Production method for fluoropolymer aqueous dispersion

• US 9,574,020 B2
• Filed: 12/02/2013
• Issued: 02/21/2017
• Est. Priority Date: 11/30/2012
• Status: Active Grant

• Current Assignee: Daikin Industries Ltd
• Original Assignee: Daikin Industries Ltd
• Inventors: Nanba, Yoshinori
• Primary Examiner(s): EGWIM, KELECHI CHIDI
• Application Number:
  US14/648,366
• Publication Number:
  US 20150299341A1
• Time in Patent Office: 1,177 Days
• Field of Search: 524/805
• US Class Current: 1/1
• CPC Class Codes: C08F 14/18 Monomers containing fluorine
• CPC Class Codes: C08F 2/10 Aqueous solvent
• CPC Class Codes: C08F 2/26 anionic
• CPC Class Codes: C08L 2201/54 Aqueous solutions or dispersions
• CPC Class Codes: C08L 27/18 Homopolymers or copolymers or tetrafluoroethene

Abstract

The present invention aims to provide a method of producing a fluoropolymer aqueous dispersion having a significantly small particle size and excellent dispersion stability without using a long-chain fluorosurfactant. The present invention relates to a method of producing an aqueous dispersion containing at least one fluoropolymer selected from the group consisting of polytetrafluoroethylene and melt-processible fluororesins excluding polytetrafluoroethylene. The method includes polymerizing a fluoromonomer in an aqueous medium in the presence of a fluorosurfactant having a Log POW value of not higher than 3.4 and a polymerization initiator. The amount of the fluorosurfactant corresponds to 4600 to 500000 ppm of the aqueous medium.

Claims

1. A method of producing an aqueous dispersion containing at least one fluoropolymer selected from the group consisting of polytetrafluoroethylene and tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymers, the method comprising

polymerizing a fluoromonomer in an aqueous medium in the presence of a fluorosurfactant having a Log POW value of not higher than 3.4 and a polymerization initiator and at least one of a modifying monomer and a chain-transfer agent,

the amount of the fluorosurfactant corresponding to 18000 to 500000 ppm of the aqueous medium,

wherein the modifying monomer is at least one selected from the group consisting of hexafluoropropylene, chlorotrifluoroethylene, vinylidene fluoride, perfluoropropyl vinyl ether, perfluorobutylethylene, ethylene, perfluoromethyl vinyl ether, perfluorohexylethylene and a fluorinated vinyl ether represented by the formula CF₂═

CFORf⁹CN wherein Rf⁹ represents a C2-C7 alkylene group in which an oxygen atom may optionally be inserted between two carbon atoms,

the chain-transfer agent is at least one selected from the group consisting of methane, ethane, propane, butane, chloromethane, dichloromethane, difluoroethane, methanol, ethanol and hydrogen,

the amount of the modifying monomer is 0.02-1.49 mol % based on the sum of the amounts of the monomers supplied, and

the amount of the chain-transfer agent is 159-3000 ppm based on the sum of the amounts of the monomers supplied.

2. The method of producing a fluoropolymer aqueous dispersion according to claim 1,

wherein the fluorosurfactant is a fluorinated compound represented by the following formula (1):

X—

(CF₂)_m1—

Y 

 

(1)

wherein X represents H or F;

m1 is an integer of 3 to 5; and

Y represents —

SO₃M, —

SO₄M, —

SO₃R, —

SO₄R, —

COOM, —

PO₃M₂, or —

PO₄M₂, where M represents H, NH₄, or an alkali metal, and R represents a C1-C12 alkyl group.

3. The method of producing a fluoropolymer aqueous dispersion according to claim 1,

wherein the polymerization is performed in the absence of a fluorinated compound represented by the following formula (2):

X—

(CF₂)_m2—

Y 

 

(2)

wherein X represents H or F;

m2 is an integer of 6 or greater; and

Y represents —

SO₃M, —

SO₄M, —

SO₃R, —

SO₄R, —

COOM, —

PO₃M₂, or —

PO₄M₂, where M represents H, NH₄, or an alkali metal, and R represents a C1-C12 alkyl group.

4. The method of producing a fluoropolymer aqueous dispersion according to claim 1,

wherein the fluoropolymer has a volume average particle size of not smaller than 0.1 nm but smaller than 20 nm.

5. The method of producing a fluoropolymer aqueous dispersion according to claim 1,

wherein the polymerization initiator is at least one selected from the group consisting of persulfates and organic peroxides.

6. The method of producing a fluoropolymer aqueous dispersion according to claim 1,

wherein the amount of the polymerization initiator corresponds to 1 to 5000 ppm of the aqueous medium.