Well completion methods using gellable treatment fluids having long term thermal stability of the gelled state

• US 8,955,587 B2
• Filed: 11/16/2011
• Issued: 02/17/2015
• Est. Priority Date: 11/16/2011
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Sherman, John Walter, Funkhouser, Gary P., Deville, Jay Paul
• Primary Examiner(s): Bates, Zakiya W
• Assistant Examiner(s): RUNYAN, SILVANA C
• Application Number:
  US13/297,663
• Publication Number:
  US 20130118740A1
• Time in Patent Office: 1,189 Days
• Field of Search: 166/279, 166/308.1, 166/308.2, 166/308.6
• US Class Current: 166/279
• CPC Class Codes: C09K 8/5083 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09K 8/512 containing cross-linking agents
• CPC Class Codes: C09K 8/685 containing cross-linking agents
• CPC Class Codes: C09K 8/887 containing cross-linking agents

Abstract

Gellable treatment fluids containing a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid monomer units can be used in various subterranean operations where it is necessary for the treatment fluid to remain in a gelled state for extended periods of time at high formation temperatures. Methods for treating a subterranean formation can comprise providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a gel stabilizer, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof; introducing the treatment fluid into a subterranean formation; allowing the treatment fluid to form a gel in the subterranean formation; and breaking the gel after it has been in the subterranean formation for at least about one day.

Claims

1. A method comprising:

providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a gel stabilizer for a crosslinked gel, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof;

wherein the gel stabilizer comprises a hydroxylamine;

introducing the treatment fluid into a subterranean formation;

allowing the treatment fluid to form a gel in the subterranean formation, the gel comprising a crosslinked gel formed from a reaction between the terpolymer and the crosslinking agent; and

breaking the gel after it has been in the subterranean formation for at least about one day.

2. The method of claim 1, wherein the subterranean formation is at a temperature ranging between about 275°

F. and about 350°

F.

3. The method of claim 1, wherein the treatment fluid further comprises a gellation accelerator that decreases a time required to form the gel.

4. The method of claim 1, wherein the gel stabilizer further comprises an antioxidant selected from the group consisting of a sulfite salt, erythorbic acid, ascorbic acid, a hydroquinone, any salt thereof, any derivative thereof, and any combination thereof.

5. The method of claim 1, wherein the crosslinked gel does not under in situ stress within the subterranean formation.

6. The method of claim 1, wherein a concentration ratio of the terpolymer to the crosslinking agent ranges between about 1:

1 and about 6;

1.

7. A method comprising:

providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a gel stabilizer for a crosslinked gel, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof;

wherein the gel stabilizer comprises a hydroxylamine;

introducing the treatment fluid into a subterranean formation; and

allowing the treatment fluid to form a crosslinked gel in the subterranean formation, the crosslinked gel being formed from a reaction between the terpolymer and the crosslinking agent and the crosslinked gel not flowing under in situ stress within the subterranean formation.

8. The method of claim 7, wherein the crosslinked gel at least partially blocks the flow of formation fluids in at least a portion of the subterranean formation.

9. The method of claim 7, further comprising:

breaking the crosslinked gel after it has been in the subterranean formation for at least about one day.

10. The method of claim 7, wherein the subterranean formation is at a temperature ranging between about 275°

F. and about 350°

F.

11. The method of claim 7, wherein the treatment fluid has a pH ranging between about 4.2 and about 4.8.

12. The method of claim 7, wherein a concentration ratio of the terpolymer to the crosslinking agent ranges between about 1:

1 and about 6;

1.

13. The method of claim 7, wherein the gel stabilizer further comprises an antioxidant selected from the group consisting of a sulfite salt, erythorbic acid, ascorbic acid, a hydroquinone, any salt thereof, any derivative thereof, and any combination thereof.

14. A method comprising:

providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a gel stabilizer for a crosslinked gel, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof;

wherein the gel stabilizer comprises a hydroxylamine;

introducing the treatment fluid into a subterranean formation;

allowing the treatment fluid to form a gel in the subterranean formation that at least partially blocks the flow of formation fluids in at least a portion of the subterranean formation, the gel comprising a crosslinked gel formed from a reaction between the terpolymer and the crosslinking agent; and

breaking the gel after it has been in the subterranean formation for at least about one day.

15. The method of claim 14, wherein the subterranean formation is at a temperature ranging between about 275°

F. and about 350°

F.

16. The method of claim 14, wherein a concentration ratio of the terpolymer to the crosslinking agent ranges between about 1:

1 and about 6;

1.

17. The method of claim 14, wherein the gel stabilizer further comprises an antioxidant selected from the group consisting of erythorbic acid, ascorbic acid, any salt thereof, any derivative thereof, and any combination thereof.

18. The method of claim 14, wherein the crosslinked gel does not flow under in situ stress within the subterranean formation.