Flexible amine sensor based on ultrathin poly-thiophene thin film transistor

• US 9,157,886 B2
• Filed: 06/03/2011
• Issued: 10/13/2015
• Est. Priority Date: 06/03/2011
• Status: Active Grant

• Current Assignee: City University of Hong Kong
• Original Assignee: City University of Hong Kong
• Inventors: Roy, Vellaisamy A. L., Xu, Zong-Xiang
• Primary Examiner(s): Williams, Hezron E
• Assistant Examiner(s): Frank, Rodney T
• Application Number:
  US13/152,816
• Publication Number:
  US 20120304741A1
• Time in Patent Office: 1,593 Days
• Field of Search: 73/310.6
• US Class Current: 1/1
• CPC Class Codes: G01N 27/12 of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid , for detecting components in the fluid
• CPC Class Codes: G01N 27/127 comprising nanoparticles
• CPC Class Codes: G01N 27/4141 specially adapted for gases
• CPC Class Codes: G01N 27/4145 specially adapted for biomolecules, e.g. gate electrode with immobilised receptors
• CPC Class Codes: H10K 10/466 Lateral bottom-gate IGFETs comprising only a single gate
• CPC Class Codes: H10K 85/113 Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene

Abstract

The design and fabrication of ultrathin poly-3-hexyl thiophene (P3HT) film based amine sensors are described herein. Ultrathin P3HT monolayer films can be built on a patterned flexible n-octadecylphosphonic acid (ODPA)/Al₂O₃/PET substrate, forming a flexible polymer thin film transistor according to a solution process. The mechanism of the sensor is based on the interaction of amine molecules with the surface of the P3HT monolayer. The interaction of amine molecules with the surface of the P3HT monolayer can affect the current density of the PTFT, and the change in current density can indicate the presence of amine molecules in the surroundings. The amine sensors described herein can easily detect amine molecules in a parts per billion (ppb) range. The amine sensors can be utilized, for example, as disposable sensors within food packaging to ensure the safety of the packaged food.

Claims

1. A method, comprising:

fabricating a substrate; and

depositing a film of poly-3-hexyl thiophene (P3HT) on an octadecylphosphonic acid (ODPA) monolayer of the substrate to form a top layer of a gas sensor for sensing gas vapors.

2. The method of claim 1, wherein the fabricating the substrate further comprises fabricating an ODPA/aluminum oxide (Al₂O₃)/polyethylene terephthalate (PET) substrate.

3. The method of claim 1, wherein the depositing the film of P3HT comprises depositing the film of P3HT according to a solution process.

4. The method of claim 1, wherein the depositing the film of P3HT further comprises depositing the film of P3HT with a thickness on an order of nanometers.

5. The method of claim 1, wherein the depositing the film of P3HT further comprises depositing the film of P3HT with a thickness between approximately one and approximately 60 nanometers.

6. The method of claim 1, wherein the depositing the film of P3HT further comprises depositing the film of P3HT with a thickness between approximately one and approximately 15 nanometers.

7. The method of claim 1, wherein the depositing the film of P3HT further comprises depositing the film of P3HT with a thickness between approximately 1.5 and approximately 3 nanometers.

8. The method of claim 1, wherein the depositing the film of P3HT further comprises depositing the film of P3HT with a thickness between approximately two and approximately three nanometers.

9. The method of claim 1, wherein the sensing the gas vapors further comprises sensing amine vapors with the gas sensor.

10. The method of claim 1, wherein the sensing the gas vapors further comprises sensing amine vapors with the gas sensor with a sensitivity to amine concentrations less than 500 parts per billion.

11. The method of claim 1, wherein the sensing the gas vapors further comprises sensing amine vapors with the gas sensor with a sensitivity to amine concentrations less than 100 parts per billion.

12. The method of claim 1, wherein the sensing the gas vapors further comprises sensing amine vapors with the gas sensor with a sensitivity to amine concentrations less than 50 parts per billion.

13. The method of claim 1, wherein the means for depositing the film of P3HT further comprises means for depositing the film of P3HT via a solution process.

14. A polymer thin film transistor amine sensor, comprising:

a substrate; and

a film of poly-3-hexyl thiophene (P3HT) that is formed on an octadecylphosphonic acid (ODPA) monolayer of the substrate and as a top layer of the polymer thin film transistor amine sensor,

wherein the polymer thin film transistor amine sensor has a sensitivity to amine vapors with a particular concentration.

15. The polymer thin film transistor amine sensor of claim 14, wherein the substrate is an ODPA/aluminum oxide (Al₂O₂)/polyethylene terephthalate (PET) substrate.

16. The polymer thin film transistor amine sensor of claim 15, wherein the film of P3HT is deposited on the ODPA/Al₂O₃/PET substrate.

17. The polymer thin film transistor amine sensor of claim 14, wherein the film of P3HT has a film thickness between approximately one and approximately 60 nanometers.

18. The polymer thin film transistor amine sensor of claim 14, wherein the film of P3HT has a film thickness between approximately two and approximately three nanometers.

19. The polymer thin film transistor amine sensor of claim 14, wherein the particular concentration is a concentration of less than 600 parts per billion.

20. The polymer thin film transistor amine sensor of claim 14, wherein the particular concentration is a concentration of less than 50 parts per billion.

21. A system, comprising:

means for fabricating a substrate; and

means for depositing a film of poly-3-hexyl thiophene (P3HT) on an octadecylphosphonic acid (ODPA) monolayer of the substrate to form a top layer of a gas sensor for sensing gas vapors.