Oxidation catalyst systems compositions and methods thereof

• US 9,259,716 B2
• Filed: 03/22/2013
• Issued: 02/16/2016
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: Clean Diesel Technologies, Inc.
• Original Assignee: Clean Diesel Technologies, Inc.
• Inventors: Nazarpoor, Zahra
• Primary Examiner(s): Dunn, Colleen
• Assistant Examiner(s): Soliman, Haytham
• Application Number:
  US13/849,230
• Publication Number:
  US 20140274675A1
• Time in Patent Office: 1,061 Days
• Field of Search: 502/303, 502/304
• US Class Current: 1/1
• CPC Class Codes: B01D 2255/2061 Yttrium
• CPC Class Codes: B01D 2255/2063 Lanthanum
• CPC Class Codes: B01D 2255/2065 Cerium
• CPC Class Codes: B01D 2255/20761 Copper
• CPC Class Codes: B01D 2255/2092 Aluminium
• CPC Class Codes: B01D 2255/908 O2-storage component incorporated in the catalyst
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 23/66 Silver or gold
• CPC Class Codes: B01J 23/83 with rare earths or actinides
• CPC Class Codes: B01J 23/894 with rare earths or actinides
• CPC Class Codes: B01J 2523/00 Constitutive chemical elements of heterogeneous catalysts
• CPC Class Codes: B01J 2523/17 Copper
• CPC Class Codes: B01J 2523/18 Silver
• CPC Class Codes: B01J 2523/31 Aluminium
• CPC Class Codes: B01J 2523/3706 Lanthanum
• CPC Class Codes: B01J 2523/3712 Cerium
• CPC Class Codes: B01J 2523/3718 Praseodymium
• CPC Class Codes: B01J 2523/3725 Neodymium
• CPC Class Codes: B01J 2523/48 Zirconium
• CPC Class Codes: B01J 37/0036 Grinding
• CPC Class Codes: B01J 37/0244 : Coatings comprising several layers
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies

Abstract

Compositions and methods for the preparation of ZPGM oxidation catalyst systems are disclosed. ZPGM catalyst systems may be employed within catalytic converters under lean hydrocarbon, air to fuel ratio condition to oxidize toxic gases, such as carbon monoxide and other hydrocarbons that may be included in exhaust gas. ZPGM oxidation catalyst systems are completely free of PGM catalyst and may include: a substrate, a washcoat, and an overcoat. Washcoat may include silver as ZPGM catalyst, and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Overcoat of the disclosed ZPGM catalyst system may include copper and cerium as ZPGM catalysts. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems. ZPGM catalyst systems may include high surface area, low conversion temperature catalysts that may exhibit high efficiency in the conversion of exhaust gases.

Claims

1. A method of preparing an oxidation catalyst system, comprising:

mixing a powder material containing at least one of a zero platinum group metal (ZPGM) catalyst, a transition metal catalyst and a carrier material oxide with a solvent to form a ZPGM catalyst slurry; and

applying the ZPGM catalyst slurry to a substrate as at least one of a washcoat and an overcoat applied over the washcoat, wherein at least one of the washcoat and the overcoat is synthesized by co-precipitation;

wherein an average particle size of the powder is in the range of about 4 microns to about 10 microns.

2. The method of claim 1, wherein the solvent is one of water and an organic solvent.

3. The method of claim 2, wherein the organic solvent includes at least one selected from the group consisting of ethanol, diethyl ether, carbon tetrachloride, and trichloroethylene.

4. The method of claim 1, further comprising forming the powder by milling pieces of at least one of the ZPGM transition metal catalyst and the carrier material oxide metal.

5. The method of claim 1, wherein the ZPGM catalyst slurry contains at least one oxygen storage material (OSM).

6. The method of claim 5, wherein the OSM is included in the powder material mixed with the solvent.

7. The method of claim 1, wherein the method is performed in an environment having a temperature in the range of about 18°

C. to about 24°

C.

8. The method of claim 5, wherein the OSMincludes at least one of cerium, zirconium, lanthanum, yttrium, a lanthanide, and an actinide.

9. The method of claim 1, wherein at least one of the washcoat and the overcoat has a specific surface area of about 80 m²/g to about 200 m²/g.

10. The method of claim 1, further comprising forming the washcoat on the walls of the parallel flow passages of a substrate, whereby gas flowing through the flow passages contacts the washcoat on the walls of the passages.

11. The method of claim 1, further comprising, after depositing the wash coat on the substrate:

converting metal salts within the deposited washcoat into metal oxides by heating the deposited washcoat.

12. The method of claim 11, wherein the heating comprises exposure to a temperature of about 300°

C. to about 700°

C. for between about 2 hours to about 6 hours.

13. The method of claim 11, wherein the heating comprises exposure to a temperature of about 550°

C. for about 4 hours.

14. The method of claim 11, further comprising:

cooling the treated washcoat to a range of about 18°

C. to about 24°

C. and depositing the overcoat to the washcoat.

15. The method of claim 1, further comprising applying an impregnation component to at least one of the washcoat and the overcoat.

16. The method of claim 15, wherein the impregnation component includes at least one of a transition metal, an alkali, an alkaline earth metal, cerium, lanthanum, yttrium, a lanthanide, and an actinide.

17. The method of claim 16, wherein the impregnation component converts metal salts into metal oxides.

18. The method of claim 17, wherein at least one of the washcoat and the overcoat contains at least one catalyst.

19. The method of claim 16, wherein the impregnation component includes at least one impregnation step comprising:

depositing on one of the washcoat and the overcoat at least one impregnation component; and

heating the deposited impregnation component.

20. The method of claim 1, wherein the washcoat comprises silver.

21. The method of claim 1, wherein the overcoat comprises copper.

22. The method of claim 1, wherein the overcoat comprises cerium.

23. The method of claim 1, wherein the applying the ZPGM catalyst slurry to the substrate comprises vacuum dosing.