Linerless prepregs, composite articles therefrom, and related methods

• US 8,772,398 B2
• Filed: 09/27/2006
• Issued: 07/08/2014
• Est. Priority Date: 09/28/2005
• Status: Active Grant

• Current Assignee: Entrotech, Inc.
• Original Assignee: Entrotech Composites, LLC
• Inventors: Strange, Andrew C., McGuire, James E. Jr.
• Primary Examiner(s): CAIN, EDWARD J
• Application Number:
  US12/066,263
• Publication Number:
  US 20080299395A1
• Time in Patent Office: 2,841 Days
• Field of Search: 524/492, 523/466
• US Class Current: 524/492
• CPC Class Codes: C08J 2371/00 Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain of polyacetals C08J2359/00; of epoxy resins C08J2363/00; of polythioether-ethers C08J2381/02; of polyethersulfones C08J2381/06; Derivatives of such polymers
• CPC Class Codes: C08J 5/248 using pre-treated fibres
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 7/06 Elements
• CPC Class Codes: Y10T 428/31 Surface property or characteristic of web, sheet or block
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

Linerless prepreg, composite articles therefrom, and related methods are disclosed. In linerless prepreg according to the invention, matrix material is impregnated into a reinforcement material without the need for any release liners during manufacture or storage thereof. Beneficially, prepreg of the invention is capable of being easily wound into a roll or stacked for storage, without sticking to itself when it is later used in the manufacture of composite articles.

Claims

1. A resin composition forming an initial matrix material during preparation of a composite article, the composition comprising:

an essentially uncured initial resin comprising at least one thermosetting resin and, optionally, at least one thermoplastic resin;

at least one curative for the at least one thermosetting resin; and

at least one viscosity modifier;

wherein viscosity of the initial resin in the resin composition is less than about 6 Pa·

s when tested at 25°

C.;

wherein the resin composition is capable of impregnating a reinforcement material to form a prepreg capable of being used to form the composite article without use of release liners; and

wherein the resin composition is capable of remaining impregnated throughout the reinforcement material, without partial curing, until final cure of the resin composition to form the composite article.

2. The resin composition of claim 1, wherein the initial resin has a viscosity of about 2.5 Pa·

s to about 4.5 Pa·

s when tested at 25°

C.

3. The resin composition of claim 1, wherein the initial resin comprises at least one resin based on diglycidyl ether of Bisphenol F.

4. The resin composition of claim 1, wherein the reinforcement material comprises a fibrous reinforcement material.

5. The resin composition of claim 1, wherein the viscosity modifier comprises a thixotropic agent.

6. The resin composition of claim 5, wherein the resin composition exhibits Bingham plastic fluid behavior.

7. The resin composition of claim 1, wherein the resin composition exhibits Bingham plastic fluid behavior.

8. The resin composition of claim 1, wherein the viscosity modifier comprises fumed silica.

9. The resin composition of claim 1, wherein the viscosity modifier comprises a nanomaterial.

10. The resin composition of claim 1, wherein about 2% to about 7% by weight of the total resin composition comprises one or more viscosity modifiers.

11. The resin composition of claim 1, wherein the curative facilitates cure of the resin composition within about 45 to about 60 minutes when heated to about 120°

C.

12. The resin composition of claim 1, wherein at least one curative is selected from an amine curative and a dicyandiamide.

13. The resin composition of claim 1, further comprising at least one elastomeric toughening component.

14. The resin composition of claim 1, wherein the resin composition is hot-melt processable.

15. A prepreg comprising:

the reinforcement material of claim 1; and

the resin composition of claim 1 impregnated throughout the reinforcement material.

16. The prepreg of claim 15, wherein the resin composition is essentially uncured.

17. The prepreg of claim 15, wherein the prepreg is manufactured and stored without the use of release liners.

18. A composite article derived from the prepreg of claim 15, wherein the resin composition is cured.

22. A method of preparing a prepreg, comprising:

providing the resin composition of claim 1; and

impregnating the reinforcement material of claim 1 with the resin composition of claim 1 to form the prepreg.

23. The method of claim 22, wherein the resin composition is impregnated throughout the reinforcement material without the use of solvent.

24. The method of claim 22, wherein the resin composition remains essentially uncured until fully curing the prepreg to form a composite article.

25. A method of preparing a composite article, comprising:

assembling the prepreg of claim 15 into a desired shape; and

curing the resin composition of the prepreg to form the composite article in essentially the desired shape.

26. The resin composition of claim 1, wherein the initial resin consists of thermosettable resin.

27. The resin composition of claim 1, wherein thermosettable resin in the initial matrix material consists of the initial resin having a viscosity of less than about 6 Pa·

s when tested at 25°

C.

19. A linerless prepreg comprising:

a reinforcement material; and

a matrix material,

wherein a layer of the linerless prepreg is capable of being stacked adjacent another layer of the linerless prepreg or rolled upon itself without significantly sticking to the adjacent linerless prepreg layer or itself when used in manufacture of a composite article therefrom.

20. A linerless prepreg comprising:

a reinforcement material; and

a matrix material,

wherein a layer of the linerless prepreg is capable of being stacked adjacent another layer of the linerless prepreg or rolled upon itself without significantly sticking to the adjacent linerless prepreg layer or itself when used in manufacture of a composite article therefrom, and,

wherein an amount of force required to separate adjacent stacked layers of the linerless prepreg is less than about 3 N/cm as measured according to a 180-degree peel angle test conducted at a testing speed of 30 cm/min (12 in/min).

21. The linerless prepreg of claim 20, wherein the amount of force is less than about 1 N/cm.