Solar reflective coatings and coating systems

• US 9,056,988 B2
• Filed: 10/28/2009
• Issued: 06/16/2015
• Est. Priority Date: 02/05/2007
• Status: Active Grant

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Decker, Eldon L., Hellring, Stuart D., McQuown, Stephen G., Minch, Britt A., Vanier, Noel R., Polk, W. David
• Primary Examiner(s): Cai, Wenwen
• Application Number:
  US12/607,681
• Publication Number:
  US 20100047620A1
• Time in Patent Office: 2,057 Days
• Field of Search: 524/441, 524/500, 524/505
• US Class Current: 1/1
• CPC Class Codes: B05D 7/54 No clear coat specified
• CPC Class Codes: C08F 293/00 Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule on to polymers modified by introduction of unsaturated end groups C08F290/02
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08K 5/0041 Optical brightening agents, organic pigments
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 17/003 containing an organic pigment process features in the making of dye stuff preparations C09B67/00
• CPC Class Codes: C09D 5/004 Reflecting paints; Signal paints
• CPC Class Codes: C09D 7/41 Organic pigments; Organic dyes
• CPC Class Codes: C09D 7/45 Anti-settling agents
• CPC Class Codes: C09D 7/61 inorganic
• CPC Class Codes: C09D 7/67 Particle size smaller than 100 nm
• CPC Class Codes: C09D 7/70 characterised by shape, e.g. fibres, flakes or microspheres

Abstract

Disclosed are infrared reflective coating compositions and cured coatings deposited on a substrate, as well as multi-component composite coating systems. The coating compositions include an infrared transparent pigment and an infrared reflective pigment.

Claims

1. A coating composition comprising:

(a) a film-forming resin;

(b) colored and/or opaque infrared reflective pigment particles;

(c) infrared transparent pigment particle; and

(d) a tri-block copolymer pigment dispersant;

wherein the colored and/or opaque infrared reflective pigment and the infrared transparent pigment are separate and different components and are separately dispersed in the coating composition and wherein the coating composition, when formed into a cured coating, exhibits;

(1) a total solar reflectance of at least 15% as measured in accordance with ASTM E 903-96; and

(2) an angle dependent color change of no more than 5 Δ

E units at a viewing angle from 110°

to −

15°

when compared to the color of a control coating not containing the colored and/or opaque infrared reflective pigment particles (b).

2. The coating composition of claim 1, wherein the cured coating further exhibits an angle dependent CIELAB L* value of no more than 50 at an observation angle of 25°

.

3. The coating composition of claim 2, wherein the angle dependent CIELAB L* value is no more than 25.

4. The coating composition of claim 1, wherein the total solar reflectance is at least 25%.

5. The coating composition of claim 1, wherein the tri-block copolymer comprises:

(a) a first segment comprising infrared transparent pigment affinic groups;

(b) a second segment comprising polar groups; and

(c) a third segment which is different from the first segment and the second segment.

6. The coating composition of claim 5, wherein the infrared transparent pigment affinic groups comprise aromatic groups.

7. The coating composition of claim 5, wherein the third segment is substantially non-polar and substantially free of infrared transparent pigment affinic groups.

8. The coating composition of claim 1, wherein the tri-block copolymer pigment dispersant has a polymer chain structure represented by the general formula:

φ

-(G)_p-(W)_q-(Y)_s-T

wherein;

(a) G is a residue of at least one radically polymerizable ethylenically unsaturated monomer;

(b) W and Y are residues of at least one radically polymerizable ethylenically unsaturated monomer;

with W and Y being different from one another;

(c) φ

is a hydrophobic residue of or derived from an initiator and is free of a radically transferable group of the initiator;

(d) T is or is derived from the radically transferable group of the initiator; and

(e) p, q, and s are each individually selected such that the pigment dispersant has a number average molecular weight of at least 250.

9. The coating composition of claim 1, wherein the tri-block copolymer pigment dispersant comprising:

(i) a first block comprising an oxirane functional monomer reacted with a carboxylic acid;

(ii) a second block comprising (meth)acrylic acid alkyl esters; and

(iii) a third block comprising (meth)acrylic acid alkyl esters.

10. The coating composition of claim 1, wherein the infrared reflective pigment particles have a ratio of reflectivity in the near-infrared region to reflectivity in the visible region of greater than 1:

1.

11. The coating composition of claim 1, wherein the infrared reflective pigment particles comprise an interference pigment.

12. The coating composition of claim 1, wherein the infrared transparent pigment particles comprise an organic pigment.

13. The coating composition of claim 12, wherein the organic pigment comprises aromatic groups.

14. The coating composition of claim 13, wherein the organic pigment comprises a perylene-based pigment.

15. A multi-component composite coating comprising:

(a) a first coating exhibiting a CIELAB L* value of no more than 50 and a total solar reflectance of at least 15% as measured in accordance with ASTM E 903-96 and deposited from a first coating composition comprising;

(i) a film-forming resin;

(ii) colored and/or opaque infrared reflective pigment particles;

(iii) infrared transparent pigment particles; and

(iv) a tri-block copolymer pigment dispersant;

wherein the colored and/or opaque infrared reflective pigment and the infrared transparent pigment are separate and different components and are separately dispersed in the first coating composition, and

wherein the first coating composition, when formed into a cured coating, exhibits an angle dependent color change of no more than 5 Δ

E units at a viewing angle from 110°

to −

15°

when compared to the color of a control coating not containing the infrared reflective pigment particles (ii); and

(b) a second coating deposited beneath at least a portion of the first coating, the second coating being deposited from a second coating composition comprising;

(i) a film-forming resin;

(ii) infrared reflective flake pigment particles; and

(iii) infrared reflective inorganic oxide pigment particles;

wherein the infrared reflective flake pigment and the infrared reflective inorganic oxide pigment are separate and different components of the second coating coating composition.

16. The composite coating of claim 15, wherein the sum of (b)(ii) and (b)(iii) in the second coating composition from which the second coating is deposited is no more than 10% by weight, based on the total solids weight of the second coating composition.