Low vinyl styrene-butadiene polymers and methods of making the same

• US 9,243,099 B2
• Filed: 06/15/2011
• Issued: 01/26/2016
• Est. Priority Date: 06/15/2010
• Status: Active Grant

• Current Assignee: Trinseo Europe Gmbh
• Original Assignee: Trinseo Europe Gmbh
• Inventors: Valenti, Silvia, Hamann, Evemarie
• Primary Examiner(s): Fink, Brieann R
• Application Number:
  US13/702,685
• Publication Number:
  US 20130090440A1
• Time in Patent Office: 1,686 Days
• Field of Search: 526/204, 526/340
• US Class Current: 1/1
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 236/10 with vinyl-aromatic monomers
• CPC Class Codes: C08F 4/48 selected from lithium, rubidium, caesium or francium C08F4/461 takes precedence
• CPC Class Codes: C08L 9/06 Copolymers with styrene

Abstract

The invention provides a process for the continuous polymerization of a polymer comprising monomeric units derived from styrene and 1,3-butadiene, said process comprising:

• • polymerizing the monomers in the presence of an initiator, and at least one polar agent selected from Formula 1;

• • wherein R1 and R2 are each independently an alkyl, and preferably a C1-C4 alkyl; R3, R4, R5, R6, R7 and R8 are each independently selected from hydrogen or an alkyl, and preferably hydrogen or a C1-C4 alkyl;
  • and wherein a 1,2-diene is added to the polymerization, and the 1,2-diene to active initiator (active for polymerization) molar ratio is from 0.1 to 1.0, preferably from 0.1 to 0.9, and more preferably from 0.1 to 0.85; and
  • wherein the polar agent to the active initiator molar ratio is from 0.05 to 0.6, preferably from 0.1 to 0.5, more preferably from 0.15 to 0.3.

The invention also provides a composition comprising a polymer comprising monomeric units derived from styrene and 1,3-butadiene, and wherein the polymer has at least the following characteristics:

• • A) vinyl content from 12 to 40 weight percent, based on the weight of polymerized butadiene in the polymer,
  • B) block styrene content less than 8 weight percent, based on the weight of styrene in the polymer, and
  • C) a styrene content from 10 to 50 weight percent, based on the weight of the polymer.

Claims

1. A composition comprising a polymer comprising monomeric units derived from styrene and 1,3-butadiene, and wherein the polymer comprises:

A) a vinyl content from 20 to 30 weight percent, based on the weight of polymerized butadiene in the polymer,

B) a block styrene content less than 8 weight percent, based on the weight of styrene in the polymer, and

C) a styrene content from 10 to 50 weight percent, based on the weight of the polymer,

wherein the polymer is polymerized in the presence of a 1,2-diene, an active initiator, and at least one polar agent,

wherein the 1,2-diene to active initiator molar ratio is from 0.1 to 1.0,

wherein the polar agent to the active initiator molar ratio is from 0.05 to 0.6,

wherein the polymer has a number average molecular weight (Mn) from 70,000 to 300,000 g/mole, wherein the composition does not comprise an oil, wherein the polar agent is ditetrahydrofurylpropane and wherein the 1,2-diene is 1,2 butadiene.

2. The composition of claim 1, wherein the polymer has a molecular weight distribution from 1.5 to 3.

3. The composition of claim 1, wherein the polymer has a Mooney Viscosity from 30 to 90.

4. An article comprising at least one component formed from the composition of claim 1.

5. The composition of claim 1, wherein the composition contains less than 2400 ppm residual styrene.

6. The composition of claim 1, wherein the composition contains less than 1000 ppm of residual monomers.

7. The composition of claim 1, wherein the polymer has a weight average molecular weight from 105,000 to 1,500,000 g/mole.

8. The composition of claim 1, wherein the polymer is living.

9. The composition of claim 1, wherein the block styrene content is less than 6 weight percent, based on the weight of styrene in the polymer.

10. The composition of claim 1, wherein the styrene content is from 20 to 43 weight percent, based on the weight of the polymer.

11. The composition of claim 1, wherein the polymer has a molecular weight distribution from 1.7 to 2.2.