Pesticidal compositions

• US 9,006,446 B2
• Filed: 11/14/2012
• Issued: 04/14/2015
• Est. Priority Date: 05/05/2009
• Status: Expired due to Fees

• Current Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Trullinger, Tony K., Hunter, Ricky, Garizi, Negar, Yap, Maurice C. H., Buysse, Ann M., Pernich, Dan, Johnson, Timothy C., Bryan, Kristy, Deamicis, Carl, Zhang, Yu, Niyaz, Noormohamed M., McLeod, CaSandra Lee, Ross, Ronald Jr., Zhu, Yuanming, Johnson, Peter Lee, Eckelbarger, Joseph D., Parker, Marshall H.
• Primary Examiner(s): Grazier, Nyeemah A
• Application Number:
  US13/676,746
• Publication Number:
  US 20130072382A1
• Time in Patent Office: 881 Days
• Field of Search: None
• US Class Current: 546/270.4
• CPC Class Codes: A01N 43/40 six-membered rings
• CPC Class Codes: A01N 43/78 1,3-Thiazoles; Hydrogenated 1,3-thiazoles
• CPC Class Codes: C07D 417/04 directly linked by a ring-member-to-ring-member bond
• CPC Class Codes: C07D 417/14 containing three or more hetero rings

Abstract

This document discloses molecules having the following formula (“Formula I”):

Claims

1. A molecule having the following formula (“

Formula I”

), and isotopes and stereoisomers thereof;

4. A molecule according to claim 1 or 2 wherein said molecule having a formula according to Formula I is further in the form of a pesticidally acceptable acid addition salt, salt derivative, or solvate.

5. A molecule according to claim 1 or 2 wherein said molecule having a formula according to Formula I has at least one H that is a ²H.

6. A molecule according to claim 1 or 2 wherein said molecule having a formula according to Formula I has at least one C that is a ¹⁴C.

7. A molecule according to claim 1 or 2 wherein said molecule having a formula according to Formula I is a resolved stereoisomer.

8. A composition comprising a molecule according to claim 1 or 2 or 3 and at least one member of an Insecticide Group, Acaricide Group, Nematicide Group, Fungicide Group, or Herbicide Group.

9. A composition comprising a molecule according to claim 1 or 2 or 3 and at least one biopesticide.

10. A composition comprising a molecule according to claims 1 or 2 or 3 and at least one of the following compounds:

(a) 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;

(b) 3-(4′

-chloro-2,4-dimethyl[1,1′

-biphenyl]-3-yl)-4-hydroxy-8-oxa-1-azaspirol[4,5]dec-3-en-2-one;

(c) 4-[[(6-chloro-3-pyridinyl)methyl]methylamino]-2(5H)-furanone;

(d) 4-[[(6-chloro-3-pyridinyl)methyl]cyclopropylamino]-2(5H)-furanone;

(e) 3-chloro-N2-[(1S)-1-methyl-2-(methylsulfonyl)ethyl]-N1-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-1,2-benzenedicarboxamide;

(f) 2-cyano-N-ethyl-4-fluoro-3-methoxy-benenesulfonamide;

(g) 2-cyano-N-ethyl-3-methoxy-benzene sulfonamide;

(h) 2-cyano-3-difluoromethoxy-N-ethyl-4-fluoro-benzene sulfonamide;

(i) 2-cyano-3-fluoromethoxy-N-ethyl-benzenesulfonamide;

(j) 2-cyano-6-fluoro-3-methoxy-N,N-dimethyl-benzenesulfonamide;

(k) 2-cyano-N-ethyl-6-fluoro-3-methoxy-N-methyl-benzenesulfonamide;

(l) 2-cyano-3-difluoromethoxy-N,N-dimethylbenzenesulfon-amide;

(m) 3-(difluoromethyl)-N-[2-(3,3-dimethylbutyl)phenyl]-1-methyl-1H-pyrazole-4-carboxamide;

(n) N-ethyl-2,2-dimethylpropionamide-2-(2,6-dichloro-α

,α

,α

-trifluoro-p-tolyl) hydrazone;

(o) N-ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro-α

,α

,α

-trifluoro-p-tolyl) hydrazone nicotine;

(p) O-{(E-)-[2-(4-chloro-phenyl)-2-cyano-1-(2-trifluoromethylphenyl)-vinyl]} S-methyl thiocarbonate;

(q) (E)-N-1-[(2-chloro-1,3-thiazol-5-ylmethyl)]-N2-cyano-N1-methylacetamidine;

(r) 1-(6-chloropyridin-3-ylmethyl)-7-methyl-8-nitro-1,2,3,5,6,7-hexahydro-imidazo[1,2-a]pyridin-5-ol;

(s) 4-[4-chlorophenyl-(2-butylidine-hydrazono)methyl)]phenyl mesylate;

or

(t) N-Ethyl-2,2-dichloro-1-methylcyclopropanecarboxamide-2-(2,6-dichloro-alpha,alpha,alpha-trifluoro-p-tolyl)hydrazone.

2. A molecule having the following formula (“

Formula I”

), and isotopes and steroisomers thereof;

3. A molecule according to claim 2 and isotopes and steroisomers thereof, wherein

(a) X is CR8;

(b) R1 is H;

(c) R2 is H;

(d) R3 is H;

(e) R4 is Cl or CH₃;

(f) R5 is H or unsubstituted C₁-C₆ alkyl;

(g) R6 is O;

(h) R7 is (unsubstituted C₁-C₆ alkyl)S(O)_n(unsubstituted C₁-C₆ alkyl), (unsubstituted C₁-C₆ alkyl)S(O)_n(unsubstituted C₁-C₆ alkenyl), O(unsubstituted C₁-C₆ alkyl), or (C₁-C₆ alkyl);

(i) R8 is H or F; and

(k) n is 0, 1, or 2.