Mirror for use in humid environments, and/or method of making the same

• US 9,341,748 B2
• Filed: 08/23/2013
• Issued: 05/17/2016
• Est. Priority Date: 12/28/2011
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Green, Lisa, Den Boer, Willem, Krasnov, Alexey
• Primary Examiner(s): Hasan, Mohammed
• Assistant Examiner(s): Abdur, Rahman
• Application Number:
  US13/974,722
• Publication Number:
  US 20140055857A1
• Time in Patent Office: 998 Days
• Field of Search: 359/883, 359/884, 359/900, 427/165
• US Class Current: 1/1
• CPC Class Codes: B32B 17/10018 comprising only one glass sheet
• CPC Class Codes: B32B 17/10229 Metallic layers sandwiched by dielectric layers
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: C03C 17/38 at least one coating being a coating of an organic material
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 1/105 Protective coatings
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 5/0808 having a single reflecting layer G02B5/0883, G02B5/0891 take precedence
• CPC Class Codes: G02B 5/0858 the reflecting layers comprising a single metallic layer with one or more dielectric layers
• CPC Class Codes: G02B 5/0866 incorporating one or more organic, e.g. polymeric layers

Abstract

Certain example embodiments of this invention relate to sputtered aluminum second surface mirrors with tapes optionally provided thereto, and/or methods of making the same. The tape replaces the paint backing that conventionally is used in the mirror industry to help protect the reflecting member of the mirror from the ingress of moisture. The final layer of the thin film layer stack is selected so as to help make its interface with the tape less sensitive to moisture. Because the safety tape can remain adhered to the layer stack even in high humidity environments, such minors may be used in a potentially broader array of applications and/or environments such as, for example, bathrooms, interior and/or exterior applications in areas where there are humid climates, etc. In one of the example embodiments, the tape is a safety tape.

Claims

1. A mirror, comprising:

a glass substrate;

a multilayer thin film coating supported by the substrate, the multilayer thin film coating comprising, in order moving away from the substrate;

a first dielectric layer,

a metallic or substantially metallic layer comprising aluminum, and

a second dielectric layer, the second dielectric layer being the outermost layer of the thin film coating and having a contact angle of at least 40 degrees;

and an adhesive tape material disposed directly over and contacting the outermost layer of the multilayer thin film coating, wherein the adhesive tape material is adapted to survive seven day exposure to an 85 degree C. temperature at 85% relative humidity, as well as seven day exposure to a 49 degree C. temperature at 100% relative humidity, without peeling away from the outermost layer of the thin film coating.

2. The mirror of claim 1, wherein the second dielectric layer comprises an oxide and/or nitride of either tin or titanium.

3. The mirror of claim 2, wherein the second dielectric layer comprises sputter deposited tin oxide.

4. The mirror of claim 2, wherein the second dielectric layer comprises sputter deposited titanium oxide.

5. The mirror of claim 1, wherein the second dielectric layer comprises diamond-like carbon.

6. The mirror of claim 1, wherein the first dielectric layer comprises an oxide and/or nitride of silicon.

7. The mirror of claim 1, wherein the first dielectric layer comprises an oxide of Al, Zr, Ti, Y, Zn, or Sn.

8. The mirror of claim 1, wherein the metallic or substantially metallic layer comprising aluminum is 40-50 nm thick.

9. The mirror of claim 1, wherein at least one of the first and second dielectric layers is 1-20 nm thick.

10. The mirror of claim 9, wherein the second dielectric layer is at least about two times as thick as the first dielectric layer.

11. The mirror of claim 1, wherein the adhesive material is Category I or Category II safety tape.

12. The mirror of claim 1, wherein the adhesive material is safety tape that has an acrylic-based adhesive.

13. The mirror of claim 1, wherein the mirror has a glass side reflectance of at least 76% in the visible spectrum.

14. A mirror, comprising:

a substrate;

a multilayer thin film coating supported by the substrate, the multilayer thin film coating comprising a metallic or substantially metallic layer comprising aluminum sandwiched between inner and outer dielectric layers, the inner dielectric layer being located between at least the substrate and the metallic or substantially metallic layer comprising aluminum;

an adhesive tape directly over and contacting an outermost layer of the multilayer thin film coating, wherein the outermost layer of the multilayer thin film coating has a contact angle of at least 40 degrees; and

wherein the adhesive tape is adapted to survive seven day exposure to an 85 degree C. temperature at 85% relative humidity, as well as seven day exposure to a 49 degree C. temperature at 100% relative humidity, without peeling away from the outermost layer of the thin film coating.

15. The mirror of claim 14, wherein the adhesive tape has a peel strength of 200-500 cN/20 mm wide strip.

16. A method of making a mirror, the method comprising:

sputter-depositing on a glass substrate a coating comprising at least the following layers in the following order;

a first dielectric layer,

a metallic or substantially metallic layer comprising aluminum, and

a second dielectric layer, wherein the second dielectric layer is the outermost layer of the thin film coating and has a contact angle of at least 40 degrees; and

applying an adhesive tape material over and contacting the outermost layer of the multilayer thin film coating, wherein the adhesive tape material is safety tape that has an acrylic-based adhesive and is adapted to survive seven day exposure to an 85 degree C. temperature at 85% relative humidity, as well as seven day exposure to a 49 degree C. temperature at 100% relative humidity, with no evidence of delamination of the adhesive material and no evidence of deterioration of the coating.

17. The method of claim 16, wherein the second dielectric layer comprises SnNx, SnOxNy, TiNx, TiOxNy, or diamond-like carbon.

18. The method of claim 17, wherein the second dielectric layer consists essentially of a sub-oxidized metal oxide.

19. The method of claim 16, further comprising:

receiving, at a fabricator location, a mirror made in accordance with the method of claim 16; and

cutting the coated article into pieces of one or more respective desired sizes for making smaller mirrors.