Methods for selecting and applying a layer of Cu—Mn spinel phase to ZPGM catalyst systems for TWC application

• US 9,433,930 B2
• Filed: 11/26/2013
• Issued: 09/06/2016
• Est. Priority Date: 11/26/2013
• Status: Active Grant

• Current Assignee: Clean Diesel Technologies, Inc.
• Original Assignee: Clean Diesel Technologies, Inc.
• Inventors: Nazarpoor, Zahra
• Primary Examiner(s): Hailey, Patricia L
• Application Number:
  US14/090,809
• Publication Number:
  US 20150148215A1
• Time in Patent Office: 1,015 Days
• Field of Search: 502/345, 502/354, 502/355, 502/324, 502/349, 502/524
• US Class Current: 1/1
• CPC Class Codes: B01D 2255/20715 Zirconium
• CPC Class Codes: B01D 2255/2073 Manganese
• CPC Class Codes: B01D 2255/20761 Copper
• CPC Class Codes: B01D 2255/209 Other metals
• CPC Class Codes: B01D 2255/40 Mixed oxides
• CPC Class Codes: B01D 2255/65 Catalysts not containing noble metals
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 23/005 Spinels
• CPC Class Codes: B01J 23/8892 Manganese
• CPC Class Codes: B01J 2523/00 Constitutive chemical elements of heterogeneous catalysts
• CPC Class Codes: B01J 2523/17 Copper
• CPC Class Codes: B01J 2523/31 Aluminium
• CPC Class Codes: B01J 2523/48 Zirconium
• CPC Class Codes: B01J 2523/56 Niobium
• CPC Class Codes: B01J 2523/72 Manganese
• CPC Class Codes: B01J 37/0244 Coatings comprising several layers
• CPC Class Codes: B01J 37/035 Precipitation on carriers
• CPC Class Codes: B01J 37/038 to form slurries or suspensions, e.g. a washcoat
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

The present disclosure relates to selecting the layer of applying ZPGM active phase in washcoat, or applying ZPGM active phase in overcoat, for achieving optimized performance and enhanced thermal stability. Applying ZPGM active phase catalyst in overcoat shows improvements compare to applying ZPGM active phase in washcoat. The selected active phase material may include a chemical composition that is substantially free from PGM, including a formulation of stoichiometric Cu—Mn spinel structure active phase deposited on Niobium-Zirconium support oxide. The selected active phase layer applied in overcoat may include a washcoat of alumina coated on a suitable ceramic substrate. The disclosed active phase may be applied in overcoat to maximize efficiency of catalyst systems, which may exhibit enhanced catalytic activity properties, which may stable after aging and under steady state and oscillating condition, showing optimized performance purifying gases in TWC condition.

Claims

1. A method for optimizing a catalytic component, comprising:

applying to a substrate a first washcoat comprising AL₂0₃,

applying to the substrate of a second washcoat or an overcoat having at least one active phase catalyst composition comprising Cu—

Mn and a support oxide comprising Nb₂0₅-Zr0₂, wherein a loading of Cu—

Mn in the catalyst composition is from 25 to 34%, and a loading of the Nb₂0₅-Zr0₂ in the catalyst composition is from 66 to 75%, based on a total loading of the catalyst composition.

2. The method of claim 1, wherein the substrate comprises cordierite.

3. The method of claim 1, wherein the substrate comprises ceramics.

4. The method of claim 1, wherein the substrate comprises a honeycomb structure.

5. The method of claim 1, wherein the at least one active phase catalyst is an aqueous slurry.

6. The method of claim 1, wherein the at least one active phase catalyst comprises at least one spinel structure.

7. The method of claim 1, wherein the Cu—

Mn is stoichiometric.

8. The method of claim 1, wherein the at least one active catalyst is calcined at about 600°

C.

9. The method of claim 1, wherein the least one active phase catalyst is substantially free from platinum group metals.

10. The method of claim 1, wherein the least one active phase catalyst is made by a co-precipitation method.

11. The method of claim 1, wherein the least one active phase catalyst is applied in the second washcoat.

12. The method of claim 11, wherein the least one active phase catalyst is applied as a powder.

13. The method of claim 11, wherein the least one active phase catalyst is applied as a slurry.

14. The method of claim 1, wherein the least one active phase catalyst has a higher catalytic activity when substantially contained in the overcoat.

15. The method of claim 1, wherein the least one active phase catalyst has a higher stability when substantially contained in the overcoat.

16. The method of claim 1, wherein a loading of Cu in the catalyst composition is from 8 to 13%.

17. The method of claim 1, wherein a loading of Mn in the catalyst composition is from 16 to 21%.

18. A method for optimizing a catalytic component, comprising:

applying to a substrate a first washcoat comprising AL₂0₃,

applying to the substrate of a second washcoat or an overcoat having at least one active phase catalyst composition consisting of Cu—

Mn and a support oxide of Nb₂0₅-Zr0₂.