Methods and devices for optically determining a characteristic of a substance

• US 8,941,046 B2
• Filed: 04/26/2012
• Issued: 01/27/2015
• Est. Priority Date: 04/26/2012
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Freese, Robert, Jones, Christopher Michael, Perkins, David, Simcock, Michael, Soltmann, William
• Primary Examiner(s): Ko, Tony
• Application Number:
  US13/456,350
• Publication Number:
  US 20130284899A1
• Time in Patent Office: 1,006 Days
• Field of Search: 250/208.2, 356/51, 356/300, 356/303, 356/417, 356/318
• US Class Current: 250/208.2
• CPC Class Codes: G01J 2003/1226 Interference filters
• CPC Class Codes: G01N 2021/3137 with selection of wavelengths after the sample
• CPC Class Codes: G01N 2021/3174 Filter wheel
• CPC Class Codes: G01N 21/17 Systems in which incident light is modified in accordance with the properties of the material investigated where the material investigated is optically excited causing a change in wavelength of the incident light G01N21/63
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/31 Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry G01N21/72 takes precedence
• CPC Class Codes: G06E 3/001 Analogue devices in which mathematical operations are carried out with the aid of optical or electro-optical elements optical elements per se G02B; devices consisting of a plurality of solid state components, including light sensitive semiconductor components, formed in or on a common substrate H01L27/14; electro-, magneto- or acousto-optics, non-linear optics G02F1/00; graph reading G06K11/00

Abstract

Optical computing devices are disclosed. One exemplary optical computing device includes an electromagnetic radiation source configured to optically interact with a sample and first and second integrated computational elements arranged in primary and reference channels, respectively. The first and second integrated computational elements produce first and second modified electromagnetic radiations, and a detector is arranged to receive the first and second modified electromagnetic radiations and generate an output signal corresponding to the characteristic of the sample.

Claims

1. A device, comprising:

an electromagnetic radiation source configured to optically interact with a sample having a characteristic of interest;

a first integrated computational element arranged within a primary channel and configured to optically interact with the electromagnetic radiation source and produce a first modified electromagnetic radiation;

a second integrated computational element arranged within a reference channel and configured to optically interact with the electromagnetic radiation source and produce a second modified electromagnetic radiation; and

a first detector arranged to generate a first signal from the first modified electromagnetic radiation, to generate a compensating signal from the second modified electromagnetic radiation, the compensating signal indicative of a radiating deviation in the primary channel, and to generate an output signal corresponding to the characteristic of the sample.

2. The device of claim 1, wherein the first detector is a split detector comprising a first detector portion arranged in the primary channel to receive the first modified electromagnetic radiation and a second detector portion arranged in the reference channel to receive the second modified electromagnetic radiation.

3. The device of claim 2, wherein the split detector computationally combines the first and second modified electromagnetic radiations to determine the characteristic of the sample.

4. The device of claim 2, wherein the output signal comprises a first output signal generated by the first detector portion and a second output signal generated by the second detector portion, the first and second output signals being transmitted to and received by a signal processor configured to computationally combine the first and second output signals to determine the characteristic of the sample.

5. The device of claim 1, further comprising a second detector arranged in a second reference channel and configured to detect electromagnetic radiating deviations stemming from the electromagnetic radiation source.

6. The device of claim 1, further comprising a signal processor communicably coupled to the first detector, the signal processor being configured to receive and computationally combine the output signal and the compensation signal to normalize the output signal.

7. The device of claim 1, wherein the first and second integrated computational elements are coupled together to form a monolithic structure.

8. The device of claim 1, wherein the first and second computational elements are arranged in series.

9. The device of claim 1, wherein the first and second integrated computational elements are arranged parallel relative to the other.

10. The device of claim 1, wherein the first and second integrated computational elements are configured to be associated with the characteristic of the sample.

11. The device of claim 1, wherein at least one of the first and second integrated computational elements is configured to be disassociated with the characteristic of the sample.

12. The device of claim 1, further comprising a movable assembly configured for rotation, the first and second integrated computational elements being radially disposed within the movable assembly for rotation therewith,

wherein the primary channel is generated as the first integrated computational element aligns with the electromagnetic radiation source and the first detector, and the reference channel is generated as the second integrated computational element aligns with the electromagnetic radiation source and the first detector.

13. The device of claim 1, wherein the first and second integrated computational elements are laterally arranged upon a movable assembly such that the first and second integrated computational elements optically interact with electromagnetic radiation individually,

wherein the primary channel is generated as the first integrated computational element aligns with the electromagnetic radiation source and the first detector, and the reference channel is generated as the second integrated computational element aligns with the electromagnetic radiation source and the first detector.

14. The device of claim 13, wherein the movable assembly is configured for lateral or vertical oscillation.

15. A device, comprising:

an electromagnetic radiation source configured to optically interact with a sample having a characteristic of interest;

a first integrated computational element arranged within a primary channel and configured to optically interact with the electromagnetic radiation source and produce a first modified electromagnetic radiation;

a second integrated computational element arranged within a second channel and configured to optically interact with the electromagnetic radiation source and produce a second modified electromagnetic radiation;

a first detector arranged to receive the first modified electromagnetic radiation and generate a first output signal;

a second detector arranged to receive the second modified electromagnetic radiation and generate a second output signal; and

a signal processor configured to receive and computationally combine the first and second output signals to determine the characteristic of interest of the sample, wherein the second output signal is a compensating signal indicative of a radiating deviation in the primary channel.

16. The device of claim 15, further comprising a beam splitter configured to produce a first beam of light directed toward the first integrated computational element and a second beam of light directed toward the second integrated computational element.

17. The device of claim 15, wherein the second detector is arranged in a second reference channel and is further configured to detect electromagnetic radiating deviations from the electromagnetic radiation source.

18. The device of claim 15, wherein the signal processor is configured to receive and computationally combine the output signal and the compensation signal to normalize the output signal.

19. The device of claim 15, wherein the first and second integrated computational elements are coupled together to form a monolithic structure.

20. The device of claim 15, wherein the first and second computational elements are arranged in series.

21. The device of claim 15, wherein the first and second integrated computational elements are arranged parallel relative to the other.

22. The device of claim 15, wherein the first and second integrated computational elements are configured to be associated with the characteristic of the sample.

23. The device of claim 15, wherein at least one of the first and second integrated computational elements is configured to be disassociated with the characteristic of the sample.