Modified rubber compositions and methods of preparation

• US 8,969,450 B2
• Filed: 12/01/2010
• Issued: 03/03/2015
• Est. Priority Date: 12/01/2009
• Status: Active Grant

• Current Assignee: Bridgestone Corporation
• Original Assignee: Bridgestone Corporation
• Inventors: Wang, Xiaorong, Foltz, Victor J., Kelley, Edward D.
• Primary Examiner(s): NERANGIS, VICKEY M
• Application Number:
  US13/513,213
• Publication Number:
  US 20120302665A1
• Time in Patent Office: 1,553 Days
• Field of Search: 524/17, 524/217, 524/285, 524/325
• US Class Current: 524/217
• CPC Class Codes: B60C 1/0016 Compositions of the tread
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 5/05 Alcohols; Metal alcoholates
• CPC Class Codes: C08K 5/101 of monocarboxylic acids
• CPC Class Codes: C08K 5/20 Carboxylic acid amides
• CPC Class Codes: C08K 5/548 containing sulfur C08K5/5477 takes precedence
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 89/00 Compositions of proteins; Compositions of derivatives thereof foodstuff preparations A23J3/00
• CPC Class Codes: C08L 9/06 Copolymers with styrene

Abstract

Modified rubber compositions containing an elastomer component and a modifier comprising a steroid and/or a peptide and methods of their production. Such modified rubber compositions can have improved properties and can be useful in making various articles of manufacture, such as, for example, in the manufacture of tires.

Claims

1. A tire comprising a rubber composition comprising:

an elastomer component and a modifier comprising a steroid, wherein said tire comprises said rubber composition in an amount of at least 0.1 weight percent based on the entire weight of said tire.

2. The tire of claim 1, wherein said steroid is selected from the group consisting of cholestanes, cholanes, pregnanes, androstanes, estranes, derivatives thereof, and mixtures of two or more thereof.

3. The tire of claim 1, wherein said steroid comprises cholesterol, a derivative of cholesterol, or mixtures thereof.

4. The tire of claim 1, wherein said steroid comprises an ester derivative of cholesterol selected from the group consisting of cholesteryl formate, cholesteryl acetate, cholesteryl propionate, cholesteryl butyrate, cholesteryl benzoate, cholesteryl laurate, cholesteryl caprylate, cholesteryl chloroformate, and mixtures of two or more thereof.

5. The tire of claim 1, wherein said steroid comprises a halogenated derivative of cholesterol selected from the group consisting of cholesteryl bromide, cholesteryl chloride, cholesteryl iodide, and mixtures of two or more thereof.

6. The tire of claim 1, wherein said steroid comprises cholesterol.

7. The tire of claim 1, wherein said rubber composition comprises said modifier in an amount of at least 5 weight percent based on the weight of said elastomer component in said rubber composition.

8. The tire of claim 1, wherein said elastomer component is selected from the group consisting of natural rubber, synthetic polyisoprene, styrene-butadiene rubber, butyl rubber, halogenated butyl rubber, polybutadiene, nitrile rubber, hydrogenated nitrile rubber, chloroprene rubber, polyurethane, ethylene propylene diene rubber, derivatives thereof, and mixtures of two or more thereof.

9. The tire of claim 1, wherein said elastomer component comprises styrene-butadiene rubber.

10. The tire of claim 1, wherein said rubber composition comprises said elastomer component in an amount of at least 10 weight percent based on the entire weight of said rubber composition.

11. The tire of claim 1, wherein said tire comprises said rubber composition in an amount of at least 10 weight percent based on the entire weight of said tire.

12. The tire of claim 1, wherein said rubber composition further comprises one or more additives selected from the group consisting of silica fillers, carbon blacks, aromatic oils, waxes, stearic acid, antioxidants, silane coupling agents, sulfur, zinc oxide, retarding agents, and accelerating agents.

13. The tire of claim 1, wherein said tire comprises a tread member, wherein at least a portion of said rubber composition is located in said tread member.

14. The tire of claim 13, wherein said tread member comprises said rubber composition in an amount of at least 50 weight percent based on the weight of said tread member.

15. The tire of claim 1, wherein said rubber composition has a ring-tensile strength at 23°

C. (M50) of at least 1.3 under the conditions provided for in ASTM D412 using a ring-shaped sample having a width of 0.05 inches and a thickness of 0.075 inches, wherein said rubber composition exhibits a Lambourn index value of at least 105 at a 65% slip ratio as compared to an un-modified rubber sample otherwise having the same composition but having an equivalent amount of aromatic oil in place of the absent modifier and providing a relative standard Lambourn index value of 100, wherein said rubber composition has a wet traction of at least 62 as measured on a British Portable Skid Tester with a sample size of 2.54×

7.62×

0.64 cm.

16. A method of making a tire, said method comprising:

(a) preparing a rubber composition comprising an elastomer component and a modifier comprising a steroid;

(b) introducing at least a portion of said rubber composition into a tire mold; and

(c) subjecting said rubber composition in said tire mold to one or more curing conditions to thereby form said tire.

17. The method of claim 16, wherein said preparing of step (a) comprises the steps of:

(i) subjecting said elastomer component and a silica filler to an initial mixing stage to thereby form an initial mixture;

(ii.) combining and mixing said steroid with said initial mixture following said initial mixing stage to thereby form an intermediate mixture; and

(iii) combining and mixing one or more curing additives with said intermediate mixture to thereby form said rubber composition.

18. The method of claim 17, wherein step (i) further comprises combining one or more additional components with said elastomer component and said silica filler, wherein said additional components are selected from the group consisting of aromatic oils, waxes, stearic acid, antioxidants, coupling agents, and mixtures of two or more thereof.

19. The method of claim 17, wherein said curing additives of step (iii) are selected from the group consisting of sulfur, zinc oxide, retarding agents, accelerating agents, and mixtures of two or more thereof.

20. The method of claim 16, wherein said rubber composition is introduced into said tire mold in step (b) as at least a portion of a green tire.

21. The method of claim 20, wherein said green tire comprises one or more components selected from the group consisting of a tread member, an inner lining, sidewalls, body plies, and/or a belt package.

22. The method of claim 21, wherein said green tire comprises said tread member, wherein said tread member comprises at least a portion of said rubber composition.

23. The method of claim 16, wherein said steroid comprises cholesterol, a derivative of cholesterol, or mixtures thereof.

24. The method of claim 16, wherein said elastomer component is selected from the group consisting of natural rubber, synthetic polyisoprene, styrene-butadiene rubber, butyl rubber, halogenated butyl rubber, polybutadiene, nitrile rubber, hydrogenated nitrile rubber, chloroprene rubber, polyurethane, ethylene propylene diene rubber, derivatives thereof, and mixtures of two or more thereof.

25. The method of claim 16, wherein said rubber composition further comprises one or more additives selected from the group consisting of silica fillers, carbon black, aromatic oils, waxes, stearic acid, antioxidants, silane coupling agents, sulfur, zinc oxide, retarding agents, and accelerating agents.

26. The method of claim 16, wherein said rubber composition has a ring-tensile strength at 23°

C. (M50) of at least 1.3 under the conditions provided for in ASTM-D 412 using a ring-shaped sample having a width of 0.05 inches and a thickness of 0.075 inches, wherein said rubber composition exhibits a Lambourn index value of at least 105 at a 65% slip ratio as compared to an un-modified rubber sample otherwise having the same composition but having an equivalent amount of aromatic oil in place of the absent modifier and providing a relative standard Lambourn index value of 100, wherein said rubber composition has a wet traction of at least 62 as measured on a British Portable Skid Tester with a sample size of 2.54×

7.62×

0.64 cm.