High performance moldable composite

• US 9,533,630 B2
• Filed: 10/05/2015
• Issued: 01/03/2017
• Est. Priority Date: 10/29/2014
• Status: Active Grant

• Current Assignee: Nonwoven Network LLC
• Original Assignee: Nonwoven Network LLC
• Inventors: Foss, Stephen W., Turra, Jean-Marie
• Primary Examiner(s): Phillips, Forrest M
• Application Number:
  US14/874,947
• Publication Number:
  US 20160121814A1
• Time in Patent Office: 456 Days
• Field of Search: 181/290
• US Class Current: 1/1
• CPC Class Codes: B29C 48/0018 combined with shaping by orienting, stretching or shrinking, e.g. film blowing B29C48/0017 takes precedence
• CPC Class Codes: B29C 48/0021 combined with joining, lining or laminating
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 66/4722 Fixing strips to surfaces other than edge faces fixing strips to edge faces B29C63/0026
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: B29K 2105/041 Microporous
• CPC Class Codes: B29K 2105/045 with open cells
• CPC Class Codes: B29K 2105/25 Solid
• CPC Class Codes: B29K 2995/0001 having particular acoustical properties
• CPC Class Codes: B29K 2995/0016 Non-flammable or resistant to heat
• CPC Class Codes: B29L 2031/3005 Body finishings
• CPC Class Codes: B32B 2262/0253 Polyolefin fibres vinyl or acrylic copolymers B32B2262/0223 or B32B2262/0246
• CPC Class Codes: B32B 2262/0284 Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
• CPC Class Codes: B32B 2262/14 Mixture of at least two fibres made of different materials
• CPC Class Codes: B32B 2266/025 Polyolefin vinyl or acrylic copolymers B32B2266/0221, B32B2266/0242
• CPC Class Codes: B32B 2307/102 Insulating
• CPC Class Codes: B32B 2605/08 Cars
• CPC Class Codes: B32B 37/203 One or more of the layers being plastic
• CPC Class Codes: B32B 5/022 Non-woven fabric
• CPC Class Codes: B32B 5/20 : foamed in situ
• CPC Class Codes: B32B 5/245 : another layer next to it being a foam layer
• CPC Class Codes: B60R 13/0815 : Acoustic or thermal insulation of passenger compartments wall or roof liners integrating the insulating function B60R13/02; insulating floor mats or carpets B60N3/04
• CPC Class Codes: D04H 1/435 : Polyesters
• CPC Class Codes: D04H 1/5412 : sheath-core
• CPC Class Codes: D04H 1/5418 : Mixed fibres, e.g. at least two chemically different fibres or fibre blends
• CPC Class Codes: D04H 1/558 : in combination with mechanical or physical treatments other than embossing

Abstract

A moldable composite with high heat resistance and noise absorption properties utilizes nonwoven fabrics and a heat resistance additive. The composition that provides both superior acoustic performance and excellent flex modulus that may be utilized in automotive products and applications in interior and exterior structures. A blowing agent may be utilized to create micro porous cells in a polymer non-woven structure. The cells or voids make the material lighter and allow the material to have superior acoustic properties that are useful in automotive applications.

Claims

1. A formable automotive structural non-woven composite comprising:

a blend of fibers having a plurality of high melt fibers and a plurality of low melt fibers to form a first nonwoven composite layer;

the blend of fibers further including a high melt carrier fiber of polyethylene terephthalate (PET) or polybutylene terephthalate (PBT), and a low melt binder fiber made of polyethylene glycol (PETG), Polylactic acid (PLA), Isophthallic modified PET, polyethylene, or polypropylene;

at least one of the high melt carrier fiber or the low melt fiber is a non-flame retardant fiber containing an internal flame retardant selected from the group consisting of polyphosphonates, organophosphates, phosphonates, antimony trioxide and any combination thereof;

the high melt carrier fiber and low melt binder fiber having at least a 10°

C. (19°

F.) difference in melt temperatures to allow the low melt fiber to melt during processing and stick to the high melt fibers;

a meniscus formed between bond points of the high melt carrier fiber and low melt binder fiber when the low melt binder fiber is melted and flows into interstitial spaces between the high melt carrier fiber and low melt binder fiber;

the first nonwoven composite layer having improved acoustic impedance due to a decreased nonwoven web pore sizes created by the low melt fibers when amorphous portions of the low melt binder fiber are melted during bonding wherein air flow resistance through the formable automotive structural non-woven composite is decreased due to the decreased web pore sizes and attributable to increased acoustic properties of the formable automotive structural non-woven composite;

a blown film layer disposed onto the first nonwoven composition layer as a second nonwoven composite layer and forms a multi-layer nonwoven composite, the blown film layer having controlled micro-porosity of the film for restricting air flow and furthering acoustic impedance properties of the formable automotive structural non-woven composite;

and wherein the blend of fibers further having a physical properties including a flexural modulus sufficient for automotive structural use, and heat resistance to withstand automotive engine compartment conditions and the formable composite is used as an automotive structural component for use in areas around the engine compartment or under the vehicle.

2. The formable composite of claim 1 further including a second nonwoven composite layer, the fibers having a plurality of high melt fibers and a plurality of low melt fibers, and the second layer attached to the blown film layer to form a tri-laminate.

3. The formable composite of claim 1 wherein the blend of fibers further include fiber material selected from the group consisting of polyester, nylon, acrylic, polypropylene, Polylactic acid, fiberglass and any combination thereof.

4. The formable composite in claim 1, wherein the high melt fiber and low melt binder fiber both further include a flame retardant.

5. The formable composite of claim 1 wherein the fibers are from 0.9 to 50 deniers.

6. The formable composite of claim 1 wherein the fibers are from 25 mm (1″

) to 180 MM (7.1″

) in length.

7. The formable composite of claim 1, wherein the blend of fibers further include fibers that are both high melt temperature fibers and low melt temperature fibers, and wherein the low melt and high melt temperature fibers are selected from a group consisting of polyethylene, low density polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene (HDPE), polypropylene (PP), polyvinylchloride(PVC), polyethylene terephthalate(PET), polyethylene terephalate glycol-modified (PETG),polyamide (Nylon), Ethylene Vinyl Acetate, Isophthalic modified PET, and any combination thereof.

8. The formable composite of claim 1 wherein the high melt temperature fibers range from 30 to 95% by weight in content.

9. The formable composite of claim 1 wherein the low melt temperature fibers range from 5 to 70% by weight in content.

10. The formable composite of claim 1 wherein the fibers range from 0.7 to 100 denier and a length from 12 mm to 180 mm (0.5 to 7″

).

11. The formable composite of claim 1 further includes a second a blown film layer combined with the first composite layer or a second blown film combined with the first composite layer and the second composite layer.

12. The formable composite of claim 1 wherein the blown film is defining holes formed using an inert gas during an extrusion process.

13. The formable composite of claim 12 furthering including use of an inert gas is selected from a group consisting of air, nitrogen, carbon dioxide, carbon monoxide, helium, argon, oxygen, and any combination thereof.

14. The formable composite of claim 13 wherein the holes in the blown film are formed using a blowing agent blended with the film at a weight percentage of 0.2% to 3.0%.

15. The formable composite of claim 1 wherein the holes in the blown film are formed using a blowing agent blended with the film at a weight percentage of 0.2% to 3.0%.

16. The formable composite of claim 1 wherein each nonwoven fabric layer is 50 grams per square meter (gsm) to 2000 grams per square meter (gsm).

17. The formable composite of claim 1 wherein the each nonwoven fabric layer is 50 grams per square meter (gsm) to 1,200 grams per square meter (gsm).

18. The formable composite of claim 1 wherein the porosity of air flow measures greater than 1.5 M-RAYLS.

19. The formable composite of claim 1 wherein the low melt binder fiber is blended with natural fibers such as cotton, wool, flax, jute, or mineral fibers.

20. The formable composite in claim 1 wherein the low melt binder fiber is between 5% and 75% of the composite.

21. The formable composite of claim 20 wherein the flame resistance rate is V-0.

22. A method of making a formable automotive structural non-woven composite, comprising:

extruding a high melt and a low melt nonwoven polymeric fibers and incorporating a flame resistant additive into the low melt fiber having at least one region defining holes to create a microporous open cell structure for acoustic impedance, and heat and flame resistance.

23. The method of claim 22 wherein the flame resistant additive is a polyphosphonate.

24. The method of claim 23 wherein the extruding is done below 290°

C. to avoid degradation of the polyphosphonate.

25. A method of making a formable automotive structural non-woven composite, comprising:

compounding a flame retardant into a carrier fiber, wherein the flame retardant is supportive to provide heat resistance to withstand automotive engine compartment conditions and the flame retardant is selected from a group consisting of polyphosphonate, organophosphates, phosphonates, antimony trioxide, halogens and any combination thereof; and

wherein the carrier fiber is selected from a group consisting of polyethylene glycol (PETG) cyclohexanedimethanol (CHDM), polyester, nylon, acrylic, polypropylene, polylactic acid, fiberglass, and any combination thereof;

said compounding done below 290°

C. with no heat history;

drawing the carrier fiber at a low draw ratio of approximately 2-2.5 to prevent crystallinity from occurring thereby creating an amorphous carrier fiber; and

creating a nonwoven web material having pores by combining the carrier fiber with a blend of fibers having physical properties that includes a flexural modulus sufficient for automotive structural use, wherein amorphous fibers will melt at a lower temperature filling the pores within the nonwoven material to block air and create resistance for sound.

26. The method of making a formable automotive structural non-woven composite of claim 25, further comprising:

combining a first layer nonwoven material having improved acoustic impedance due to decreased nonwoven web pore sizes with

a blown film layer to form a multi-layer nonwoven composite, the blown film having controlled micro-porosity of the film for restricting air flow and furthering acoustic impedance properties.

27. The method of making a formable automotive structural non-woven composite of claim 26, further comprising:

combining a second layer nonwoven material to the blown film layer, and

forming a tri-layer composite material that has acoustic impedance properties, moisture resistance, structural integrity, and heat resistance to withstand environmental conditions inside an automobile engine compartment and underneath the automobile'"'"'s undercarriage and wheel wells.