Stabilizers for ceramic body extrusion

• US 8,741,209 B2
• Filed: 11/30/2007
• Issued: 06/03/2014
• Est. Priority Date: 11/30/2007
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Chou, Kevin Ying
• Primary Examiner(s): Del Sole, Joseph S
• Assistant Examiner(s): SNELTING, ERIN LYNN
• Application Number:
  US11/998,634
• Publication Number:
  US 20090143219A1
• Time in Patent Office: 2,377 Days
• Field of Search: 264/630, 264/631
• US Class Current: 264/630
• CPC Class Codes: B28B 2003/203 for multi-channelled structures, e.g. honeycomb structures
• CPC Class Codes: C04B 35/195 Alkaline earth aluminosilicates, e.g. cordierite or anorthite
• CPC Class Codes: C04B 38/0006 Honeycomb structures from one or more corrugated sheets by winding or stacking C04B38/0083
• CPC Class Codes: Y10T 428/24149 Honeycomb-like

Abstract

A mixture for making a ceramic article includes a ceramic forming component, a liquid vehicle, a cellulosic binder, and a stabilizer comprising an acetate salt. The disclosure also provides a method of making the ceramic article including extruding the mixture to form a ceramic green body, drying the ceramic green body to remove at least a portion of the liquid vehicle, and optionally firing to form the ceramic article. The ceramic green body possesses excellent strength and excellent skin properties without increasing the organic load or the addition of hydrated clays.

Claims

1. A method of forming a honeycomb green body, the method comprising:

forming an extrudable mixture of a ceramic forming component, an aqueous liquid vehicle, an alkyl cellulosic binder, and an extrudable mixture stabilizer comprising a source of acetate anion in an amount of from 0.2 to 1.5 wt % added to the mixture as an aqueous solution; and

extruding the mixture to form the honeycomb green body having superior strength properties as measured by breaking strain, scant modulus, peak load, and stiffness, and superior skin properties as measured by the absence of streaking or cracking, the superior strength and superior skin properties being compared to a green body prepared without the stabilizer, wherein the source of an acetate anion stabilizer includes a cation selected from a group consisting of an alkali metal cation, an alkali earth metal cation, ammonium cation, and a mixture thereof.

2. The method of claim 1, further comprising drying the ceramic honeycomb green body to remove at least a portion of the aqueous liquid vehicle.