Selective removal of silica from silica containing brines

• US 9,051,827 B1
• Filed: 06/24/2010
• Issued: 06/09/2015
• Est. Priority Date: 09/02/2009
• Status: Active Grant

• Current Assignee: TerraLithium LLC (Occidental Petroleum Corporation)
• Original Assignee: Simbol Mining Corp.
• Inventors: Harrison, Stephen
• Primary Examiner(s): Bates, Zakiya W
• Assistant Examiner(s): RUNYAN, SILVANA C
• Application Number:
  US12/823,000
• Time in Patent Office: 1,811 Days
• Field of Search: 166/305.1, 166/222, 166/294, 166/295
• US Class Current: 1/1
• CPC Class Codes: E21B 37/06 using chemical means for preventing or limiting , e.g. eliminating, the deposition of paraffins or like substances
• CPC Class Codes: E21B 43/16 Enhanced recovery methods for obtaining hydrocarbons
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection
• CPC Class Codes: E21B 43/25 Methods for stimulating production by vibrating earth formations E21B43/003

Abstract

A method for selective removal and recovery of silica and silicon containing compounds from solutions that include silica and silicon containing compounds, including geothermal brines. Also included are methods of preventing silica scale buildup in the geothermal power equipment and processes employing geothermal brines by the selective removal of silica.

Claims

1. A method for preventing silica scale in geothermal brine reinjection wells by selectively removing silica from a geothermal brine solution, the method comprising the steps of:

obtaining a geothermal brine solution comprising silica;

maintaining the pH of the geothermal brine solution at a pH of between 4 and 6.25;

contacting the geothermal brine solution comprising silica with activated alumina, such that silica present in the geothermal brine solution selectively binds to the activated alumina;

recovering an aqueous brine product stream from the contacting step, said aqueous product stream having a reduced silica concentration relative to the geothermal brine solution; and

injecting the aqueous brine product stream into the geothermal well, the aqueous brine product stream comprising less than about 80 ppm of silica.

2. The method of claim 1, wherein the aqueous brine product stream comprises less than about 35 ppm of silica.

3. The method of claim 1, wherein the aqueous brine product stream comprises less than about 20 ppm of silica.

4. The method of claim 1, wherein the aqueous brine product stream comprises less than about 10 ppm of silica.

5. The method of claim 1, wherein the geothermal brine solution comprising silica has a silica concentration of between about 150 ppm and 250 ppm.

6. The method of claim 1, wherein the geothermal brine solution is contacted with the activated alumina at a temperature of less than about 100°

C.

7. The method of claim 1, further comprising a step prior to injecting the aqueous brine product stream, of supplying at least a portion of the aqueous brine product stream to a process for recovery of lithium.

8. The method of claim 1, further comprising a step prior to injecting the aqueous brine product stream, of supplying at least a portion of the aqueous brine product stream to a process for recovery of manganese or zinc.

9. A method for preventing silica scale in geothermal brine reinjection wells by selectively removing silica from a geothermal brine solution, the method comprising the steps of:

obtaining a geothermal brine solution containing silica and an iron (II) salt;

oxidizing the iron (II) salt to iron (III) hydroxide;

maintaining the pH of the geothermal brine solution at an adjusted pH of between 4.5 and 6.5;

contacting the silica and the iron (III) hydroxide at the adjusted pH for a time sufficient for the silica to attach to the iron (III) hydroxide and form a solid fraction containing a silica/iron precipitate and a liquid fraction, wherein the liquid fraction contains a geothermal brine product stream having a decreased concentration of silica and iron relative to the geothermal brine;

separating the silica/iron precipitate from the liquid fraction; and

injecting the liquid fraction into the geothermal well, the liquid fraction comprising less than about 80 ppm of silica.

10. The method of claim 9, wherein the liquid fraction comprises less than about 35 ppm of silica.

11. The method of claim 9, wherein the liquid fraction comprises less than about 20 ppm of silica.

12. The method of claim 9, wherein the liquid fraction comprises less than about 10 ppm of silica.

13. The method of claim 9, wherein the liquid fraction further comprises less than about 15 ppm of iron.

14. The method of claim 9, wherein the liquid fraction comprises less than about 10 ppm of silica and less than about 10 ppm of iron.

15. The method of claim 9, further comprising a step prior to injecting the liquid fraction, of supplying at least a portion of the liquid fraction to a process for recovery of lithium.

16. The method of claim 9, wherein the geothermal brine comprising silica has a silica concentration of between about 150 ppm and 250 ppm.