Oxygen sensors

• US 8,845,871 B2
• Filed: 06/21/2012
• Issued: 09/30/2014
• Est. Priority Date: 11/01/2006
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Chapples, John, Tillotson, John Anthony, McLeod, Ian, Williamson, Martin
• Primary Examiner(s): LEONG, SUSAN DANG
• Application Number:
  US13/529,568
• Publication Number:
  US 20120285828A1
• Time in Patent Office: 831 Days
• Field of Search: 204/400, 204/415, 204408-409, 204418-419, 204/424, 204/432, 205/775, 205/782.5, 205783-7855
• US Class Current: 204/408
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

An electrochemical oxygen sensor includes a micro-porous plastic membrane supported on a sealing disk and located between a gas inflow port and the sensor'"'"'s electrolyte. The membrane and disk minimize thermal shock effects due to using the sensor at a first location, at a first temperature, and then moving it to a second location at a different temperature.

Claims

1. An electrochemical gas sensor comprising:

a housing with an open end;

a partition carried on the open end with the partition including at least a rigid support member that carries a selected membrane, the support member is sandwiched between the membrane and the open end of the housing, and the support member is sealed to the open end of the housing with an air tight seal;

a cap which carries an electrode, the cap is sealed to the housing adjacent to the open end; and

a current collector which extends from within the housing, through the seal between the end of the housing and the support member and into a region between the electrode carried by the cap and the membrane wherein the membrane further comprises liquid held in the pores of the membrane, the pores having a diameter that requires a predetermined minimum pressure to force the liquid out of the pores and before gas is able to cross the membrane, the minimum pressure exceeding that created by environmental temperature changes thereby preventing the bulk transport of gas across the membrane and eliminating temperature transient effect.

2. An electrochemical gas sensor as in claim 1 which includes sensing and counter electrodes.

3. An electrochemical gas sensor as in claim 1 where the membrane is positioned in the sensor between a counter electrode and a gas inflow port.

4. An electrochemical gas sensor as in claim 3 which includes a compressible gasket which carries the membrane.

5. An electrochemical gas sensor as in claim 1 which includes a compressible foam adhesive gasket which carries the membrane, the gasket forms another air tight seal.

6. An electrochemical gas sensor as in claim 1 where the support member defines at least one opening therethrough.

7. An electrochemical gas sensor as in claim 6 which includes a compressible gasket which carries the membrane, the gasket overlays the support member, and, the gasket reduces the amount of free volume in a region between the support member and the cap.

8. An electrochemical gas sensor as in claim 7 where the cap has a gas inflow port, the cap being adjacent to the membrane, the support member being adjacent to an internal region of the housing and to an electrode.

9. An electrochemical gas sensor as in claim 7 where the gasket includes adhesive surfaces which provide another air tight seal between the support member and the membrane.

10. An electrochemical gas sensor as in claim 9 where electrolyte is adjacent to the support member and located within the housing.

11. An electrochemical gas sensor as in claim 10 where the support member is one of perforated, or, permeable to the electrolyte.

12. A gas sensor which comprises a housing having first and second chambers;

the housing carrying at least sensing and counter electrodes;

a body of electrolyte in contact with at least one of the electrodes;

the housing defining a gas inflow port;

a planar membrane located within an interior of the housing, closing the interior of the housing between the first and second chambers, to regulate an inflow of ambient gas, the membrane allowing electrolyte to pass therethrough and preventing an exchange of air between the first and second chambers, the membrane holding liquid in the pores thereof by surface tension and capillary action;

an air tight seal between one of the chambers and a rigid support member that underlies the membrane, and a second air tight seal between at least portions of the membrane and the rigid support member wherein the pores have a diameter that requires a predetermined minimum pressure to force the liquid out of the pores and before gas is able to cross the membrane, the minimum pressure exceeding that created by environmental temperature changes thereby preventing the bulk transport of gas across the membrane and eliminating temperature transient effect.

13. A gas sensor as in claim 12 which includes a gasket, where the gasket carries the membrane and implements the second air tight seal, at least in part.

14. A gas sensor as in claim 13 which includes a current collector which extends between both chambers of the housing, through a portion of the air tight seal, wherein the seal is formed by welding the support member to the housing.

15. An oxygen sensor as in claim 14 where a portion of the current collector extends into a region adjacent to the membrane.

16. A gas sensor as in claim 13 where the gasket comprises an adhesive, compressible gasket which implements the second air tight seal.

17. An oxygen sensor as in claim 16 where the support member comprises one of an annular disk, a disk exhibiting a plurality of spaced apart openings therethrough, or an electrolyte permeable disk.

18. An electrochemical gas sensor comprising a housing with a gas inflow port, the housing carries at least one electrode and which includes an inwardly extending, at least partly annular support surface for a support element, a gasket and a membrane where the gasket is located between the at least one electrode and the support element, and the gasket provides at least in part an air tight seal between the membrane and the support element;

and at least one filter element between the support element and the at least partly annular support surface wherein the membrane further comprises liquid held in the pores of the membrane, the pores having a diameter that requires a predetermined minimum pressure to force the liquid out of the pores and before gas is able to cross the membrane, the minimum pressure exceeding that created by environmental temperature changes thereby preventing the bulk transport of gas across the membrane and eliminating temperature transient effect.

19. An electrochemical gas sensor as in claim 18 which includes a second air tight seal between the support element and the at least partly annular support surface.

20. An electrochemical gas sensor as in claim 19 which includes a current collector which extends in the housing, through a portion of the air tight seal, wherein the seal is formed by welding the support element to the housing.