Method for producing a porous particle composite for an electrical insulating paper

• US 9,017,810 B2
• Filed: 04/11/2012
• Issued: 04/28/2015
• Est. Priority Date: 05/05/2011
• Status: Active Grant

• Current Assignee: Siemens AG
• Original Assignee: Siemens AG
• Inventors: Eder, Florian, Grppel, Peter, Lang, Steffen, Grbel, Vicky
• Primary Examiner(s): BOYLE, KARA BRADY
• Application Number:
  US14/114,953
• Publication Number:
  US 20140060386A1
• Time in Patent Office: 1,112 Days
• Field of Search: 156/53, 106/409, 428/304.4, 428/328, 428/323
• US Class Current: 428/328
• CPC Class Codes: C01P 2004/20 extending in two dimensions, e.g. plate-like
• CPC Class Codes: C01P 2004/22 with a polygonal circumferential shape
• CPC Class Codes: C09C 1/407 Aluminium oxides or hydroxides
• CPC Class Codes: C09C 3/12 Treatment with organosilicon compounds C09C3/006 takes precedence
• CPC Class Codes: D21H 13/36 Inorganic fibres or flakes
• CPC Class Codes: D21H 15/02 characterised by configuration
• CPC Class Codes: D21H 21/14 characterised by function or properties in or on the paper D21H19/66, D21H27/02 take precedence
• CPC Class Codes: H01B 3/10 metallic oxides ceramics H01B3/12
• CPC Class Codes: H01B 3/18 mainly consisting of organic substances organic macromolecular compounds or compositions C08
• CPC Class Codes: H01B 3/44 vinyl resins; acrylic resins silicones H01B3/46
• CPC Class Codes: H01B 3/46 silicones
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof

Abstract

A method is provided for producing an electrical insulation paper having a particle composite. The method involves mixing a dispersion of particles in platelet form, a carrier fluid and a functionalizing agent which is distributed in the carrier fluid and has a proportion by mass in the dispersion corresponding to a predetermined mass ratio based on the proportion by mass of the particles. The dispersion is sedimented, such that the particles in platelet form are arranged in essentially plane-parallel layers in the sediment. The carrier fluid is removed from the sediment. Energy is introduced into the sediment to overcome the activation energy of that chemical reaction of the functionalizing agent with the particles which forms the particle composite from the sediment with coupling of the particles via the functionalizing agent. The mass ratio is predetermined such that the particle composite has a porous structure. The insulation paper is thereby produced.

Claims

1. A method for producing an electrical insulation paper comprising a particle composite, comprising the steps of:

mixing a dispersion of particles in platelet form, a carrier fluid and a functionalizing agent which is distributed in the carrier fluid and has a proportion by mass in the dispersion corresponding to a predetermined mass ratio based on the proportion by mass of the particles,

producing a sediment by sedimenting the dispersion, as a result of which the particles in platelet form are arranged in essentially plane-parallel layers in the sediment;

removing the carrier fluid from the sediment,

introducing energy into the sediment to overcome the activation energy of that chemical reaction of the functionalizing agent with the particles which forms the particle composite from the sediment with coupling of the particles via the functionalizing agent,

wherein the mass ratio is predetermined such that the particle composite has a porous structure,

producing the insulation paper.

2. The method as claimed in claim 1, wherein the carrier fluid is a solvent in which the functionalizing agent is soluble,

wherein the functionalizing agent has been dissolved in the solvent.

3. The method as claimed in claim 2, wherein the functionalizing agent is selected such that, when the dispersion is mixed, the functionalizing agent forms an essentially monomolecular thin layer on the surface of the particles.

4. The method as claimed in claim 2, further comprising:

prior to the mixing of the dispersion, the particles are formed with an essentially monomolecular thin layer on the surface of the particles,

wherein the thin layer is produced from a further functionalizing agent, such that the chemical reaction for coupling of the particles takes place between the thin layer and the functionalizing agent.

5. The method as claimed in claim 3, further comprising:

further mixing of the dispersion,

wherein formation of the monomolecular thin layer is followed by mixing of additional particles into the dispersion, these having an essentially monomolecular thin layer, such that the chemical reaction for coupling of the particles takes place between the thin layers.

6. The method as claimed in claim 4, further comprising:

further mixing of the dispersion,

wherein formation of the monomolecular thin layer is followed by mixing of additional particles into the dispersion, these having an essentially monomolecular thin layer, such that the chemical reaction for coupling of the particles takes place between the thin layers.

7. The method as claimed in claim 1, wherein the particles comprise aluminum oxide.

8. The method as claimed in claim 2, wherein the functionalizing agent is a polymer.

9. The method as claimed in claim 8, wherein the polymer is a thermoplastic.

10. The method as claimed in claim 8, wherein the polymer is:

a polyolefin alcohol, or

an incompletely hydrolyzed polyvinyl alcohol having a molecular mass between 1000 and 4000, or

a polyalkylsiloxane, or

a silicone polyester.

11. The method as claimed in claim 10, wherein the polyolefin alcohol is polyethylene glycol.

12. The method as claimed in claim 10, wherein the polyalkylsiloxane is methoxy-terminated polydimethylsiloxane.

13. The method as claimed in claim 2,

wherein the functionalizing agent is an alkoxysilane,

wherein the alkoxysilane has epoxy groups, or amino groups.

14. The method as claimed in claim 13, wherein the epoxy groups include 3-glycidoxypropyltrimethoxysilane.

15. The method as claimed in claim 13, wherein the amino groups include 3-aminopropyltrimethoxysilane.

16. The method as claimed in claim 1,

wherein the functionalizing agent comprises nanoparticles.

17. The method as claimed in claim 16, wherein the nanoparticles comprise nanoparticles of silicon oxide with surface epoxide groups.

18. The method as claimed in claim 1, wherein the energy to overcome the activation energy is supplied in the form of heat and/or radiation.

19. The method as claimed in claim 1, wherein the removal of the carrier fluid from the sediment is accomplished by filtration and subsequent supply of heat.

20. The method as claimed in claim 1, wherein the carrier fluid is water.