Glass articles with infrared reflectivity and methods for making the same

• US 9,487,441 B2
• Filed: 10/25/2012
• Issued: 11/08/2016
• Est. Priority Date: 10/28/2011
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Borrelli, Nicholas Francis, Koch, Karl William III, Schroeder, Joseph Francis III
• Primary Examiner(s): Sample, David
• Assistant Examiner(s): Gugliotta, Nicole T
• Application Number:
  US14/353,172
• Publication Number:
  US 20140356604A1
• Time in Patent Office: 1,475 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C03C 15/00 Surface treatment of glass, not in the form of fibres or filaments, by etching etching or surface-brightening compositions, in general C09K13/00
• CPC Class Codes: C03C 21/002 to perform ion-exchange between alkali ions C03C21/005 takes precedence
• CPC Class Codes: C03C 21/005 to introduce in the glass such metals or metallic ions as Ag, Cu
• CPC Class Codes: C03C 23/007 by thermal treatment
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

Glass articles with infrared reflectivity and methods for making the same are disclosed herein. In one embodiment, glass article having infrared reflectivity includes a first surface, a second surface and a body extending between the first and second surfaces. A plurality of discrete layers of metallic silver are formed in the body creating at least one optical cavity in the body. Each discrete layer may have a thickness T such that 100 nm≦T≦250 nm and may be spaced apart from adjacent layers of metallic silver by a spacing S≦500. The glass article reflects at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 800 nm to 2500 nm and transmits at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 390 nm to 750 nm.

Claims

1. A glass article having infrared reflectivity, the glass article comprising:

a first glass surface, a second glass surface and a glass body, wherein the glass of the glass body extends from the first glass surface to the second glass surface;

a plurality of discrete layers of metallic silver formed in the glass body, each of the plurality of discrete layers of metallic silver having a thickness T such that 100 nm≦

T≦

250 nm, wherein each of the plurality of discrete layers of metallic silver is spaced apart from an adjacent layer of metallic silver by a spacing S such that S≦

500 nm thereby forming at least one optical cavity in the glass body, wherein;

the glass article reflects at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 800 nm to 2500 nm; and

the glass article transmits at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 390 nm to 750 nm.

2. The glass article of claim 1, wherein the glass article has an infrared reflectance R_IR such that 25%≦

R_IR≦

50% for wavelengths of electromagnetic radiation incident on the glass article within a wavelength range from 800 nm to 2500 nm.

3. The glass article of claim 1, wherein the glass article has a visible transmittance T_V such that 10%≦

T_V≦

20% for wavelengths of electromagnetic radiation incident on the first surface of the glass article within a wavelength range from 390 nm to 750 nm.

4. The glass article of claim 1, wherein a first layer of the plurality of discrete layers is spaced apart from the first surface by a distance D, wherein D≦

5 μ

m.

5. The glass article of claim 1 further comprising a layer of compressive stress extending into the glass body of the glass article, the layer of compressive stress having a depth of layer DOL of up to about 60 μ

m and magnitude of compression C≧

200 MPa.

6. A method for forming a glass article with infrared reflectivity, the method comprising:

providing an ion-exchangeable glass article having a first glass surface, a second glass surface and a glass body, wherein the glass of the glass body extends from the first glass surface to the second glass surface;

exchanging sodium ions in the glass article for silver ions; and

forming the silver ions in the glass article into a plurality of discrete layers of metallic silver in the glass body of the glass article, wherein each layer of the plurality of discrete layers of metallic silver is contained within the glass body of the glass article and is spaced apart from an adjacent layer of metallic silver such that the plurality of discrete layers of metallic silver form at least one optical cavity in the glass article,

wherein each of the plurality of discrete layers of metallic silver have a thickness T such that 100 nm≦

T≦

250 nm, and wherein each of the plurality of discrete layers of metallic silver is spaced apart from an adjacent layer of metallic silver by a spacing S such that S≦

500 nm, wherein;

the glass article reflects at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 800 nm to 2500 nm; and

the glass article transmits at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 390 nm to 750 nm.

7. The method of claim 6, wherein sodium ions are exchanged for the silver ions by positioning the glass article in a salt bath comprising from about 0.05 wt. % to about 5 wt. % AgNO₃ and from about 95 wt. % to about 99.95 wt. % of MNO₃, wherein M is an alkali metal ion and the salt bath has a bath temperature from about 300°

C. to about 500°

C. to facilitate diffusion of Ag⁺¹ ions into the glass article.

8. The method of claim 7, wherein the glass article is held in the salt bath for an ion exchange period P, wherein 5 min.≦

P≦

1 h.

9. The method of claim 6, wherein the silver ions in the glass article are formed into the plurality of discrete layers of metallic silver by:

positioning the glass article in flowing hydrogen gas; and

heating the glass article in the flowing hydrogen gas to a reducing temperature from about 250°

C. to about 500°

C. for a treatment period Q to form the plurality of discrete layers of metallic silver in the glass body of the glass article, wherein 5 minutes≦

Q≦

50 h.

10. The method of claim 9, wherein the reducing temperature is 300°

C. or less.

11. The method of claim 6, wherein a first layer of the plurality of discrete layers is spaced apart from the first surface by a distance D, wherein D≦

5 μ

m.

12. The method of claim 6, further comprising a preliminary step of:

positioning the glass article in a salt bath comprising KNO₃ at a bath temperature from about 300°

C. to about 500°

C. to diffuse K⁺¹ ions into the glass article thereby forming a layer of compressive stress in the glass article prior to positioning the glass article in the salt bath comprising AgNO₃ and MNO₃.

13. The method of claim 12, wherein the layer of compressive stress extends into the glass body to a depth of layer DOL of up to about 60 μ

m and a magnitude of compression C of the layer of compressive stress is ≧

200 MPa.

14. The method of claim 6, further comprising etching the glass article in an acid solution to selectively remove one or more discrete layers of metallic silver to achieve a desired reflectance of electromagnetic radiation incident on the glass article.