Polyurethane foam formulation, products and methods

• US 9,243,120 B2
• Filed: 08/28/2014
• Issued: 01/26/2016
• Est. Priority Date: 12/29/2006
• Status: Expired due to Fees

• Current Assignee: Adient Luxembourg Holding S..R.L.
• Original Assignee: Johnson Controls Technology Company (Johnson Controls International plc)
• Inventors: McEvoy, James T., McRoberts, Terrence M., Yamasaki, Ryoko, Li, William, Metcalfe, Murray D.
• Primary Examiner(s): COONEY, JOHN M
• Application Number:
  US14/472,121
• Publication Number:
  US 20140371337A1
• Time in Patent Office: 516 Days
• US Class Current: 1/1
• CPC Class Codes: B29K 2075/00 Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2105/045 with open cells
• CPC Class Codes: C08G 18/4072 Mixtures of compounds of group C08G18/63 with other macromolecular compounds
• CPC Class Codes: C08G 18/4804 Two or more polyethers of different physical or chemical nature
• CPC Class Codes: C08G 18/4841 containing oxyethylene end groups
• CPC Class Codes: C08G 18/632 onto polyethers
• CPC Class Codes: C08G 2110/0008 flexible
• CPC Class Codes: C08G 2110/0058 ≥50 and <150kg/m3
• CPC Class Codes: C08G 2110/0083 prepared using water as the sole blowing agent
• CPC Class Codes: C08G 2350/00 Acoustic or vibration damping material
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 2375/08 from polyethers
• CPC Class Codes: C08J 9/14 organic
• CPC Class Codes: C08J 9/228 Forming foamed products
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]

Abstract

A foam article for use in a seat cushion includes an open cell, polyurethane foam material that includes a base polyol; a crosslinker; an isocyanate; a surfactant; and water, that are reacted together to produce a seat cushion having dynamic and static performance specifications that are better than the performance characteristics for a traditional, high resilient material seat cushion, as well as other seating materials.

Claims

1. A method of making an open cell, molded polyurethane foam object, comprising:

reacting a reaction mixture in a mold to produce a reaction product, wherein the reaction mixture comprises;

a base polyol having a molecular weight of from 5000 to 10000 and a monol content of less than 10% by weight;

an isocyanate;

a surfactant; and

water;

curing the reaction product in the mold;

removing the reaction product from the mold; and

crushing the reaction product by performing a crushing step, wherein the crushing step comprises first compressing the reaction product to about 50% of its original height, then compressing the reaction product to about 90% of its original height, and then again compressing the reaction product to about 90% of its original height to generate an open cell, polyurethane foam material having a comfort value of less than 13.0, and the comfort value is the natural frequency multipled by the peak measured transmissivity.

2. The method of claim 1, wherein the crushing step occurs between 60 and 600 seconds after the reaction product is removed from the mold.

3. The method of claim 1, wherein the crushing step occurs between 60 and 300 seconds after the reaction product is removed from the mold.

4. The method of claim 1, wherein the interval between each compression of the foam article is at least 30 seconds.

5. The method of claim 1, wherein the reaction mixture further comprises:

bis(2-dimethylaminoethyl) ether as an amine blowing catalyst;

triethylene diamine as an amine gelling catalyst, wherein a ratio of the amine blowing catalyst to the amine gelling catalyst is 1;

3, by weight; and

a copolymer polyol comprising a mixture of an ethylene oxide (EO) capped base polyol and styrene acrylonitrile (SAN) polymer solids, wherein the copolymer polyol is present in the reaction mixture in an amount of 50 parts per hundred parts polyol (pphp), and the base polyol is present in the reaction mixture in an amount of 50 parts per hundred parts polyol, or wherein the copolymer polyol is present in the reaction mixture in an amount of 70 parts per hundred parts polyol (pphp), and the base polyol is present in the reaction mixture in an amount of 30 parts per hundred parts polyol.

6. The method of claim 1, wherein the polyol has a molecular weight of from 6000 to 8000.

7. The method of claim 1, wherein the reaction mixture further comprises bis(2-dimethylaminoethyl) ether as an amine blowing catalyst.

8. The method of claim 7, wherein the reaction mixture further comprises triethylene diamine as an amine gelling catalyst.

9. The method of claim 6, wherein the reaction mixture further comprises a copolymer polyol, and wherein the copolymer polyol is a mixture of an ethylene oxide (EO) capped base polyol and polymer solids, and the polymer solids comprise styrene acrylonitrile (SAN).

10. The method of claim 6, comprising providing the reaction mixture to a mold such that the open cell, polyurethane foam material is a molded foam, and comprising removing the molded foam from the mold before crushing.

11. The method of claim 10, comprising performing a pressure release before removing the molded foam from the mold to vent gasses formed during the production of the reaction product.

12. The method of claim 11, wherein the crushing occurs between 60 seconds and 120 seconds after demolding.

13. The method of claim 11, comprising curing the reaction product before performing the pressure release.

14. The method of claim 1, wherein the open cell, polyurethane foam material has a natural frequency between about 2.6 hertz and about 4.6 hertz.

15. The method of claim 1, wherein the open cell, polyurethane foam material has a transmissivity of about 1.01 to about 3.5 at the natural frequency for a 25 mm to 150 mm thick cushion, wherein the transmissivity is the ratio A/Ao, Ao is an input acceleration to the cushion, A is the measured acceleration response as a result of the input acceleration, and the natural frequency is the frequency at which A/Ao is the highest.

16. The method of claim 1, wherein the reaction mixture further comprises diethanolamine (DEOA).