Transparent electrochromic systems with a plurality of polarisation electrodes

• US 8,736,946 B2
• Filed: 09/24/2010
• Issued: 05/27/2014
• Est. Priority Date: 09/28/2009
• Status: Active Grant

• Current Assignee: Essilor International SA
• Original Assignee: Essilor International SA
• Inventors: Archambeau, Samuel, Biver, Claudine, Bovet, Christian, Cano, Jean-Paul, Duluard, Sandrine, Saugey, Anthony
• Primary Examiner(s): Collins, Darryl J
• Assistant Examiner(s): O'NEILL, GARY WILLIAM
• Application Number:
  US13/498,107
• Publication Number:
  US 20120307340A1
• Time in Patent Office: 1,341 Days
• Field of Search: 359265-267, 359/271, 359273-275, 359/591, 296/77.1, 296/84.1, 296 9619- 9622, 296 971- 9713
• US Class Current: 359/275
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2001/1557 Side by side arrangements of working and counter electrodes

Abstract

The invention relates to transparent electrochromic systems which each include one pair of supply electrodes and at least one pair of polarization electrodes. The polarization electrodes prevent a reaction of mutual neutralization of the electroactive substances of the systems from causing unnecessary consumption of electric current. Said electrodes also prevent a neutralization reaction from limiting a lower value of light transmission of the systems. For this purpose, the polarization electrodes produce an electric field inside the systems, which attracts the electroactive substances that have already reacted with the supply electrodes to different areas.

Claims

1. A transparent electrochromic system, allowing clear vision through said system, and comprising:

first and second outer walls defining a closed volume, the system being transparent for a direction of gaze passing through the outer walls and said closed volume between two opposite sides;

a liquid or gel contained in the closed volume;

first and second electroactive substances distributed in the liquid or gel, with respective oxidation-reduction potential values that are different, at least some of the first and second electroactive substances having an optical effect that varies between an oxidised form and a reduced form of said substances;

a pair of transparent first and second supply electrodes, together supported by the first outer wall, and configured to be connected respectively to two output terminals of a first variable electrical source for supplying the system with electric current, so as to transfer electrons to or from at least some of the electroactive substances, in a reverse mode between said first and second electroactive substances at a same moment of operation of the system; and

a pair of transparent first and second polarisation electrodes together supported by the second outer wall and having no contact with said supply electrodes within the system, said first polarisation electrode being situated opposite the first supply electrode and on an opposite side of the closed volume with respect to the first supply electrode along a direction perpendicular to the outer walls, and said second polarisation electrode being situated opposite the second supply electrode and on an opposite side of the closed volume with respect to the second supply electrode along a direction perpendicular to the outer walls,

the first polarisation electrode and the first supply electrode being configured to be further connected respectively to two output terminals of a second variable electrical source, the output terminals of said first and second variable electrical sources that are connected to the first supply electrode being configured to have respective polarities that are identical at least at some moments of operation of the system, said polarities being considered respectively with respect to the other output terminal of the corresponding electrical source.

2. The system according to claim 1, further comprising a transparent third polarisation electrode situated between the supply electrodes on one hand and the first outer wall on the other hand, said third polarisation electrode having no contact with said supply electrodes and with the liquid or gel contained in the closed volume, and with said first and second polarisation electrodes, and being configured to be connected to a reference terminal having electrical potential.

12. An electrochromic device comprising:

a transparent electrochromic system according to claim 1;

the first variable electrical source, with the two output terminals of said first variable electrical source including first and second output terminals connected respectively to the first and second supply electrodes, the first variable electrical source being configured to supply the system with electric current by applying between said supply electrodes an electric voltage that is greater than a difference between the respective oxidation-reduction potential values of the first and second electroactive substances; and

the second variable electrical source having a first output terminal connected to the first polarisation electrode.

13. The electrochromic device according to claim 12, in which:

a second output terminal of the second variable electrical source is connected to the first supply electrode,

the first output terminal of the second variable electrical source being further connected to the second supply electrode, and

the second output terminal of the second variable electrical source being further connected to the second polarisation electrode,

the first output terminals of said first and second electrical sources having respective polarities that are identical at least at some moments of operation of the system, said polarities being considered respectively with respect to the second output terminals of the corresponding electrical sources.

14. The electrochromic device according to claim 12, in which:

a second output terminal of the second variable electrical source is connected to the first supply electrode,

the device further comprising a third variable electrical source having a first output terminal connected to the second supply electrode, and a second output terminal connected to the second polarisation electrode,

the first output terminal of said first variable electrical source and the second output of the second variable electrical sources having respective polarities that are identical at least at some moments of operation of the system, said polarities being considered respectively with respect to the other output terminal of the corresponding electrical source.

15. The electrochromic device according to claim 13, in which:

the system includes a transparent third polarisation electrode situated between the supply electrodes on one hand and the first outer wall on the other hand, said third polarisation electrode having no contact with said supply electrodes and with the liquid or gel contained in the closed volume, and

at least one of the electrical sources has a reference terminal having an electric potential different from the output terminals of said electrical source, said reference terminal being connected to the third polarisation electrode.

3. A transparent electrochromic system, allowing a clear vision through said system, and comprising:

first and second outer walls defining a closed volume, the system being transparent for a direction of gaze passing through the outer walls and said closed volume between two opposite sides;

a liquid or gel contained in the closed volume;

first and second electroactive substances distributed in the liquid or gel, with respective oxidation-reduction potential values that are different, at least some of the first and second electroactive substances having an optical effect that varies between an oxidised form and a reduced form of said substances;

a pair of transparent supply electrodes, together supported by a the first outer wall, and configured to be connected respectively to two output terminals of a first variable electrical source for supplying the system with electric current, so as to transfer electrons to or from at least some of the electroactive substances, in a reverse mode between said first and second electroactive substances at a same moment of operation of the system;

a pair of transparent first and second polarisation electrodes together supported by the second outer wall and having no contact with said supply electrodes within the system, and said first and second polarisation electrodes being situated respectively opposite the first and second supply electrodes, and on and opposite side of the closed volume with respect to the supply electrodes in a direction perpendicular to the outer walls; and

a pair of transparent third and fourth polarisation electrodes situated between the supply electrodes on one hand, and the first outer wall on the other hand, said third and fourth polarisation electrodes being situated respectively in line with the first and second supply electrodes along respective directions perpendicular to the outer walls with no contact with said supply electrodes within the system,

said first and third polarisation electrodes being configured to be connected respectively to two output terminals of a second variable electrical source, the output terminals of said first and second variable electrical sources that are connected respectively to the first supply electrode and the third polarisation electrode being configured to have respectively polarities that are identical at least at some moments of operation of the system, said polarities being considered respectively with respect to the other output terminal of the corresponding electrical source.

4. The system according to claim 3, in which the first electroactive substances in the oxidised form of said first electroactive substances each have an electric charge greater than an electric charge of each second electroactive substance in the reduced form of said second electroactive substances.

5. The system according to claim 3, forming at least a portion of a spectacle eyeglass, a goggles eyeglass, an optical lens, a helmet visor, an aeroplane window or a glazing.

6. The system according to claim 3, in which the first and second polarisation electrodes are in contact with the liquid or gel contained in the closed volume.

7. The system according to claim 3, comprising at least one electrically insulating film arranged to prevent contact between the first and second polarisation electrodes and the liquid or gel contained in the closed volume.

8. The system according to claim 3, further comprising a network of inner walls forming a partition of the closed volume into cells that are juxtaposed parallel to the outer walls, said inner walls being perpendicular to said outer walls, and in which the supply electrodes are each in contact with the liquid or gel contained in a plurality of the cells, and the liquid or gel contained in each cell containing both the first and second electroactive substances.

9. The system according to claim 3, further comprising a network of inner walls forming a partition of the closed volume into cells that are juxtaposed parallel to the outer walls, said inner walls being perpendicular to said outer walls, and in which, for at least some of the cells, a single one of the supply electrodes is in contact with the liquid or gel contained in each cell, a first one of said cells that is supplied by the first supply electrode being adjacent to a second of said cells that is supplied by the second supply electrode with an ion bridge between said first and second cells.

10. The system according to claim 9, in which at least some of the inner walls extend towards the second outer wall, along a direction perpendicular to the outer walls, until closing said cells on the side of said outer wall to avoid the electroactive substances that are close to said first and second polarisation electrodes passing from one cell to a neighbouring cell.

11. The system according to claim 9, in which the liquid or gel in the first one of the cells contains first electroactive substances without second electroactive substances, and the liquid or gel in the second one of the cells contains second electroactive substances without first electroactive substances.

16. An electrochromic device, comprising:

the electrochromic system according to claim 3;

the first variable electrical source, with the two output terminals of said first variable electrical source including first and second output terminals connected respectively to the first and second supply electrodes, the first variable electrical source being configured to supply the system with electric current by applying between said supply electrodes an electric voltage that is greater than a difference between the respective oxidation-reduction potential values of the first and second electroactive substances; and

the second variable electrical source having a first output terminal connected to the first polarisation electrode, and a second output terminal connected to the third polarisation electrode,

the first output terminal of said first variable electrical source and the second output terminal of the second variable electrical source having respective polarities that are identical at least at some moments of operation of the system, said polarities being considered respectively with respect to the other output terminal of the corresponding electrical source.

17. The electrochromic device according to claim 16, further comprising:

a third variable electrical source having a first output terminal connected to the fourth polarisation electrode, and a second output terminal connected to the second polarisation electrode,

the second output terminal of said first electrical source and the first output terminal of the third variable electrical source having respective polarities that are identical at least at some moments of operation of the system, said polarities being considered respectively with respect to the other output terminal of the corresponding electrical source.

18. The electrochromic device according to claim 16, in which:

the first output terminal of the second variable electrical source is further connected to the fourth polarisation electrode, and

the second output terminal of the second electrical source is further connected to the second polarisation electrode.