Thermoplastic resin composition and molded products thereof

• US 9,631,087 B2
• Filed: 12/05/2012
• Issued: 04/25/2017
• Est. Priority Date: 12/19/2011
• Status: Active Grant

• Current Assignee: Lotte Advanced Materials Co., Ltd. (Lotte Chemical Corporation)
• Original Assignee: Lotte Advanced Materials Co., Ltd. (Lotte Chemical Corporation)
• Inventors: Chung, Jin Hwa, Kwon, Kee Hae, Jang, Joo Hyun, Goo, Ja Kwan, Park, Kwang Soo
• Primary Examiner(s): PENG, KUO LIANG
• Application Number:
  US14/365,091
• Publication Number:
  US 20140371375A1
• Time in Patent Office: 1,602 Days
• CPC Class Codes: C08F 220/14 Methyl esters , e.g. methyl (meth)acrylate
• CPC Class Codes: C08F 220/1806 C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
• CPC Class Codes: C08L 33/10 Homopolymers or copolymers of methacrylic acid esters
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates

Abstract

A thermoplastic resin composition according to the present invention is characterized by comprising: (A) a polycarbonate resin; and (B) a biphenyl group-containing (meth)acrylic copolymer. As such, the refractive index of the biphenyl group-containing (meth)acrylic copolymer (B) can be approximately from 1.495 to 1.640. The thermoplastic resin composition exhibits superior balance of material properties such as impact strength, internal scratch resistance, transparency, thermal resistance and appearance.

Claims

1. A thermoplastic resin composition comprising:

(A) a polycarbonate resin; and

(B) a (meth)acrylic copolymer having a biphenyl group or a terphenyl group, the (B) (meth)acrylic copolymer having a weight average molecular weight of about 50,000 g/mol to about 250,000 g/mol, the (B) (meth)acrylic copolymer being derived from a monomer mixture including;

(b1) a biphenyl or terphenyl group-containing (meth)acrylate having an index of refraction from about 1.580 to about 1.700;

(b2) a monofunctional unsaturated monomer; and

(b3) an alicyclic or aromatic (meth)acrylate having an index of refraction from about 1.490 to about 1.579.

2. The thermoplastic resin composition according to claim 1, wherein the (B) (meth)acrylic copolymer has an index of refraction from about 1.495 to about 1.640.

3. The thermoplastic resin composition according to claim 1, comprising:

about 50 wt % to about 99 wt % of the (A) polycarbonate resin; and

about 1 wt % to about 50 wt % of the (B) (meth)acrylic copolymer.

4. A molded product formed from the thermoplastic resin composition according to claim 3, the molded product having a scratch width from about 180 μ

m to about 350 μ

m as measured in accordance with a Ball-type Scratch Profile Test, and a pencil hardness from 2B to 3H.

5. The thermoplastic resin composition according to claim 1, comprising:

about 1 wt % to about 49 wt % of the (A) polycarbonate resin; and

about 51 wt % to about 99 wt % of the (B) (meth)acrylic copolymer.

6. A molded product formed from the thermoplastic resin composition according to claim 5, the molded product having a total light transmittance of about 85% or greater, a scratch width of about 210 μ

m or less as measured in accordance with a Ball-type Scratch Profile Test, and a Vicat softening temperature (VST) as a measure of heat resistance of about 110°

C. or greater as measured under conditions of a load of 5 Kg at 50°

C./hr in accordance with ASTM D1525.

7. The thermoplastic resin composition according to claim 1, wherein the monomer mixture comprises about 1 wt % to about 50 wt % of (b1) the biphenyl or terphenyl group-containing (meth)acrylate having an index of refraction from about 1.580 to about 1.700, about 99 wt % or less of (b2) the monofunctional unsaturated monomer, and about 50 wt % or less of (b3) the alicyclic or aromatic (meth)acrylate having an index of refraction from about 1.490 to about 1.579.

8. The thermoplastic resin composition according to claim 1, wherein the (b1) biphenyl or terphenyl group-containing (meth)acrylate is represented by Formula 1:

9. The thermoplastic resin composition according to claim 1, wherein the (b2) monofunctional unsaturated monomer comprises at least one of a C₁ to C₈ alkyl (meth)acrylate;

an unsaturated carboxylic acid including (meth)acrylic acid;

an acid anhydride including maleic anhydride;

a hydroxyl group-containing (meth)acrylate;

(meth)acrylamide;

unsaturated nitrile;

allyl glycidyl ether;

glycidyl methacrylate; and

an aromatic vinyl monomer.

10. The thermoplastic resin composition according to claim 1, wherein the (b3) alicyclic or aromatic (meth)acrylate having the index of refraction from about 1.490 to about 1.579 comprises a compound represented by Formula 2, a compound represented by Formula 3, or mixtures thereof:

11. The thermoplastic resin composition according to claim 1, wherein the (B) (meth)acrylic copolymer has a non-crosslinked structure.

12. The thermoplastic resin composition according to claim 1, wherein the (B) (meth)acrylic copolymer has a glass transition temperature from about 90°

C. to about 150°

C., and permits extrusion or injection at a temperature higher than or equal to the glass transition temperature.

13. The thermoplastic resin composition according to claim 1, further comprising:

(C) a rubber-modified vinyl graft copolymer resin.

14. The thermoplastic resin composition according to claim 13, wherein the (C) rubber-modified vinyl graft copolymer resin has a core-shell structure in which an unsaturated monomer is grafted onto a core rubber to form a shell, the unsaturated monomer comprising at least one of a C₁ to C₁₂ alkyl (meth)acrylate, an acid anhydride, and a C₁ to C₁₂ alkyl or phenyl-nuclear substituted maleimide.

15. A molded product formed from the thermoplastic resin composition according to claim 13, the molded product having a total light transmittance of about 40% or greater, a scratch width from about 280 μ

m or less as measured in accordance with a Ball-type Scratch Profile Test, a Vicat softening temperature (VST) as a measure of heat resistance of about 105°

C. or greater as measured under conditions of a load of 5 Kg at 50°

C./hr in accordance with ASTM D1525, and a ⅛

″

Izod notch impacted strength of about 8 kg·

cm/cm or higher as measured in accordance with ASTM D256.

16. The thermoplastic resin composition according to claim 1, further comprising:

at least one additive selected from the group consisting of flame retardants, surfactants, nucleating agents, coupling agents, fillers, plasticizers, impact modifiers, lubricants, antibacterial agents, release agents, heat stabilizers, antioxidants, light stabilizers, compatibilizers, inorganic additives, antistatic agents, pigments, and dyes.

17. A molded product formed from the thermoplastic resin composition according to claim 1.