Elastomeric compositions comprising hydrocarbon polymer additives

• US 9,062,189 B2
• Filed: 12/29/2008
• Issued: 06/23/2015
• Est. Priority Date: 01/18/2008
• Status: Active Grant

• Current Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Rodgers, Michael B., Dias, Anthony J., Davis, Rick Dowell, Barbee, Thomas R., Mowry, Shawn W.
• Primary Examiner(s): Cai, Wenwen
• Application Number:
  US12/345,154
• Publication Number:
  US 20090186965A1
• Time in Patent Office: 2,367 Days
• Field of Search: 524/525, 524/571, 524/575.5
• US Class Current: 1/1
• CPC Class Codes: B60C 1/0016 Compositions of the tread
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: C08L 23/283 Halogenated homo- or copolymers of iso-olefins
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 7/00 Compositions of natural rubber
• CPC Class Codes: C08L 9/00 Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
• CPC Class Codes: C08L 9/06 Copolymers with styrene

Abstract

Provided are elastomeric compositions comprising at least one elastomer and a hydrocarbon polymer additive. Preferably the hydrocarbon polymer additive comprises from 60 to 90% piperylene, from 5 to 15% cyclic components, from 5 to 20% styrenic components, up to 5% isoprene, up to 5% indenic components, and up to 10% amylene. Also provided are elastomeric compositions comprising at least one elastomer and a hydrocarbon polymer additive, wherein the hydrocarbon polymer additive has a molecular weight of from 520 to 650 g/mole and a glass transition temperature (Tg) of from 48 to 53° C. The elastomeric compositions are particularly useful in making tires and other cured rubber articles.

Claims

1. An elastomeric composition comprising:

a) at least one elastomer; and

b) a hydrocarbon polymer additive, wherein the hydrocarbon polymer additive comprises from 70 weight % to 90 weight % piperylene, from 5 weight % to 15 weight % cyclic components, and from 5 weight % to 20 weight % styrenic components;

wherein the hydrocarbon polymer additive is substantially free of amylene or contains less than 10 weight % amylene;

wherein the hydrocarbon polymer additive is substantially free of isoprene; and

wherein the hydrocarbon polymer additive has a Tg of from 48°

C. to 53°

C.

2. The composition of claim 1, wherein the at least one elastomer is selected from the group consisting of butyl rubber, halogenated butyl rubber, branched butyl rubber, halogenated star-branched butyl rubber, poly(isobutylene-co-p-methylstyrene), halogenated poly(isobutylene-co-p-methylstyrene), general purpose rubber, natural rubber, polybutadiene rubber, polyisoprene rubber, styrene-butadiene rubber, styrene-isoprenebutadiene rubber, isoprene-butadiene rubber, high cis-polybutadiene, ethylene-propylene rubber, ethylene-propylene-diene rubber, nitrile rubber, brominated butyl rubber, chlorinated butyl rubber, star-branched polyisobutylene rubber, and mixtures thereof.

3. The composition of claim 1, wherein the hydrocarbon polymer additive is present from 5 to 50 phr.

4. The composition of claim 1, wherein the hydrocarbon polymer additive is substantially free of indenic components or contains less than 5 weight % indenic components.

5. The composition of claim 1, wherein the elastomeric composition further comprises one or more filler components selected from the group consisting of calcium carbonate, clay, mica, silica, silicates, talc, titanium dioxide, starch wood flour, carbon black, and mixtures thereof.

6. The composition of claim 1, wherein the elastomeric composition is cured.

7. The composition of claim 1, wherein the elastomeric composition is substantially free of aromatic oil.

8. The elastomeric composition of claim 1, wherein the hydrocarbon polymer additive has a number average molecular weight of from 520 g/mole to 650 g/mole.

9. The elastomeric composition of claim 8, wherein the at least one elastomer is selected from the group consisting of butyl rubber, halogenated butyl rubber, branched butyl rubber, halogenated star-branched butyl rubber, poly(isobutylene-co-p-methylstyrene), halogenated poly(isobutylene-co-p-methylstyrene), general purpose rubber, natural rubber, polybutadiene rubber, polyisoprene rubber, styrene-butadiene rubber, styrene-isoprene-butadiene rubber, isoprene-butadiene rubber, high cis-polybutadiene, ethylene-propylene rubber, ethylene-propylene-diene rubber, nitrile rubber, brominated butyl rubber, chlorinated butyl rubber, star-branched polyisobutylene rubber, and mixtures thereof

10. The elastomeric composition of claim 8, wherein the elastomeric composition is cured.

11. The elastomeric composition of claim 10, wherein the cured elastomeric composition is used for making a tire or a tire component.

12. A cured rubber article comprising an elastomer and a hydrocarbon polymer additive, wherein the hydrocarbon polymer additive comprises from 60 weight % to 90 weight % piperylene, from 5 weight % to 15 weight % cyclic components, and from 5 weight % to 20 weight % styrenic components;

wherein the hydrocarbon polymer additive is substantially free of amylene;

wherein the hydrocarbon polymer additive is substantially free of isoprene; and

wherein the hydrocarbon polymer additive has a Tg of from 48°

C. to 53°

C.

13. The article of claim 12, wherein the cured rubber article is a tire or tire component.

14. The article of claim 12, wherein the hydrocarbon polymer additive comprises less than 5 weight % indenic components.

15. The article of claim 12, wherein the cured rubber article comprises a tire tread.

16. A cured elastomeric composition obtained by the process of blending an elastomer with from 5 to 50 phr of at least one hydrocarbon polymer additive, and vulcanizing the blend;

wherein the at least one hydrocarbon polymer additive comprises from 60 weight % to 90 weight % piperylene, from 5 weight % to 15 weight % cyclic components, and from 5 weight % to 20 weight % styrenic components;

wherein the at least one hydrocarbon polymer additive is substantially free of isoprene, contains less than 10 weight % amylene, and contains less than 5 weight % indenic components; and

wherein the at least one hydrocarbon polymer additive has a Tg of from 48°

C. to 53°

C.

17. The composition of claim 16, wherein the at least one hydrocarbon polymer additive has a number average molecular weight of from 520 g/mole to 650 g/mole, and wherein the at least one hydrocarbon polymer additive is substantially free of amylene and indenic compounds.