohol, methanol, ethanol, acetone and combinations thereof.

14. A method for making an article having a hydrophobic and/or oleophobic coating with reversibly reduced hydrophobicity, comprising the steps of:

providing a substrate;

applying a hydrophobic and/or oleophobic coating to the substrate, the hydrophobic and/or oleophobic coating adhered to the substrate and having a thickness greater than about 10 nm and having an excess portion of the coating that is mechanically removable from the substrate, the excess portion of the coating having a surface; and

modifying the surface to reduce hydrophobicity by treatment with high energy charged particles.

15. The method of claim 14, wherein the treatment with high energy charged particles is selected from the group consisting of:

ion bombardment, atmospheric plasma and electron beam.