Method for making marco-scale carbon nanotube tube structure

• US 9,523,162 B2
• Filed: 03/14/2011
• Issued: 12/20/2016
• Est. Priority Date: 08/23/2010
• Status: Active Grant

• Current Assignee: Hon Hai Precision Industry Co., Ltd., Tsinghua University
• Original Assignee: Hon Hai Precision Industry Co., Ltd., Tsinghua University
• Inventors: Wei, Yang, Fan, Shou-Shan
• Primary Examiner(s): OCHYLSKI, RYAN M
• Application Number:
  US13/046,955
• Publication Number:
  US 20120043012A1
• Time in Patent Office: 2,108 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C01B 32/16 Preparation
• CPC Class Codes: D01D 5/24 with a hollow structure; Spinnerette packs therefor D01D5/38 takes precedence; producing tubes of plastic material B29D; addition of agents forming hollow filaments D01F1/08
• CPC Class Codes: D01F 9/12 Carbon filaments; Apparatus specially adapted for the manufacture thereof
• CPC Class Codes: Y10T 428/2918 including free carbon or carbide or therewith [not as steel]
• CPC Class Codes: Y10T 428/292 In coating or impregnation

Abstract

A method for making a macro-scale carbon nanotube tube structure includes the following steps. A linear structure and a carbon nanotube structure are provided. The carbon nanotube structure includes at least one carbon nanotube film or at least one carbon nanotube wire. The carbon nanotube structure is wrapped around the linear structure to form a carbon nanotube composite structure. The linear structure is removed from the carbon nanotube composite structure, thereby forming the macro-scale carbon nanotube tube structure.

Claims

1. A method for making a macro-scale carbon nanotube tube structure, the method comprising:

(a) providing a linear structure and a carbon nanotube structure comprising at least one carbon nanotube film or at least one carbon nanotube wire, wherein a material of the linear structure is metal;

providing the linear structure and the carbon nanotube structure comprises;

providing a supply unit having a guiding shaft and providing a bobbin;

coiling the linear structure around the bobbin; and

suspending the bobbin wound around the linear structure on the guiding shaft;

(b) wrapping the carbon nanotube structure around the linear structure to form a carbon nanotube composite structure; and

(c) removing the linear structure from the carbon nanotube composite structure.

2. The method of claim 1, wherein an outline of a cross section of the linear structure along a direction substantially perpendicular to an extending direction of the linear structure is rectangular, trapezoid shaped, circle shaped, or ellipse shaped.

3. The method of claim 1, wherein step (b) further comprises:

(b1) fixing one end of the carbon nanotube structure on the linear structure; and

(b2) making a relative motion between the carbon nanotube structure and the linear structure to wrap the carbon nanotube structure around the linear structure.

4. The method of claim 1, wherein the at least one carbon nanotube film or at least one carbon nanotube wire comprises a plurality of carbon nanotubes;

in step (b) the carbon nanotubes in the carbon nanotube structure are joined together by van der Waals to form the carbon nanotube composite structure.

5. The method of claim 1, wherein step (a) further comprises:

providing a wrapping unit comprising a hollow rotating shaft and a face plate mounted on the hollow rotating shaft, the face plate comprising a support stage;

providing a carbon nanotube array with a growing substrate;

fixing the growing substrate on the support stage; and

drawing a drawn carbon nanotube film or an untwisted carbon nanotube wire from the carbon nanotube array.

6. The method of claim 5, wherein step (b) further comprises:

providing a collecting unit comprises a collecting shaft being rotatable;

fixing one end of the linear structure on the collecting shaft;

adhering the drawn carbon nanotube film or the untwisted carbon nanotube wire to the linear structure; and

rotating the face plate and the collecting shaft such that the linear structure moves along a fixed direction, while the drawn carbon nanotube film or the untwisted carbon nanotube wire are simultaneously drawn from the carbon nanotube array and wound around the linear structure to form the carbon nanotube composite structure.

7. The method of claim 6, wherein step (b) further comprises a step of treating the carbon nanotube composite structure using an organic solvent.

8. The method of claim 1, wherein step (c) is executed by a chemical method or a physical method.

9. The method of claim 1, wherein step (c) further comprises:

applying the carbon nanotube composite structure into an acidic liquid; and

reacting the linear structure with the acidic liquid.

10. The method of claim 1, wherein if the linear structure is made of gold, silver, or an alloy thereof, step (c) further comprises heating the carbon nanotube composite structure to evaporate the linear structure.

11. The method of claim 1, wherein step (c) further comprises pulling the linear structure out from the carbon nanotube composite structure using a stretching device along the axial direction of the linear structure.

12. A method for making a macro-scale carbon nanotube tube structure, the method comprising:

(a) providing a supply unit, a collecting unit, and a wrapping unit located between the supply unit and the collecting unit, the wrapping unit comprising a hollow rotating shaft and a face plate mounted on the hollow rotating shaft, and supplying a linear structure by the supply unit;

(b) passing the linear structure through the hollow rotating shaft and fixing the linear structure on the collecting unit;

(c) applying a carbon nanotube array on the face plate, and drawing a carbon nanotube structure from the carbon nanotube array, and adhering one end of the carbon nanotube structure to the linear structure;

(d) rotating the face plate and pulling the linear structure along a fixed direction such that the carbon nanotube structure wraps around the linear structure, thereby forming a carbon nanotube composite structure; and

(e) removing the linear structure from the carbon nanotube composite structure.

13. The method of claim 12, wherein the supply unit comprises a pedestal and a guiding shaft fixed on the pedestal, and the step (a) further comprises:

winding a bobbin with the linear structure; and

hanging the bobbin wound by the linear structure on the guiding shaft, the bobbin being movable around the guiding shaft.

14. The method of claim 12, wherein the step (c) further comprises:

(c1) growing the carbon nanotube array on a growing substrate;

(c2) fixing the growing substrate with the carbon nanotube array grown thereon on the face plate;

(c3) drawing a drawn carbon nanotube film or an untwisted carbon nanotube wire from the carbon nanotube array; and

(c4) adhering the drawn carbon nanotube film or the untwisted carbon nanotube wire to the linear structure.

15. The method of claim 12, wherein the collecting unit comprises a collecting shaft being rotatable around a second axis thereof, and the step (d) further comprises:

(d1) rotating the collecting shaft to move the linear structure along the fixed direction and drawing the carbon nanotube structure from the carbon nanotube array;

(d2) rotating the face plate to rotate the carbon nanotube structure around the linear structure, thereby forming the carbon nanotube composite structure; and

(d3) winding the carbon nanotube composite structure around the collecting shaft to form the carbon nanotube composite structure.

16. A method for making a macro-scale carbon nanotube tube structure, the method comprising:

(a) providing a supply unit, a wrapping unit, and a collecting unit, the supply unit comprising a pedestal, a guiding shaft fixed on the pedestal, and a bobbin hung on the guiding shaft, the wrapping unit comprising a hollow rotating shaft rotatable around a first axis thereof, and a face plate mounted on the hollow rotating shaft, the collecting unit comprising a collecting shaft rotatable around a second axis thereof, and the second axis of the collecting shaft being substantially perpendicular to the first axis of the hollow rotating shaft;

(b) supplying a linear structure by the bobbin;

(c) passing the linear structure through the hollow rotating shaft and fixing the linear structure on the collecting shaft;

(d) applying a carbon nanotube array on the face plate;

(e) drawing a carbon nanotube structure from the carbon nanotube array, and adhering one end of the carbon nanotube structure to the linear structure;

(f) rotating the hollow rotating shaft around the first axis thereof, and simultaneously rotating the collecting shaft around the second axis thereof, thereby forming a carbon nanotube composite structure; and

(g) removing the linear structure from the carbon nanotube composite structure.

17. The method of claim 16, wherein the wrapping unit further comprises a drive mechanism comprising a first motor, and an actuator mounted on the first motor and the hollow rotating shaft, and in step (f), the step of rotating the hollow rotating shaft further comprises:

operating the first motor to cause the actuator to rotate the hollow rotating shaft around the first axis thereof such that the face plate is rotated around the first axis of the hollow rotating shaft, wherein the carbon nanotube array is rotated around the linear structure, such that the carbon nanotube structure is wrapped around the linear structure to form the carbon nanotube composite structure.

18. The method of claim 17, wherein the collecting unit further comprises a second motor, and the collecting shaft is mounted on the second motor, and in step (f), the step of pulling the linear structure further comprises:

operating the second motor to rotate the collecting shaft around the second axis thereof such that the linear structure is drawn from the bobbin along a fixed direction, the carbon nanotube structure is drawn from the carbon nanotube array, and the carbon nanotube composite structure is wrapped around the collecting shaft.