Oral care whitening compositions

• US 9,155,688 B2
• Filed: 12/18/2012
• Issued: 10/13/2015
• Est. Priority Date: 12/20/2011
• Status: Active Grant

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Boyd, Thomas, Ontumi, Dennis, Mandadi, Prakasarao, Chopra, Suman, Nesta, Jason, Pimenta, Paloma
• Primary Examiner(s): WEBB, WALTER E
• Application Number:
  US14/366,356
• Publication Number:
  US 20140314693A1
• Time in Patent Office: 1,029 Days
• Field of Search: 424/53, 424/49
• US Class Current: 1/1
• CPC Class Codes: A61K 2800/872 Pencils; Crayons; Felt-tip pens
• CPC Class Codes: A61K 8/22 Peroxides; Oxygen; Ozone
• CPC Class Codes: A61K 8/38 Percompounds, e.g. peracids
• CPC Class Codes: A61K 8/8176 Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61Q 11/00 Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

Abstract

Described herein are whitening compositions comprising a peroxide source, and an adhesion system comprising a hydrophobic component comprising a silicone adhesive; and a dental surface adhesion enhancing agent, which are physically stable and effectively provide whitening. Methods of making and using these compositions are also described herein.

Claims

1. A non-aqueous oral care composition comprising:

a peroxide source in the amount effective to deliver 0.01% to 5.5% of hydrogen peroxide; and

an adhesion system comprising;

a hydrophobic component comprising a silicone polymer and a silicone adhesive; and

a dental surface adhesion enhancing agent,

wherein the composition when applied to the teeth is sufficiently viscous to form an adherent, continuous layer on a dental surface and deliver an effective amount of said peroxide source to a tooth surface;

wherein the peroxide source is selected from;

hydrogen peroxide;

urea peroxide, a crosslinked polyvinylpyrrolidone-hydrogen peroxide complex;

sodium perborate; and

a combination of two or more thereof; and

wherein the adhesion system further comprises an organic material selected from;

bees wax, mineral oil, a mineral oil and polyethylene blend, petrolatum, a liquid paraffin and butene/ethylene/styrene hydrogenated copolymer blend, a polyethylene wax, polyisobutene, a polyvinyl pyrrolidone/vinyl acetate copolymer;

a polyacrylate;

a shellac; and

a combination of two or more thereof;

wherein the composition has a Herschel-Bulkley rate index of less than 0.7; and

wherein the composition has a critical strain greater than or equal to 0.02.

2. The composition of claim 1, wherein the peroxide source is a crosslinked polyvinylpyrrolidone-hydrogen peroxide complex.

3. The composition of claim 1, wherein the dental surface adhesion enhancing agent comprises an additional amount of cross-linked polyvinylpyrrolidone.

4. The composition of claim 3, wherein the additional amount of cross-linked polyvinylpyrrolidone is not complexed with a peroxide source.

5. The composition of claim 1, wherein the peroxide source is present in an amount effective to deliver about 0.1% hydrogen peroxide.

6. The composition of claim 1, wherein the peroxide source is present in an amount effective to deliver about 4.5% hydrogen peroxide.

7. The composition of claim 1, wherein the silicone adhesive is a pressure sensitive silicone adhesive.

8. The composition of claim 7, wherein the pressure sensitive silicone adhesive is a copolymer prepared by condensing a silicone resin with a dihydroxy polydiorganosiloxane.

9. The composition of claim 8, wherein the dihydroxy polydiorganosiloxane is dihydroxy polydimethylsiloxane.

10. The composition of claim 7, wherein the silicone resin is a silanol-containing silicone resin.

11. The composition of claim 1, wherein the organic material is mineral oil or a mineral oil and polyethylene blend.

12. The composition of claim 11, wherein the organic material comprises mineral oil.

13. The composition of claim 1, wherein the adhesion system further comprises mineral oil;

and wherein the weight percentage of mineral oil is substantially similar to, or greater than, the weight percentage of the silicone adhesive.

14. The composition of claim 1, wherein the adhesion system further comprises mineral oil;

and wherein the weight percentage of mineral oil is greater than, the weight percentage of the silicone adhesive, based on the total weight of the composition.

15. The composition of claim 1, wherein the composition has a G′

/G″

ratio of greater than or equal to 1 in the linear viscoelastic region.

16. A method for whitening a tooth comprising applying the composition of claim 1 to a tooth of a mammal.

17. The method of claim 16, wherein the composition is applied using a pen.

18. The method of claim 16, wherein the composition is allowed to remain on the surface of the tooth for a plurality of minutes.

19. The method of claim 16, wherein the composition is allowed to remain on the surface of the tooth for at least 15 minutes.

20. The method of claim 16, wherein the composition is allowed to remain on the surface of the tooth for about 30 minutes.

21. The method of claim 17, wherein the pen is stored within an oral care implement.

22. The method of claim 21, wherein the pen is removed from the oral care implement prior to application of the composition to the tooth.

23. The method of claim 17, wherein the composition is applied to the tooth after brushing.

24. The method of claim 17, wherein the composition is applied to the tooth after brushing with the oral care implement.

25. The composition of claim 11, wherein the organic material comprises a mineral oil and polyethylene blend.

26. The composition of claim 1, wherein the composition has a viscosity greater than about 10,000 cPs and less than about 100,000 cPs.

27. The composition of claim 1, wherein the composition has a viscosity greater than about 50,000 cPs and less than about 900,000 cPs.

28. The composition of claim 1, wherein the composition has a viscosity greater than about 200,000 cPs and less than about 600,000 cPs.

29. The composition of claim 11, wherein the composition has no liquid phase separation after one month.