Anti-reflective coatings for optically transparent substrates

• US 8,784,985 B2
• Filed: 09/11/2013
• Issued: 07/22/2014
• Est. Priority Date: 06/10/2009
• Status: Expired due to Fees

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Mukhopadhyay, Sudip, Pandey, Yamini, Dankers, Lea
• Primary Examiner(s): Loewe, Robert S
• Application Number:
  US14/023,616
• Publication Number:
  US 20140011019A1
• Time in Patent Office: 314 Days
• Field of Search: None
• US Class Current: 428/327
• CPC Class Codes: C03C 17/30 with silicon-containing compounds
• CPC Class Codes: C03C 2217/732 made of a single layer
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: H01L 31/02161 for devices characterised by at least one potential jump barrier or surface barrier
• CPC Class Codes: H01L 31/02168 the coatings being antireflective or having enhancing optical properties for the solar cells
• CPC Class Codes: H01L 31/042 PV modules or arrays of single PV cells supporting structures for PV modules H02S20/00
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy
• CPC Class Codes: Y02E 10/52 PV systems with concentrators
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

Anti-reflective coatings and coating solutions, optically transparent elements and improved processes for preparing AR coatings and coating solutions are described. The anti-reflective coatings are formed from at least two different alkoxy silane materials in a base catalyzed reaction.

Claims

1. An optically transparent element comprising:

an optically transparent substrate; and

an anti-reflective coating disposed on at least one surface of the optically transparent substrate, the anti-reflective coating comprising a polymer having an average particle size of between 1 nm and 100 nm, the polymer consisting essentially of tetraethoxy silane residues and methyltriethoxy silane residues;

the polymer comprising at least 50 mole percent of the tetraalkoxy silane residues based on the total moles of polymer;

the polymer comprising between 35 and 50 mole percent of the methyltriethoxy silane residues based on the total moles of polymer; and

the anti-reflective coating having a refractive index of less than 1.28.

2. The optically transparent element of claim 1, wherein the coating comprises polymer particles having an average size between 25 nm and 75 nm.

3. The optically transparent element of claim 1, wherein the anti-reflective coating has a refractive index of between 1.15 and 1.25.

4. The optically transparent element of claim 1, wherein the coating has a pencil hardness of at least 2H.

5. The optically transparent element of claim 1, wherein said substrate is glass.

6. The optically transparent element of claim 1, wherein said coating has a contact angle of less than 10.

7. The optically transparent element of claim 1, wherein said polymer is a polycondensate resulting from hydrolysis and polycondensation of tetraethoxy silane and methyltriethoxy silane.

8. The optically transparent element of claim 1, wherein said anti-reflective coating has a refractive index of 1.16 or greater and less than 1.28, and a pencil hardness of at least 2H.

9. An optically transparent element comprising:

an optically transparent glass substrate; and

a silica-based anti-reflective coating disposed on at least one surface of the optically transparent substrate, the anti-reflective coating comprising a polymer derived from at least two different alkoxysilane precursors and including at least one first tetraalkoxy silane residue, and at least one second alkoxy silane residue selected from the group consisting of trialkoxy silanes, dialkoxy silanes, monoalkoxy silanes, and combinations thereof, the polymer comprising between 35 and 50 mole percent of the at least one second alkoxy silane residue based on the total moles of polymer and having a refractive index of 1.3 or less and a pencil hardness of at least 2H.

10. The optically transparent element of claim 9, wherein the anti-reflective coating has a refractive index of between 1.15 and 1.25.

11. The optically transparent element of claim 9, wherein the at least one first tetraalkoxy silane residue comprises tetraethoxy silane and the at least one second alkoxy silane comprises methyltriethoxy silane.

12. The optically transparent element of claim 9, wherein the coating comprises polymer particles having an average size between 1 nm and 100 nm.

13. The optically transparent element of claim 9, wherein the at least one second alkoxy silane residue is selected from the group consisting of trialkoxy silanes, monoalkoxy silanes, and combinations thereof.

14. The optically transparent element of claim 9, wherein said coating has a contact angle of less than 10.

15. The optically transparent element of claim 9, wherein said polymer is a polycondensate resulting from hydrolysis and polycondensation of tetraethoxy silane and the at least one second alkoxy silane selected from the group consisting of trialkoxy silanes, dialkoxy silanes, monoalkoxy silanes, and combinations thereof.

16. The optically transparent element of claim 9, wherein said anti-reflective coating has a refractive index of 1.16 or greater and less than 1.28.

17. The optically transparent element of claim 9, wherein the coating comprises polymer particles having an average size between 25 nm and 75 nm.