Method and apparatus for diagnosing electrochemical sensor

• US 8,736,274 B2
• Filed: 04/26/2011
• Issued: 05/27/2014
• Est. Priority Date: 04/26/2011
• Status: Active Grant

• Current Assignee: Osaka Gas Company Limited
• Original Assignee: FIGARO Engineering, Inc. (New Cosmos Electric (Shanghai) Co. Ltd.), Osaka Gas Company Limited
• Inventors: Ohnishi, Hisao, Nonaka, Hidemasa, Inoue, Tomohiro, Kato, Yuki, Nonaka, Atsushi, Nakayama, Toshiro
• Primary Examiner(s): He, Amy
• Application Number:
  US13/094,374
• Publication Number:
  US 20120274337A1
• Time in Patent Office: 1,127 Days
• Field of Search: 324/525, 324/691
• US Class Current: 324/525
• CPC Class Codes: G01N 33/007 Arrangements to check the analyser calibrating gas analysers G01N33/0006

Abstract

A method and apparatus for diagnosing an electrochemical sensor that detects the concentration of a gas are operative for diagnosing whether or not the sensor is in an error state due to a rise in a resistance in the electrolyte of the sensor. Such detection is made on the basis of a current flowing between a sensing electrode and an opposite electrode or a voltage corresponding to the current. A method for diagnosing an electrochemical sensor having a solid or liquid electrolyte between a sensing electrode and an opposite electrode detects the concentration of the gas to be detected on the basis of a current flowing between the sensing electrode and the opposite electrode, or a voltage corresponding to the current. Whether or not the electrochemical sensor is in an error state is diagnosed on the basis of a resistance of the electrolyte between the two electrodes of the electrolyte.

Claims

1. A method for diagnosing an electrochemical sensor comprising a sensor unit including a solid or liquid electrolyte between a sensing electrode with which a gas to be detected makes contact and an opposite electrode, wherein the concentration of the gas to be detected is detected on the basis of a current flowing between the sensing electrode and the opposite electrode, or a voltage corresponding to the current, and wherein a water tank is connected to a lower part of the sensor unit for accommodating water or an absorbent polymer that has been caused to absorb water in an inner space thereof, the water present in the inner space being supplied to the electrolyte in the sensor unit, the method comprising the step of:

diagnosing whether or not the electrochemical sensor is in an error state representing a process of moving from a desiccated state in which there is no water at all in the water tank and there is not enough moisture in the electrolyte, to a completely dry state in which there is no moisture at all in the electrolyte when a resistance of the electrolyte is increased.

2. The method for diagnosing an electrochemical sensor of claim 1, further comprising the step of calculating the resistance of the electrolyte using an impedance of the electrochemical sensor in a state in which an alternating current or an alternating voltage has been applied in the electrochemical sensor;

and

making a diagnosis that the electrochemical sensor is in the error state when there has been found an increase in impedance relative to a normal impedance, wherein the normal impedance is the impedance of the electrochemical sensor in a normal state.

3. The method for diagnosing an electrochemical sensor of claim 2, further comprising the step of calculating the impedance using an output voltage or an output current of the electrochemical sensor in a state where an alternating current has been applied in the electrochemical sensor;

and

making a diagnosis that the electrochemical sensor is in the error state in which there has been found an increase of impedance, when there has been found an increase of voltage relative to a normal voltage, wherein the normal voltage is the output voltage of the electrochemical sensor in the normal state, or when there has been found a decrease in current relative to a normal current, wherein the normal current is the output current of the electrochemical sensor in the normal state.

4. The method for diagnosing an electrochemical sensor of claim 3, further comprising the step of applying an alternating current having a frequency of 10 Hz or greater as the alternating current.

5. The method for diagnosing an electrochemical sensor of claim 2, further comprising the step of applying an alternating current having a frequency of 10 Hz or greater as the alternating current.

6. The method for diagnosing an electrochemical sensor of claim 2, further comprising the step of calculating the impedance using an output current or an output voltage of the electrochemical sensor in a state where an alternating voltage is applied to the electrochemical sensor;

and

making a diagnosis that the electrochemical sensor is in the error state in which there has been found an increase of impedance, when there has been found a decrease in current relative to a normal current, wherein the normal current is the output current of the electrochemical sensor in the normal state, or there has been found an increase of voltage relative to a normal voltage, wherein the normal voltage is the output voltage of the electrochemical sensor in the normal state.

7. The method for diagnosing an electrochemical sensor of claim 6, further comprising the step of applying an alternating voltage having a frequency of 10 Hz or greater as the alternating voltage.

8. The method for diagnosing an electrochemical sensor of claim 2, further comprising the step of applying an alternating voltage having a frequency of 10 Hz or greater as the alternating voltage.

9. An apparatus for diagnosing an electrochemical sensor comprising a sensor unit including a solid or liquid electrolyte between a sensing electrode with which a gas to be detected makes contact and an opposite electrode, wherein the concentration of the gas to be detected is detected on the basis of a current flowing between the sensing electrode and the opposite electrode, or a voltage corresponding to the current, and wherein a water tank is connected to a lower part of the sensor unit for accommodating water or an absorbent polymer that has been caused to absorb water in an inner space thereof, the water present in the inner space being supplied to the electrolyte in the sensor unit, the apparatus comprising:

detecting means for detecting a resistance of the electrolyte; and

diagnosing means for diagnosing whether or not the electrochemical sensor is in an error state representing a process of moving from a desiccated state in which there is no water at all in the water tank and there is not enough moisture in the electrolyte, to a completely dry state in which there is no moisture at all in the electrolyte when the resistance of the electrolyte detected by the detecting means is increased.

10. The apparatus for diagnosing an electrochemical sensor of claim 9, wherein

the resistance of the electrolyte is an impedance of the electrochemical sensor in a state where an alternating current or an alternating voltage has been applied in the electrochemical sensor;

and

the diagnosing means makes a diagnosis that the electrochemical sensor is in the error state when there has been found an increase of impedance relative to the normal impedance, wherein the normal impedance is the impedance of the electrochemical sensor in the normal state.

11. The apparatus for diagnosing an electrochemical sensor of claim 10, wherein the impedance is calculated using an output voltage or an output current of the electrochemical sensor in a state where an alternating current has been applied in the electrochemical sensor;

and

the diagnosing means makes a diagnosis that the electrochemical sensor is in the error state in which there has been found an increase of impedance, when there has been found an increase of voltage relative to a normal voltage, wherein the normal voltage is the output voltage of the electrochemical sensor in the normal state, or there has been found a decrease in current relative to a normal current, wherein the normal current is the output current of the electrochemical sensor in the normal state.

12. The apparatus for diagnosing an electrochemical sensor of claim 10, wherein the impedance is calculated using an output current or an output voltage of the electrochemical sensor in a state where an alternating voltage is applied to the electrochemical sensor;

and

the diagnosing means makes a diagnosis that the electrochemical sensor is in the error state in which there has been found an increase of impedance, when there has been found a decrease in current relative to a normal current, wherein the normal current is the output current of the electrochemical sensor in the normal state, or there has been found an increase of voltage relative to a normal voltage, wherein the normal voltage is the output voltage of the electrochemical sensor in the normal state.