Nonaqueous electrolyte secondary battery and separator
First Claim
Patent Images
1. A nonaqueous electrolyte secondary battery comprising:
- a positive electrode;
a negative electrode; and
a separator disposed between the positive electrode and the negative electrode,wherein the separator includesa substrate layer, anda surface layer formed on at least one principal plane of the substrate layer,wherein the surface layer contains polyvinylidene fluoride and an inorganic material particle, the inorganic material composing at least 70 wt % of the surface layer,wherein an amount of deformation against pressure of the surface layer is larger than that of the substrate layer,wherein an average particle size of the inorganic material particle is not more than 50% relative to a thickness of the surface layer, andwherein the surface layer has a three-dimensional network structure in which continuously connected fibrils made of the polyvinylidene fluoride have an average diameter of not more than 1.0 μ
m.
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Abstract
A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The separator includes a substrate layer and a surface layer formed on at least one principal plane of the substrate layer, the surface layer contains polyvinylidene fluoride and an inorganic material particle, and an amount of deformation against pressure of the surface layer is larger than that of the substrate layer.
10 Citations
10 Claims
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1. A nonaqueous electrolyte secondary battery comprising:
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a positive electrode; a negative electrode; and a separator disposed between the positive electrode and the negative electrode, wherein the separator includes a substrate layer, and a surface layer formed on at least one principal plane of the substrate layer, wherein the surface layer contains polyvinylidene fluoride and an inorganic material particle, the inorganic material composing at least 70 wt % of the surface layer, wherein an amount of deformation against pressure of the surface layer is larger than that of the substrate layer, wherein an average particle size of the inorganic material particle is not more than 50% relative to a thickness of the surface layer, and wherein the surface layer has a three-dimensional network structure in which continuously connected fibrils made of the polyvinylidene fluoride have an average diameter of not more than 1.0 μ
m. - View Dependent Claims (2, 3, 4, 5, 6)
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7. A separator comprising:
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a substrate layer; and a surface layer formed on at least one principal plane of the substrate layer, wherein the surface layer contains polyvinylidene fluoride and an inorganic material particle, the inorganic material composing at least 70 wt % of the surface layer, wherein an amount of deformation against pressure of the surface layer is larger than that of the substrate layer, wherein an average particle size of the inorganic material particle is not more than 50% relative to a thickness of the surface layer, and wherein the surface layer has a three-dimensional network structure in which continuously connected fibrils made of the polyvinylidene fluoride have an average diameter of not more than 1.0 μ
m. - View Dependent Claims (8, 9, 10)
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Specification