Hydrocarbon gas processing

• US 9,080,810 B2
• Filed: 05/09/2006
• Issued: 07/14/2015
• Est. Priority Date: 06/20/2005
• Status: Active Grant

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: Ortloff Enigneers, Ltd.
• Inventors: Pitman, Richard N., Wilkinson, John D., Lynch, Joe T., Hudson, Hank M., Cuellar, Kyle T., Martinez, Tony L.
• Primary Examiner(s): Pettitt, John F
• Application Number:
  US11/430,412
• Publication Number:
  US 20060283207A1
• Time in Patent Office: 3,353 Days
• Field of Search: 626/20, 626/21, 626/18, 626/19
• US Class Current: 1/1
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/04 in a dual pressure main column system
• CPC Class Codes: F25J 2200/30 using a side column in a single pressure column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/76 Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
• CPC Class Codes: F25J 2200/78 Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2205/02 using simple phase separation in a vessel or drum
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2220/66 Separating acid gases, e.g. CO2, SO2, H2S or RSH
• CPC Class Codes: F25J 2230/08 Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2280/02 Control in general, load changes, different modes ("runs"), measurements
• CPC Class Codes: F25J 2290/40 Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.
• CPC Class Codes: F25J 2290/80 Retrofitting, revamping or debottlenecking of existing plant
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more

Abstract

A process for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. The stream is cooled and is thereafter expanded to the fractionation tower pressure and supplied to the fractionation tower at a lower mid-column feed position. A distillation stream is withdrawn from the column below the feed point of the stream and is then directed into heat exchange relation with the tower overhead vapor stream to cool the distillation stream and condense at least a part of it, forming a condensed stream. At least a portion of the condensed stream is directed to the fractionation tower at an upper mid-column feed position. A recycle stream is withdrawn from the tower overhead after it has been warmed and compressed. The compressed recycle stream is cooled sufficiently to substantially condense it, and is then expanded to the pressure of the fractionation tower and supplied to the tower at a top column feed position. The quantities and temperatures of the feeds to the fractionation tower are effective to maintain the overhead temperature of the fractionation tower at a temperature whereby the major portion of the desired components is recovered.

Claims

1. In a process for the separation of a gas stream containing methane, C₂ components, C₃ components, and heavier hydrocarbon components into a volatile residue gas fraction and a relatively less volatile fraction containing a major portion of said C₂ components, C₃ components, and heavier hydrocarbon components or said C₃ components and heavier hydrocarbon components, in which process

(a) said gas stream is cooled under pressure to provide a cooled stream;

(b) said cooled stream is expanded to a lower pressure whereby said cooled stream is further cooled thereby forming a further cooled expanded stream; and

(c) said further cooled expanded stream is directed into a distillation column and fractionated at said lower pressure whereby the components of said relatively less volatile fraction are recovered;

the improvement wherein said further cooled expanded stream is directed to a first mid-column feed position on said distillation column; and

(1) a vapor distillation stream is withdrawn from a region of said distillation column below said first mid-column feed position and is cooled sufficiently to condense at least a part of said vapor distillation stream, thereby forming a condensed stream and a residual vapor stream containing any uncondensed vapor remaining after said vapor distillation stream is cooled;

(2) at least a portion of said condensed stream is supplied to said distillation column at a second mid-column feed position above said first mid-column feed position;

(3) an overhead vapor stream is withdrawn from an upper region of said distillation column and is directed into heat exchange relation with at least said vapor distillation stream and heated, thereby to supply at least a portion of the cooling of step (1) and forming a heated overhead vapor stream;

(4) said heated overhead vapor stream is combined with any said residual vapor stream to form a heated combined vapor stream;

(5) said heated combined vapor stream is compressed to higher pressure and thereafter divided into said volatile residue gas fraction and a compressed recycle stream;

(6) said compressed recycle stream is cooled sufficiently to substantially condense-said compressed recycle stream, thereby forming a condensed compressed recycle stream;

(7) said substantially condensed compressed recycle stream is expanded to said lower pressure and supplied to said distillation column at a top feed position above said second mid-column feed position; and

(8) quantities and temperatures of said feed streams to said distillation column are effective to maintain an overhead temperature of said distillation column at a temperature whereby the major portions of the components in said relatively less volatile fraction are recovered.

2. The process according to claim 1 wherein said gas stream is cooled sufficiently to partially condense-said gas stream, thereby forming a partially condensed gas stream;

and

(1) said partially condensed gas stream is separated thereby to provide a vapor stream and at least one liquid stream;

(2) said vapor stream is expanded to said lower pressure whereby said vapor stream is further cooled, and thereafter supplied to said distillation column at said first mid-column feed position; and

(3) from 0% to 100% of said at least one liquid stream is expanded to said lower pressure and supplied to said distillation column at a third mid-column feed position;

(4) from 100% to 0% of said at least one liquid stream is expanded to said lower pressure and combined with said vapor distillation stream to form a combined stream;

(5) said combined stream is cooled sufficiently to condense at least a part of said combined stream, thereby forming said condensed stream and said residual vapor stream containing any uncondensed vapor remaining after said combined stream is cooled; and

(6) said overhead vapor stream is directed into heat exchange relation with at least said combined stream and heated, thereby to supply at least a portion of the cooling of step (5).

3. In an apparatus for the separation of a gas stream containing methane, C₂ components, C₃ components, and heavier hydrocarbon components into a volatile residue gas fraction and a relatively less volatile fraction containing a major, portion of said C₂ components, C₃ components, and heavier hydrocarbon components or said C₃ components and heavier hydrocarbon components, in said apparatus there being

(a) a first cooling means to cool said gas under pressure connected to provide a cooled stream under pressure;

(b) a first expansion means connected to receive at least a portion of said cooled stream under pressure and expand said cooled stream to a lower pressure, whereby said cooled stream is further cooled thereby forming a further cooled expanded stream; and

(c) a distillation column connected to receive said further cooled expanded stream, said distillation column being adapted to separate said further cooled expanded stream into an overhead vapor stream and said relatively less volatile fraction;

the improvement wherein said apparatus includes

(1) said distillation column connected to said first expansion means to receive said further cooled expanded stream at a first mid-column feed position on said distillation column;

(2) vapor withdrawing means connected to said distillation column to receive a vapor distillation stream from a region of said distillation column below said first mid-column feed position;

(3) heat exchange means connected to said vapor withdrawing means to receive said vapor distillation stream and cool said vapor distillation stream sufficiently to condense at least a part of said vapor distillation stream;

(4) first separating means connected to said heat exchange means to receive said at least partially condensed distillation stream and separate said at least partially condensed distillation stream, thereby forming a condensed stream and a residual vapor stream containing any uncondensed vapor remaining after said vapor distillation stream is cooled, said first separating means being further connected to said distillation column to supply at least a portion of said condensed stream to said distillation column at a second mid-column feed position above said first mid-column feed position;

(5) said distillation column being further connected to said heat exchange means to direct at least a portion of said overhead vapor stream separated therein into heat exchange relation with at least said vapor distillation stream and heat said overhead vapor stream, thereby to supply at least a portion of the cooling of element (3);

(6) first combining means connected to combine said heated overhead vapor stream and any said residual vapor stream into a heated combined vapor stream;

(7) compressing means connected to said first combining means to receive said heated combined vapor stream and compress said heated combined vapor stream to higher pressure;

(8) dividing means connected to said compressing means to receive said compressed heated combined vapor stream and divide said compressed heated combined vapor stream into said volatile residue gas fraction and a compressed recycle stream;

(9) second cooling means connected to said dividing means to receive said compressed recycle stream and cool said compressed recycle stream sufficiently to substantially condense said compressed recycle stream;

(10) second expansion means connected to said second cooling means to receive said substantially condensed compressed recycle stream and expand said substantially condensed compressed recycle stream to said lower pressure, said second expansion means being further connected to said distillation column to supply said expanded condensed recycle stream to said distillation column at a top feed position above said second mid-column feed position; and

(11) control means adapted to regulate the quantities and temperatures of said feed streams to said distillation column to maintain the overhead temperature of said distillation column at a temperature whereby the major portions of the components in said relatively less volatile fraction are recovered.

4. The apparatus according to claim 3 wherein said apparatus includes

(1) said first cooling means being adapted to cool said gas stream under pressure sufficiently to partially condense said gas stream;

(2) second separating means connected to said first cooling means to receive said partially condensed gas stream and separate said partially condensed gas stream into a vapor stream and at least one liquid stream;

(3) said first expansion means connected to said second separating means to receive said vapor stream and expand said vapor stream to said lower pressure, said first expansion means being further connected to said distillation column to supply said expanded vapor stream to said distillation column at said first mid-column feed position;

(4) third expansion means connected to said second separating means to receive from 0% to 100% of said at least one liquid stream and expand said at least one liquid stream to said lower pressure, said third expansion means being further connected to said distillation column to supply said expanded liquid stream to said distillation column at a third mid-column feed position;

(5) fourth expansion means connected to said second separating means to receive from 100% to 0% of said at least one liquid stream and expand said at least one liquid stream to said lower pressure;

(6) second combining means connected to said fourth expansion means to receive said expanded portion, said second combining means being further connected to said vapor withdrawing means to receive said vapor distillation stream and thereby combine said streams to form a combined stream;

(7) said heat exchange means connected to said second combining means to receive said combined stream and cool said combined stream sufficiently to condense at least a part of said combined stream, said heat exchange means being further connected to supply said at least partially condensed combined stream to said first separating means; and

(8) said heat exchange means being further connected to said distillation column to direct at least a portion of said overhead vapor stream separated therein into heat exchange relation with at least said combined stream and heat said overhead vapor stream, thereby to supply at least a portion of the cooling of element (7).