Measuring transducer for determining a measured variable representing a content of H;and/or oh;ions in a measured medium

• US 9,201,039 B2
• Filed: 06/22/2012
• Issued: 12/01/2015
• Est. Priority Date: 06/24/2011
• Status: Active Grant

• Current Assignee: Endress + Hauser Conducta Gesellschaft Fur Mess- Und Regeltechnik Mbh + Co. Kg
• Original Assignee: Endress + Hauser Conducta Gesellschaft Fur Mess- Und Regeltechnik Mbh + Co. Kg
• Inventors: Hanko, Michael, Wilhelm, Thomas, Jagiella, Manfred
• Primary Examiner(s): NOGUEROLA, ALEXANDER STEPHAN
• Application Number:
  US13/530,459
• Publication Number:
  US 20120325659A1
• Time in Patent Office: 1,257 Days
• US Class Current: 1/1
• CPC Class Codes: G01N 21/80 Indicating pH value
• CPC Class Codes: G01N 27/302 pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes ion selective electrodes G01N27/333, glass electrodes G01N27/36
• CPC Class Codes: G01N 27/3335 the membrane containing at least one organic component G01N27/3271 takes precedence; aspects concerning the enzyme reagent in enzyme electrodes C12Q1/001
• CPC Class Codes: G01N 27/414 Ion-sensitive or chemical field-effect transistors, i.e. ISFETS or CHEMFETS

Abstract

A measuring transducer, which is embodied to produce and output a measurement signal dependent on the content of H⁺ and/or OH⁻ ions present in a measured medium, wherein the measuring transducer has, in a region provided for contact with the measured medium, at least one polymer membrane selectively conducting H⁺ and/or OH⁻ ions. The polymer membrane can comprise an H⁺ ion conducting polymer and/or an OH⁻ ion conducting polymer.

Claims

1. A measuring transducer, which is embodied to produce and output a measurement signal dependent on the content of H⁺ and/or OH⁻

ions present in a measured medium, comprising;

at least one polymer membrane selectively conducting H⁺ and/or OH⁻

ions, in a region provided for contact with the measured medium, wherein;

conduction of H⁺ and/or OH⁻

ions occurs intrinsically by means of structural diffusion by transfer of H⁺ ions and/or OH⁻

ions between neighboring functional groups of said polymer membrane;

said polymer membrane comprises an OH⁻

ion conducting polymer.

2. The measuring transducer as claimed in claim 1, wherein:

said polymer membrane comprises an H⁺ ion conducting polymer.

3. The measuring transducer as claimed in claim 1, wherein:

conduction of H⁺ and/or OH⁻

ions occurs intrinsically by means of a Grotthuss-type mechanism.

4. The measuring transducer as claimed in claim 1, wherein:

said polymer membrane comprises an anhydrous polymeric proton conductor, which has a basic polymer structure, especially a polysiloxane, polystyrene or polythiophene, basic polymer structure, to which groups serving as proton solvent are bonded via side chains, especially flexible side chains.

5. The measuring transducer as claimed in claim 4, wherein:

the groups serving as proton solvent comprise at least one aromatic, heterocyclic compound, especially comprising at least one of the heterocyclic compounds from the group formed by imidazole, benzimidazole or pyrazole.

6. The measuring transducer as claimed in claim 4, wherein:

additionally, acid groups are bonded via side chains, especially flexible side chains, to the basic polymer structure, especially acid groups comprising sulfonic acid, and/or carboxyl, groups.

7. A measuring transducer, which is embodied to produce and output a measurement signal dependent on the content of H⁺ and/or OH⁻

ions present in a measured medium, comprising;

at least one polymer membrane selectively conducting H⁺ and/or OH⁻

ions, in a region provided for contact with the measured medium, wherein;

conduction of H⁺ and/or OH⁻

ions occurs intrinsically by means of structural diffusion by transfer of H⁺ ions and/or OH⁻

ions between neighboring functional groups of said polymer membrane;

said polymer membrane spatially separates a sensitive element of the measuring transducer from the measured medium.

8. The measuring transducer as claimed in claim 7, wherein:

said sensitive element comprises a field effect transistor assembly.

9. The measuring transducer as claimed in claim 7, wherein:

the measuring transducer is an optical measuring transducer; and

said sensitive element comprises a sensor matrix, especially a polymer membrane or a porous solid body, having a pH or pOH sensitive indicator immobilized by the sensor matrix.

10. The measuring transducer as claimed in claim 7, wherein:

the measuring transducer comprising a metal oxide electrode, in particular an antimony electrode; and

said polymer membrane selectively conducting H⁺ and/or OH⁻

ions spatially separates the metal oxide electrode from the measured medium.

11. A measuring transducer, which is embodied to produce and output a measurement signal dependent on the content of H⁺ and/or OH⁻

ions present in a measured medium, comprising;

at least one polymer membrane selectively conducting H⁺ and/or OH⁻

ions, in a region provided for contact with the measured medium, wherein;

conduction of H⁺ and/or OH⁻

ions occurs intrinsically by means of structural diffusion by transfer of H⁺ ions and/or OH⁻

ions between neighboring functional groups of said polymer membrane; and

the measuring transducer is embodied as a potentiometric pH probe.

12. The measuring transducer as claimed in claim 11, further comprising:

a measuring half cell, said measuring half cell comprising a housing, which encloses a measuring half cell space, said housing being sealed by said polymer membrane selectively conducting H⁺ and/or OH⁻

ions in a region of the measuring transducer provided for contacting the measured medium.

13. A measuring transducer, which is embodied to produce and output a measurement signal dependent on the content of H+ and/or OH⁻

ions present in a measured medium, comprising;

at least one polymer membrane selectively conducting H⁺ and/or OH⁻

ions, in a region provided for contact with the measured medium;

wherein;

said polymer membrane spatially separates a sensitive element of the measuring transducer from the measured medium;

the measuring transducer is an optical measuring transducer; and

said sensitive element comprises a sensor matrix, comprising a pH or pOH sensitive indicator immobilized by the sensor matrix.

14. The measuring transducer as claimed in claim 13, wherein:

the sensor matrix is a polymer membrane or a porous solid body.