Small scale microencapsulated pigments and uses thereof

• US 8,883,049 B2
• Filed: 03/15/2013
• Issued: 11/11/2014
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: ChromaticTechnologies lncoporated
• Original Assignee: ChromaticTechnologies lncoporated
• Inventors: Clayton, Terrill Scott, Owen, Timothy J., Small, Lyle
• Primary Examiner(s): Ahvazi, Bijan
• Application Number:
  US13/843,492
• Publication Number:
  US 20140272161A1
• Time in Patent Office: 606 Days
• Field of Search: 106/31.32, 106/31.33, 106/31.64, 106/31.65, 106/31.13, 220/626, 427/401, 428/34.1, 523/400, 523/427, 524/300, 524/556, 524/560, 524/590, 524/599, 252/586
• US Class Current: 252/586
• CPC Class Codes: B01J 13/14 Polymerisation; cross-linking
• CPC Class Codes: B01J 13/18 In situ polymerisation with all reactants being present in the same phase
• CPC Class Codes: B41M 5/287 using microcapsules or microspheres only
• CPC Class Codes: C09B 67/0013 with polymeric coatings
• CPC Class Codes: C09B 67/0084 Dispersions of dyes
• CPC Class Codes: C09B 67/0097 Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
• CPC Class Codes: C09D 11/30 Inkjet printing inks
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09D 5/26 Thermosensitive paints

Abstract

A method is provided for making thermochromic pigments in microcapsules having unusually small particle sizes.

Claims

1. A microcapsule-based pigment comprising microcapsules having a mean by volume particle size diameter of less than 1 micron, the microcapsules having a wall made of a cured amine formaldehyde resin with the wall encapsulating an internal phase including a thermochromic system;

the microcapsule-based pigment being in a reacted form produced from a water-based slurry utilizing

(1) an aqueous phase solution constituting from 40% to 70% of the slurry by weight, wherein from 1% to 10% of the aqueous phase solution is an anionic surfactant material;

(2) an internal phase mixture constituting from 23% to 35% of the slurry by weight, wherein from 1% to 10% by weight of the internal phase is a leuco dye and from 5% to 30% is a developer for the leuco dye; and

(3) an amine formaldehyde resin solution constituting from 15% to 28% of the slurry by weight of which from 40% to 60% is the amine formaldehyde resin itself;

the anionic surfactant as an emulsifier being present in an effective amount to achieve the mean by volume particle size diameter of less than one micron in a water-based emulsion, and a chemical dewatering agent in an effective amount to facilitate dewatering of the microcapsules with the anionic surfactant in place;

a microencapsulated pigment being in a dewatered state of reduced moisture made ready for industrial use facilitated by addition of the chemical dewatering agent the anionic surfactant and the chemical dewatering agent being present in the pigment.

2. The pigment of claim 1, wherein ninety percent of all microcapsules in the pigment have an average particle diameter of less than 1.5 microns.

3. The pigment of claim 1, wherein ninety percent of all microcapsules in the pigment have an average particle diameter of less than 1.0 microns.

4. An ink comprising the pigment of claim 1, dispersed in an ink vehicle.

5. The ink of claim 4, wherein the ink is formulated as an inkjet ink.

6. A coating comprising the pigment of claim 1, dispersed in a coating vehicle.

7. The coating of claim 6, wherein the coating is formulated as a metal decoration coating.

8. The pigment of claim 1, wherein the thermochromic system achieves a blue color when in a color-activated state.

9. The pigment of claim 1, wherein ninety percent of all microcapsules in the pigment have an average particle diameter of less than 1.5 microns.

10. The coating of claim 9, wherein the coating is formulated as a metal decoration coating.

11. The pigment of claim 1, wherein ninety percent of all microcapsules in the pigment have an average particle diameter of less than 1.0 microns.

12. An ink comprising the pigment of claim 8 dispersed in an ink vehicle.

13. A coating comprising the pigment of claim 8 dispersed in a coating vehicle.

14. The pigment of claim 1, wherein the thermochromic system achieves a green color when in a color-activated state.

15. The pigment of claim 1, wherein the thermochromic system achieves a yellow color when in a color-activated state.

16. The pigment of claim 1, wherein the thermochromic system achieves a cyan color when in a color-activated state.

17. The ink of claim 16, wherein the ink is formulated as an inkjet ink.

18. The pigment of claim 1, wherein the microcapsules have a wall made of a cured amine formaldehyde resin, and the wall encapsulates an internal phase including a photochromic material.

19. The pigment of claim 1, wherein the emulsifier is selected from the group consisting of polystyrenesulfonate, styrene copolymers, polyvinylsulfonatester salts, polyvinylsulfonates, maleic anhydridestyrene copolymer, maleic anhydride-isobutylene copolymer, maleic anhydride-ethylene copolymer, maleic anhydride-methyl vinyl ether copolymer, polyvinyl alcohol (saponified product), carboxymethyl-modified polyvinyl alcohol, gum arabic, polyacrylates, polyacrylate derivatives, acrylate copolymers, carboxymethyl cellulose, gelatin, pectin, pullulan, phtahalated gelatin, succinated gelatin, cellulose sulfate ester salt, and alginic acid.

20. The pigment of claim 1, wherein the emulsifier includes ethylene maleic anhydride.

21. The pigment of claim 1 containing from 5% to 35% moisture.