Electrochromic device capable of controlling visible and infrared radiations

• US 8,736,942 B2
• Filed: 03/11/2011
• Issued: 05/27/2014
• Est. Priority Date: 03/12/2010
• Status: Active Grant

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Risser, Steven M., McGinniss, Vincent D., Heintz, Amy M., Spahr, Kevin B., Browning, James D.
• Primary Examiner(s): Ben, Loha
• Application Number:
  US13/583,747
• Publication Number:
  US 20130010346A1
• Time in Patent Office: 1,173 Days
• Field of Search: 359265-275, 348/817, 345/105, 977/742
• US Class Current: 359/270
• CPC Class Codes: G02F 1/1516 comprising organic material
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2203/11 involving infrared radiation

Abstract

An electrochromic device that is capable of changing the transmission of either visible or infrared radiations as a function of the polarity of a voltage applied to the device.

Claims

1. An electro-chromatic device comprising:

a first conductor adapted to be connected to a voltage supply;

a layer of Infra-Red (IR) control material disposed upon said first conductor;

a layer of electrolytic material disposed upon a surface of said IR control material that is opposite from said first conductor;

a layer of color changeable material disposed upon a surface of said electrolytic material that is opposite from said IR control material; and

a second conductor adapted to be connected to a voltage supply, said second conductor disposed upon a surface of said color changeable material that is opposite from said electrolytic material.

2. The device according to claim 1 wherein said color changeable layer includes an electro-chromatic material.

3. The device according to claim 2 wherein at least one of said conductors is formed from a transparent material.

4. The device according to claim 3 wherein at least one of said conductors is formed as a Carbon NanoTube (CNT) film.

5. The device according to claim 2 further including a switching device adapted to be connected to the voltage supply, said switching device connected to said first and second conductors and operable to selectively apply a first voltage to said first and second conductors, said switching device further operable to selectively apply a second voltage to said first and second conductors, said second voltage having a reverse polarity from that of said first voltage.

6. The device according to claim 5 wherein said electrolytic material is an anionic material with a net negative charge and further wherein said color changeable material is activated to change the color of the device by application of said first voltage to said first and second conductors to urge anions from said electrolytic material into said color changeable material and said IR control material is activated to change the IR signature of the device by application of said second voltage to said first and second conductors to urge anions from said electrolytic material into said IR control material.

7. The device according to claim 6 wherein said IR control material and color changeable material revert to their original states when said voltages are removed from said first and second conductors.

8. The device according to claim 7 wherein said layers and conductors are formed as parallel sheets.

9. The device according to claim 8 wherein said parallel sheets are disposed upon a substrate.

10. The device according to claim 9 wherein said substrate is formed from a flexible material as a first flexible substrate and further wherein the device includes a second flexible substrate disposed upon a surface of the device opposite from said first flexible substrate.

11. The device according to claim 7 wherein said first conductor is formed as a fiber and further wherein said layers and said second conductor are formed as concentric layers over said first conductor.

12. The device according to claim 5 wherein said electrolytic material is an cationic material with a net positive charge and further wherein said color changeable material is activated to change the color of the device by application of said first voltage to said first and second conductors to urge cations from said electrolytic material into said color changeable material and said IR control material is activated to change the IR signature of the device by application of said second voltage to said first and second conductors to urge cations from said electrolytic material into said IR control material.

13. The device according to claim 12 wherein said IR control material and color changeable material revert to their original states when said voltages are removed from said first and second conductors.

14. The device according to claim 13 wherein said layers and conductors are formed as parallel sheets.

15. The device according to claim 14 wherein said parallel sheets are disposed upon a substrate.

16. The device according to claim 15 wherein said substrate is formed from a flexible material as a first flexible substrate and further wherein the device includes a second flexible substrate disposed upon a surface of the device opposite from said first flexible substrate.

17. The device according to claim 13 wherein said first conductor is formed as a fiber and further wherein said layers and said second conductor are formed as concentric layers over said first conductor.

18. A method for changing one of color or Infra-Red (IR) signature of a device comprising the steps of:

(a) providing a device that includes;

a first transparent conductor;

a layer of Infra-Red (IR) control material disposed upon the first transparent conductor;

a layer of electrolytic material disposed upon a surface of the IR control material that is opposite from the first transparent conductor;

a layer of color changeable material disposed upon a surface of the electrolytic material that is opposite from the IR control material; and

a second conductor disposed upon a surface of the color changeable material that is opposite from the electrolytic material; and

(b) applying a voltage to the first and second conductors to cause one of the color of the color changeable material to change or the IR signature of the control material to change.

19. The method according to claim 18 wherein application of a first voltage to the conductors in step (b) activates the color change material to change the color of the device while application of a second voltage having a polarity opposite from the first voltage to the conductors in step (b) activates the IR control material to change the IR signature of the device.

20. The method according to claim 19 further including a step of removing the voltages from the first and second conductors to cause the control material and color changeable material to revert to their original states.