Process for producing acetic acid

• US 9,505,691 B2
• Filed: 10/02/2015
• Issued: 11/29/2016
• Est. Priority Date: 10/02/2014
• Status: Active Grant

• Current Assignee: Celanese International Corporation (Celanese Corporation)
• Original Assignee: Celanese International Corporation (Celanese Corporation)
• Inventors: Shaver, Ronald David
• Primary Examiner(s): Valenrod, Yevegeny
• Assistant Examiner(s): Doletski, Blaine G
• Application Number:
  US14/874,369
• Publication Number:
  US 20160102036A1
• Time in Patent Office: 424 Days
• US Class Current: 1/1
• CPC Class Codes: C07C 51/00 Preparation of carboxylic acids or their salts, halides or anhydrides of acids by hydrolysis of oils, fats or waxes C11C
• CPC Class Codes: C07C 51/09 from carboxylic acid esters or lactones
• CPC Class Codes: C07C 51/12 on an oxygen-containing group in organic compounds, e.g. alcohols
• CPC Class Codes: C07C 51/44 by distillation
• CPC Class Codes: C07C 53/08 Acetic acid pyroligneous acid C10C; preparation of vinegar C12J

Abstract

Process for producing acetic acid is disclosed in which the reaction medium is separated into a liquid recycle and a vapor product stream including acetic acid, methyl iodide, methyl acetate and water in a flash vessel. The vapor product stream is condensed into a liquid stream that is enriched in acetic acid and this liquid stream is further sent to the distillation columns to recover acetic acid. The process advantageously improves the capacity of the acetic acid production while reducing the amount of acetic acid that is recycled.

Claims

1. A process for producing acetic acid comprising:

carbonylating at least one reactant selected from the group consisting of methanol, dimethyl ether, methyl acetate, and mixtures thereof, in the presence of 0.1 to 14 wt. % water, a metal catalyst, methyl iodide and iodide salt to form a reaction medium in a reactor;

separating the reaction medium into a liquid recycle and a vapor product stream including acetic acid, methyl iodide, methyl acetate and water;

condensing a first portion of the vapor product stream to form a liquid stream;

feeding a second portion of the vapor product stream to a first column;

feeding at least a portion of the liquid stream to the first column; and

withdrawing a side stream from the first column comprising an acetic acid product,

wherein the liquid stream is fed to the first column above the feed of the second portion of the vapor product stream and wherein the liquid stream is fed to the first column below the point at which the side stream comprising the acetic acid product is withdrawn from the first column.

2. The process of claim 1, wherein 1 to 50 wt. % of the vapor product stream is condensed to form the liquid stream, and wherein 50 to 99 wt. % of the vapor product stream is fed to the first column.

3. The process of claim 1, wherein at least 10 wt % of the liquid stream is fed to the first column.

4. The process of claim 1, further comprising:

feeding the side stream comprising the acetic acid product to a second column to obtain an acetic acid purified product.

5. The process of claim 4, wherein at least a portion of the liquid stream is introduced into the second column.

6. The process of claim 1, wherein the reaction is conducted while maintaining the reaction medium at concentrations of 1 to 25 wt. % iodide salt, 1 to 25 wt. % methyl iodide, 0.5 to 30 wt. % methyl acetate, and 0.1 to 14 wt. % water.

7. The process of claim 1, wherein the reactor further comprises a cooling unit.

8. The process of claim 1, wherein the liquid stream comprises from 65 to 95 wt. % acetic acid.

9. The process of claim 1, wherein the liquid stream is enriched in acetic acid compared to the second portion of the vapor product stream.

10. The process of claim 1, wherein carbon monoxide efficiency in the reactor is maintained above 90%.

11. A process for producing acetic acid comprising:

carbonylating at least one reactant selected from the group consisting of methanol, dimethyl ether, methyl acetate, and mixtures thereof in the presence of 0.1 to 14 wt. % water, a metal catalyst, methyl iodide and iodide salt to form a reaction medium in a reactor;

separating the reaction medium into a liquid recycle and a vapor product stream including acetic acid, methyl iodide, methyl acetate and water in a flash vessel having an optional upper scrubbing section;

condensing a first portion of the vapor product stream to form a liquid product stream;

feeding a second portion of the vapor product stream to a first column;

withdrawing a side stream comprising an acetic acid product from the first column;

feeding the side stream to a second column;

feeding at least a portion of the liquid product stream to the second column; and

obtaining an acetic acid purified product from the second column,

wherein the liquid stream is fed to the second column above the feed of the side stream.

12. The process of claim 11, wherein 1 to 50 wt % of the vapor product stream is condensed to form the liquid stream and wherein 50 to 99 wt % of the vapor product stream is fed as the second portion to the first column.

13. The process of claim 11, wherein at least 10 wt % of the liquid stream is fed to the second column.

14. The process of claim 11, wherein at least a portion of the liquid stream is introduced into the first column.

15. The process of claim 11, further comprising directing a bottom stream from the first column, a bottom stream from the second column, an overhead stream from the second column, or a combination thereof into the upper scrubbing section in an amount sufficient to remove at least a portion of the catalyst entrained in the vapor product stream.

16. The process of claim 11, wherein the liquid stream comprises from 65 to 95 wt. % acetic acid.

17. The process of claim 11, wherein the liquid stream comprises an amount equal to or greater than the amount of acetic acid in the side stream.