Sanitizing composition and method of preparation

• US 8,795,697 B2
• Filed: 04/09/2005
• Issued: 08/05/2014
• Est. Priority Date: 06/03/2004
• Status: Active Grant

• Current Assignee: James S. Brown
• Original Assignee: James S. Brown
• Inventors: Brown, James S.
• Primary Examiner(s): Justice, Gina C
• Application Number:
  US11/102,017
• Publication Number:
  US 20050271595A1
• Time in Patent Office: 3,405 Days
• Field of Search: 424/401, 424/404, 424/405, 510/130, 510/138, 510/139, 510/158
• US Class Current: 424/405
• CPC Class Codes: A61K 2800/28 Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
• CPC Class Codes: A61K 8/0204 Specific forms not provided for by any of groups A61K8/0208 - A61K8/14
• CPC Class Codes: A61K 8/0241 Containing particulates characterized by their shape and/or structure see also A61K8/04, A61K8/11, and A61K8/14, further aspects are classified in A61K2800/40 and subcodes
• CPC Class Codes: A61K 8/042 Gels
• CPC Class Codes: A61L 2/0082 using chemical substances
• CPC Class Codes: A61Q 17/005 Antimicrobial preparations
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: C11D 17/0013 Liquid compositions with insoluble particles in suspension C11D17/0021, C11D17/0026, C11D17/003 take precedence
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
• CPC Class Codes: C11D 3/201 linear
• CPC Class Codes: C11D 3/2013 fatty or with at least 8 carbon atoms in the alkyl chain
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Abstract

The invention provides a sanitizing composition in the form of a viscous liquid or gel suitable for use as a handwash composition comprising alcohol, water and a thickener wherein the viscous liquid or gel has particles suspended therein, wherein said particles provide the composition with a granular texture and are capable of being worn away when rubbed. The particles may deliver one or more agents to the skin e.g. antimicrobial, antibacterial or antiviral agents, emollients and/or moisturizers, fragrances, colorings or UV markers.

Claims

1. A sanitizing composition comprising:

a viscous liquid comprising alcohol, water, and a thickener; and

a plurality of essentially homogeneous particles comprising;

a particle-forming material; and

an antimicrobial agent different than the alcohol in the viscous liquid;

wherein the alcohol is present in a range between about 55% to about 80% by weight; and

wherein the plurality of particles are adapted to abrade away completely when rubbed.

2. The sanitizing composition of claim 1, wherein at least some of the plurality of particles additionally comprise an additional component selected from the group consisting of an emollient, a moisturizer, an ultraviolet (UV) marker and combinations thereof.

3. The sanitizing composition of claim 1, wherein the antimicrobial agent different than the alcohol in the viscous liquid is selected from the group consisting of:

Allicin, Benzalkonium chloride, bacteriophages, Benzethonium chloride, Benzoic acid, Benzyl alcohol, Bromochlorophene 2-Bromo-2-nitropropane-1,3-diol, Butylparaben, Capryloyl collagen amino acids, Capryloyl glycine, Capryloyl keratin amino acids, Captan, Cetethyldimonium bromide, Cetyl pyridinium chloride, Chlorothymol, Chloroxylenol, Citral, Citron oil, Copper PCA, Dichlorobenzyl alcohol, Dilauryldimonium chloride, Domiphen bromide, Ethylparaben, Eucalyptus globulus extract, Fennel (Foeniculum vulgare) extract, Garlic (Allium sativum) extract, Gentian violet Glyceryl caprylate, Glyceryllaurate, Hexamidine diisothionate, Hexetidine, Hinokitiol, Honeysuckle (Lonicera caprifolium) extract, Honeysuckle (Lonicera japonica) extract, Leptospermum scoparium oil, Lichen (Usnea barbata) extract, Methylparaben, Myristalkonium chloride, Pentylene glycol, Pfaffia paniculata extract, Phenethyl alcohol, Phenol, Phenoxyethanol, Phenoxyisopropanol, Phenyl mercuric acetate, Phenyl mercuric benzoate, Phenyl mercuric borate, o-Phenylphenol, Phytosphingo sine, Piroctone olamine, Polymethoxy bicyclic oxazolidine, Potassium sorbate, Propylparaben, Ricinoleamodopropyltrimonium ethosulfate, Sage (Salvia officinalis) extract, Sodium benzoate, Sodium pyrithione, Sodium ricinoleate, Sodium shale oil sulfonate, Tea tree (Melaleuca alternifolia) oil, Thimerosal, Thyme (Thymus vulgaris) extract, Thymol, Triclocarban, Triclosan, Undecylenamidopropyltrimonium methosulfate, Undecylenic acid, Zinc oxide, Zinc PCA, Zinc pyrithione, Zinc undecylenate, Aluminum PCA, Ammonium iodide, Butylglucoside caprate, Caprylic/capric glycerides, Chlorhexidine, Chlorhexidine diacetate, Chlorhexidine digluconate, Chlorhexidine dihydrochloride, Chlorphenesin, alpha-Glucan-oligosaccharide, Iceland moss (Cetraria islandica) extract, Lactoferrin, Lauralkonium bromide, Lauralkonium chloride, Laurtrimonium chloride, Laurylpyridinium chloride, Leptospermum scoparium oil, Mushroom (Cordyceps sabolifera) extract, Orange (Citrus aurantium dulcis) peel extract, Orange (Citrus sinensis) flower extract, PEG-42 ebiriko ceramides extract, Peppermint (Mentha piperita) extract, Philodendron (Phellodendron amurense) extract, Pine (Pinus sylvestris) needle extract, Polymethoxy bicyclic oxazolidine, Quaternium 73, Rubus thunbergii extract, Sodium shale oil sulfonate, Sodium usnate, Undecylenic acid, Zinc PCA, docosanol, eicosanol and mixtures thereof.

4. The composition of claim 3, wherein the thickener is selected the group consisting of:

Acrylates/C10-C30 alkyl acrylate crosspolymer, Acrylates/ceteth-20 itaconate copolymer, Acrylates/ceteth-20 methacrylates copolymer, Acrylates/palmeth-25 acrylate copolymer, Acrylates/steareth-20 itaconate copolymer, Acrylates/steareth-20 methacrylate copolymer, Acrylates/steareth-50 acrylate copolymer, AcrylatesNA crosspolymer, Acrylates/vinyl isodecanoate crosspolymer, Acrylic acid/acrylonitrogens copolymer, Algin, Aluminum/magnesium hydroxide stearate, Ammonium acrylates/acrylonitrogens copolymer, Ammonium alginate, Ammonium polyacryl dimethyl tauramide/VA, Arachidyl alcohol, Attapulgite, Behenic acid, Behenyl alcohol, Behenyl behenate, Bentonite, CI-5 alkyl galactomannan CIS-36 acid, CIS-36 acid glycol ester, CIS-36 acid triglyceride, Calcium alginate, Calcium carrageenan, C12-15 alcohols, C12-16 alcohols, Caprylic alcohol, Carbomer, Carboxymethyl hydroxyethylcellulose, Carrageenan (Chondrus crispus), Cellulose, Cellulose gum, Ceteareth-3, Ceteareth-60 myristyl glycol, Cetearyl alcohol, Cetearyl behenate, Cetearyl octanoate, Cetearyl stearate, Cetostearyl stearate, Cetyl alcohol, Cetyl betaine, Cetyl esters, Cetyl hydroxyethylcellulose, Cetyl myristate, Cetyl palmitate, Cocamide, Cocamide DEA, Cocamide MEA, Cocamide MIPA, Cocamidopropylamine oxide, Cocamidopropyl betaine, Coco-betaine, Coco/oleamidopropyl betaine, Coco-rapeseedate, Cocoyl amido hydroxy sulfobetaine, Cocoyl monoethanolamide ethoxylate, Colloidal silica sols, DEA-hydrolyzed lecithin DEA-linoleate, DEA-oleth-3 phosphate, DEA oleth-10 phosphate, Decyl alcohol, Dextran, Dextrin, Dihydroxyethyl Tallowamime, Dioleate, Dilaureth-10 phosphate, Dilinoleamidopropyl dimethyl amine, Dioleth-S phosphate, DMHF, Ethoxylated fatty alcohol, Ethylcellulose, Gellan gum, Glucouis, Glyceryl behenate, Glyceryl poly methacrylate, Glyceryl stearate, Glyceryl stearate SE, Guar (Cyanopsis tetragonoloba) gum, Guar hydroxypropyltrimonium chloride, Hectorite, Hexyl alcohol, Hydrated silica, Hydrogenated rapeseed oil, Hydrogenated starch hydrolysate, Hydrogenated vegetable glycerides, Hydrolyzed oat flour, Hydrolyzed transgenic collagen, Hydroxyethylcellulose, Hydroxypropylcellulose, Hydroxypropyl chitosan, Hydroxypropyl guar, Hydroxypropyl methylcellulose, Isoceteth-10, Isostearamide DEA, Isostearamidopropylamine oxide, Jojoba wax, Karaya (Stericulia urens) gum, Lauramide DEA, Lauramidopropyl betaine, Laureth-3, Laureth-10, Lauric acid, Lauric-linoleic DEA, Lauroyl-linoleoyl diethanolamide, Lauroyl-myristoyl diethanolamide, Lauryl alcohol, Lauryl betaine, Linoleamide DEA, Linoleic acid, Linolenic acid, Lithium magnesium sodium silicate, Locust bean (Ceratonia siliqua) gum, Mannan gum, Magnesium aluminum silicate, MDM hydantoin, Methylcellulose, Montmorillonite, Myristamide DEA, Myristamide MEA, Myristamine oxide, Myristic acid, Myristyl alcohol, Octacosanyl stearate, Oleamide, Oleamide DEA, Palmitamide MEA, Paraffin, Pectin, PEG-8, PEG-80 Glyceryl tallowate, PEG-8 PPG-3 Diisostearate, PEG-200 Hydrogenated glyceryl palmate, PEG-5M, PEG-9M, PEG-23M, PEG-45M, PEG-90M, PEG-160M, PEG-6 beeswax, PEG-S beeswax, PEG-12 beeswax, PEG-150/decyl/SMDI copolymer, PEG-4 diisostearate, PEG-8 dioleate, PEG-3 distearate, PEG-4 distearate, PEG-8 distearate, PEG-150 distearate, PEG-18 glyceryl oleatelcocoate, PEG-200 glyceryl stearate, PEG-28 glyceryl tallowate, PEG-200 glyceryl tallowate, PEG-7 hydrogenated castor oil, PEG-40 jojoba oil, PEG-3 lauramide, PEG-3 laura mine oxide, PEG-2 laurate, PEG-120 methyl glucose dioleate, PEG-4 oleamide, PEG-ISO pentaerythrityl tetrastearate, PEG-55 propylene glycol oleate, PEG-4 rapeseedamine, PEG-160 sorbitan triisostearate, PEG-S stearate, PEG-75 stearate, PEG-100 stearate, PEG-150/stearyl/SMDI copolymer, PEG-50 tallow amide, Pentaerythrityl tetrabehenate, Pentaerythrityl tetrastearate, Poloxamer 105, Poloxamer 124, Poloxamer 185, Poloxamer 237, Poloxamer 238, Poloxamer 338, Poloxamer 407, Polyacrylic acid, Polyquarternium-37, Polysorbate 20, Potassium alginate, Potassium chloride, Potassium oleate, Potassium stearate, PPG-5-ceteth-10 phosphate, PPG-14 laureth-60 alkyl dicarbamate, PPG-14 palmeth-60 alkyl dicarbamate, Propylene glycol stearate, Propylene glycol stearate SE, PVMIMA decadiene crosspolymer, PVP, Quaternium-90, Bentonite, Quaternium-18 bentonite, Quaternium-18 hectorite, Rapeseed oil, ethoxylated high erucic acid, Ricinoleamide MEA, Sclerotium gum, Sesamide, DEA, Silica, Sodium acrylates/vinyl isodecanoate crosspolymer, Sodium carbomer, Sodium carrageenan, Sodium ceteth-13-carboxylate, Sodium chloride, Sodium hyaluronate, Sodium hydroxypropyl starch phosphate, Sodium isostearoamphopropionate, Sodium lauryl sulfoacetate, Sodium magnesium silicate, Sodium stearate, Sorbitan sesquiisostearate, Sorbitan tristearate, Soy amide DEA, Soyamidopropyl betaine, Starch polyacrylonitrile copolymer-potassium salt, Starch polyacrylonitrile copolymer-sodium salt, Stearalkonium bentonite, Stearalkonium hectorite, Stearamide, Stearamide, DEA, Stearamide MEA, Stearamide MEA-stearate, Stearamidopropyl dimethyl amine lactate, Stearamine oxide, Steareth-10 alkyl ether/acrylates copolymer, Stearic acid, Stearyl alcohol, Synthetic beeswax, Tallowamide MEA, TEA-acrylates/acrylonitrogens copolymer, Tragacanth (Astragalus gummifer) gum, Tribehenin, Trideceth-2 carboxamide MEA, Trihydroxystearin, Tromethamine magnesium aluminum silicate, Wheat germamide DEA, Wheat germamidopropyl betaine, Xanthan gum, and mixtures thereof.

5. The composition of claim 4, wherein the particle forming material is selected from the group consisting of jojoba esters, collagen, natural polymers and synthetic polymers and mixtures thereof.

6. The composition of claim 5, wherein the plurality of particles have a hardness of between about 80 and about 160 measured according to ASTM D 1321-92 at 25°

C. and a diameter of between about 250 μ

m to 1500 μ

m.

7. The composition of claim 1, wherein the particles additionally comprise a UV marker, and the UV marker is 2H-1-Benzopyran-2-one, 7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-2-Benzopyrone.

8. The composition of claim 5, wherein the particles comprise a UV marker, and the UV marker is 2H-1-Benzopyran-2-one, 7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-2-Benzopyrone.

9. The composition of claim 2, wherein the particles comprise a UV marker, and the UV marker is 2H-1-Benzopyran-2-one, 7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-2-Benzopyrone.

10. The composition of claim 1, wherein the particle forming material is selected from the group consisting of jojoba esters, collagen, and synthetic polymers and mixtures thereof.

11. The sanitizing composition of claim 10, wherein the antimicrobial agent different than the alcohol in the viscous liquid is selected from the group consisting of:

Allicin, Benzalkonium chloride, bacteriophages, Benzethonium chloride, Benzoic acid, Benzyl alcohol, Bromochlorophene 2-Bromo-2-nitropropane-1,3-diol, Butylparaben, Capryloyl collagen amino acids, Capryloyl glycine, Capryloyl keratin amino acids, Captan, Cetethyldimonium bromide, Cetyl pyridinium chloride, Chlorothymol, Chloroxylenol, Citral, Citron oil, Copper PCA, Dichlorobenzyl alcohol, Dilauryldimonium chloride, Domiphen bromide, Ethylparaben, Eucalyptus globulus extract, Fennel (Foeniculum vulgare) extract, Garlic (Allium sativum) extract, Gentian violet Glyceryl caprylate, Glyceryllaurate, Hexamidine diisothionate, Hexetidine, Hinokitiol, Honeysuckle (Lonicera caprifolium) extract, Honeysuckle (Lonicera japonica) extract, Leptospermum scoparium oil, Lichen (Usnea barbata) extract, Methylparaben, Myristalkonium chloride, Pentylene glycol, Pfaffia paniculata extract, Phenethyl alcohol, Phenol, Phenoxyethanol, Phenoxyisopropanol, Phenyl mercuric acetate, Phenyl mercuric benzoate, Phenyl mercuric borate, o-Phenylphenol, Phytosphingo sine, Piroctone olamine, Polymethoxy bicyclic oxazolidine, Potassium sorbate, Propylparaben, Ricinoleamodopropyltrimonium ethosulfate, Sage (Salvia officinalis) extract, Sodium benzoate, Sodium pyrithione, Sodium ricinoleate, Sodium shale oil sulfonate, Tea tree (Melaleuca alternifolia) oil, Thimerosal, Thyme (Thymus vulgaris) extract, Thymol, Triclocarban, Triclosan, Undecylenamidopropyltrimonium methosulfate, Undecylenic acid, Zinc oxide, Zinc PCA, Zinc pyrithione, Zinc undecylenate, Aluminum PCA, Ammonium iodide, Butylglucoside caprate, Caprylic/capric glycerides, Chlorhexidine, Chlorhexidine diacetate, Chlorhexidine digluconate, Chlorhexidine dihydrochloride, Chlorphenesin, alpha-Glucan-oligosaccharide, Iceland moss (Cetraria islandica) extract, Lactoferrin, Lauralkonium bromide, Lauralkonium chloride, Laurtrimonium chloride, Laurylpyridinium chloride, Leptospermum scoparium oil, Mushroom (Cordyceps sabolifera) extract, Orange (Citrus aurantium dulcis) peel extract, Orange (Citrus sinensis) flower extract, PEG-42 ebiriko ceramides extract, Peppermint (Mentha piperita) extract, Philodendron (Phellodendron amurense) extract, Pine (Pinus sylvestris) needle extract, Polymethoxy bicyclic oxazolidine, Quaternium 73, Rubus thunbergii extract, Sodium shale oil sulfonate, Sodium usnate, Undecylenic acid, Zinc PCA, docosanol, eicosanol and mixtures thereof.

12. The composition of claim 10, wherein the particles comprise a UV marker, and the UV marker is 2H-1-Benzopyran-2-one, 7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-2-Benzopyrone.

13. A method of preparing a sanitizing composition, the method comprising:

providing a viscous liquid or gel comprising about 55% to about 80% by weight alcohol, water and a thickener; and

adding a plurality of essentially homogeneous particles to the viscous liquid or gel, wherein the plurality of essentially homogeneous particles comprise a particle-forming material and an antimicrobial agent different than the alcohol in the viscous liquid; and

wherein the plurality of particles are adapted to abrade away completely when rubbed.

14. The method of claim 13, wherein at least some of the plurality of particles additionally comprise at least one of an emollient, a moisturizer, and an ultraviolet (UV) marker.

15. The method of claim 13, wherein at least some of the plurality of particles additionally comprise 2H-1-Benzopyran-2-one, 7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-2-Benzopyrone.

16. The method of claim 13, wherein the particle forming material is selected from the group consisting of jojoba esters, collagen, natural polymers and synthetic polymers and mixtures thereof.

17. A sanitizing composition comprising:

a viscous liquid comprising alcohol, water, and a thickener; and

a plurality of essentially homogeneous particles comprising an ultraviolet (UV) marker;

wherein the alcohol is present in a range between about 30% to about 95% by weight; and

wherein the plurality of particles are adapted to abrade away completely when rubbed.

18. The sanitizing composition of claim 17, wherein the plurality of particles comprises a material selected from the group consisting of jojoba esters, collagen, natural polymers and synthetic polymers and mixtures thereof;

and wherein the UV marker is 2H-1-Benzopyran-2-one, 7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-7-(2H-Naphtho[1,2-d]Triazol-2-yl)-3-Phenyl-2-Benzopyrone.