Mixed hydrophilic/hydrophobic fiber media for liquid-liquid coalescence

• US 9,474,989 B2
• Filed: 01/06/2014
• Issued: 10/25/2016
• Est. Priority Date: 01/13/2009
• Status: Active Grant

• Current Assignee: University of Akron
• Original Assignee: University of Akron
• Inventors: Chase, George, Kulkarni, Prashant
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US14/147,824
• Publication Number:
  US 20140116947A1
• Time in Patent Office: 1,023 Days
• Field of Search: 210/799, 210/503, 210/505, 210/508, 210/509, 210/497.01, 210/DIG.5, 210/500.1, 210/502.1
• US Class Current: 1/1
• CPC Class Codes: B01D 17/0202 by ab- or adsorption
• CPC Class Codes: B01D 17/045 with coalescers
• CPC Class Codes: B01D 17/10 with stationary filtering elements
• CPC Class Codes: B01D 39/04 Organic material, e.g. cellulose, cotton
• CPC Class Codes: B01D 39/06 Inorganic material, e.g. asbestos fibres, glass beads or fibres

Abstract

An immiscible lipophilic or hydrophilic liquid phase separated respectively from a continuous hydrophilic phase or a lipophilic phase liquid. Fibers having hydrophilic and hydrophobic properties are formed into a filter. The separation mechanism involves capture of small droplets of the immiscible phase, coalescence of the small droplets into larger droplets as the immiscible liquid flows through the fiber filter, and release of the large immiscible droplets from the filter. Regarding separation of a hydrophilic immiscible fluid such as water in a lipophilic continuous fluid such as oil, the hydrophobic fibers cause small water droplets to migrate towards the hydrophilic fibers whereby large droplets form on hydrophilic surface. The large droplets stay on hydrophilic fiber surface for extended periods of time and continue to coalescence until they are so large that they can no longer be maintained by the hydrophilic fibers and are released and drained off of the filter.

Claims

1. A process for removing an immiscible lipophilic liquid from a continuous hydrophilic liquid phase or an immiscible hydrophilic liquid from a continuous lipophilic liquid phase, comprising the steps of:

forming a filter containing hydrophobic fibers and hydrophilic fibers;

flowing a liquid composition through the filter, where the liquid composition is selected from the group consisting of an immiscible lipophilic liquid in a continuous hydrophilic liquid phase and an immiscible hydrophilic liquid in a continuous lipophilic liquid phase;

capturing the immiscible lipophilic liquid or the immiscible hydrophilic liquid;

coalescing the captured immiscible lipophilic liquid or immiscible hydrophilic liquid; and

removing the coalesced immiscible lipophilic liquid or immiscible hydrophilic liquid from the filter,

wherein the hydrophobic fibers comprise one or more polymers selected from the group consisting of polyethylene, polypropylene, nomex, polyester, a halogen-containing polymer, rubber, polyurethane, polycarbonate, and a silicone polymer; and

wherein the hydrophilic fibers comprise one or more glasses selected from the group consisting of sodium glass, boron glass, phosphate glass, and B-glass.

2. The process of claim 1, wherein the weight ratio of the hydrophobic fibers to the hydrophilic fibers is from about 90 wt. % to about 10 wt. % with the remaining weight percent being the hydrophilic fibers, and wherein the filter has a wettability L/H ratio of from about 1 to about 3,000.

3. The process of claim 1, wherein the hydrophobic fibers are selected from the group consisting of polyethylene, polypropylene, polyester, and halogen-containing fibers, and wherein the hydrophilic fibers are glass fibers.

4. The process of claim 1, wherein the average fiber diameter of the hydrophobic fibers and the average fiber diameter of the hydrophilic fibers are generally similar so that the pore sizes formed by the fibers are about the same throughout the filter.

5. A process for removing an immiscible lipophilic liquid from a continuous hydrophilic liquid phase or an immiscible hydrophilic liquid from a continuous lipophilic liquid phase, comprising the steps of:

forming a filter containing hydrophobic fibers and hydrophilic fibers;

flowing a liquid composition through the filter, where the liquid composition is selected from the group consisting of an immiscible lipophilic liquid in a continuous hydrophilic liquid phase and an immiscible hydrophilic liquid in a continuous lipophilic liquid phase;

capturing the immiscible lipophilic liquid or the immiscible hydrophilic liquid;

coalescing the captured immiscible lipophilic liquid or immiscible hydrophilic liquid; and

removing the coalesced immiscible lipophilic liquid or immiscible hydrophilic liquid from the filter,

wherein the weight ratio of the hydrophobic fibers to the hydrophilic fibers is from about 90 wt. % to about 10 wt. % with the remaining weight percent being the hydrophilic fibers, wherein the filter has a wettability L/H ratio of from about 2 to about 200, the average fiber diameter of the hydrophobic fibers is from about 0.1 to about 500 microns, and the average fiber diameter of the hydrophilic fibers is from about 0.1 to about 500 microns.

6. The process of claim 5, wherein the average fiber diameter of the hydrophobic fibers is from about 0.5 to about 50 microns, and the average fiber diameter of the hydrophilic fibers is from about 0.5 to about 50 microns.

7. The process of claim 6, wherein the weight ratio of the hydrophobic fibers to the hydrophilic fibers ranges from about 70 wt. % to about 30 wt. % with the remaining weight percent being the hydrophilic fibers, wherein the average fiber diameter of the hydrophobic and the hydrophilic fibers, independently, is from about 1 to about 10 microns, and wherein the L/H ratio is from about 2 to about 150.

8. A process for removing an immiscible lipophilic liquid from a continuous hydrophilic liquid phase or an immiscible hydrophilic liquid from a continuous lipophilic liquid phase, comprising the steps of:

forming a filter containing hydrophobic fibers and hydrophilic fibers;

flowing a liquid composition through the filer, where the liquid composition is selected from the group consisting an immiscible lipophilic liquid in a continuous hydrophilic liquid phase and an immiscible hydrophilic liquid in a continuous lipophilic liquid;

capturing the immiscible lipophilic liquid or the immiscible hydrophilic liquid;

coalescing the captured immiscible lipophilic liquid or the immiscible hydrophilic liquid; and

removing the coalesced immiscible lipophilic liquid or immiscible hydrophilic liquid from the filter,

wherein the hydrophobic fibers comprises one or more minerals, and hydrophobic fibers comprising a silane coating thereon;

wherein the hydrophilic fiber comprises one or more minerals or one or more metals.

9. The process of claim 8, wherein the hydrophobic fibers comprise one or more minerals.

10. The process of claim 9, wherein the hydrophobic fibers comprise zinc oxide.

11. The process of claim 8, wherein the hydrophobic fibers comprise a silane coating thereon.

12. The process of claim 8, wherein the hydrophilic fibers comprise one or more minerals.

13. The process of claim 12, wherein the hydrophilic fibers comprise one or more of alumina, titania, and silica.

14. The process of claim 8, wherein the hydrophilic fibers comprise one or more metals.

15. The process of claim 14, wherein the hydrophilic fibers comprise one or more of aluminum and aluminum alloys.