High-strength flake graphite cast iron, manufacturing method thereof, and engine body for internal combustion engine including cast iron

• US 9,719,157 B2
• Filed: 01/06/2014
• Issued: 08/01/2017
• Est. Priority Date: 01/23/2013
• Status: Active Grant

• Current Assignee: HD Hyundai Infracore Co., Ltd.
• Original Assignee: Doosan Infracore Company Limited
• Inventors: Jung, Ki Hwan, Yang, Sik, Hwang, Jae Hyoung, Ju, Young Kyu, Chung, Jong Kwon, Lee, Yeniseul, Shim, Dong Seob
• Primary Examiner(s): Cronin, Stephen K
• Assistant Examiner(s): Tran, Long T
• Application Number:
  US14/762,858
• Publication Number:
  US 20150368763A1
• Time in Patent Office: 1,303 Days
• Field of Search: 1231935, 1231932
• CPC Class Codes: C21C 1/08 Manufacture of cast-iron
• CPC Class Codes: C21D 5/00 Heat treatments of cast-iron
• CPC Class Codes: C22C 33/08 Making cast-iron alloys
• CPC Class Codes: C22C 37/00 Cast-iron alloys
• CPC Class Codes: C22C 37/04 containing spheroidal graphite
• CPC Class Codes: C22C 37/10 containing aluminium or silicon
• CPC Class Codes: F02F 1/24 Cylinder heads
• CPC Class Codes: F02F 7/0085 Materials for constructing engines or their parts

Abstract

The present disclosure relates to a manufacturing method of high-strength flake graphite cast iron, the high-strength flake graphite cast iron manufactured by the method, and an engine body including the cast iron, and more particularly, to flake graphite cast iron and a manufacturing method thereof, wherein the flake graphite cast iron has a uniform graphite shape and low probability of forming chill and has high tensile strength of at least 350 MPa and excellent workability and fluidity by controlling the content of manganese (Mn) and a trace of strontium (Sr), which are included in the cast iron, within a specific ratio.

Claims

1. A flake graphite cast iron comprising 3.0 to 3.2% of carbon (C), 2.0 to 2.3% of silicon (Si), 1.3 to 1.6% of manganese (Mn), 0.1 to 0.13% of sulfur (S), 0.06% or less of phosphorus (P), 0.6 to 0.8% of copper (Cu), 0.25 to 0.35% of molybdenum (Mo), 0.003 to 0.006% of strontium (Sr), and the balance iron (Fe) satisfying 100% as a total weight %, and having a chemical composition, in which a ratio (Mn/Sr) of the content of manganese (Mn) to the content of strontium (Sr) is in a range of 216 to 515.

2. The flake graphite cast iron of claim 1, wherein the flake graphite cast iron has a chemical composition, in which the ratio (Mn/Sr) of the content of manganese (Mn) to the content of strontium (Sr) is in a range of 299 to 451.

3. The flake graphite cast iron of claim 1, wherein the flake graphite cast iron has a tensile strength of 355 to 375 MPa.

4. The flake graphite cast iron of claim 1, wherein the flake graphite cast iron has a Brinell hardness (BHW) of 245 to 279.

5. The flake graphite cast iron of claim 1, wherein a wedge test specimen has a chill depth of 3 mm or less.

6. The flake graphite cast iron of claim 1, wherein a fluidity test specimen has a spiral length of 730 mm or more.

7. The flake graphite cast iron of claim 1, wherein the flake graphite cast iron has a carbon equivalent (CE) in a range of 3.70 to 4.0.

8. An engine body for an internal combustion engine, comprising an engine cylinder block, an engine cylinder head, or both, which are made of the flake graphite cast iron of claim 1.

9. The engine body of claim 8, wherein the engine cylinder block or the engine cylinder head comprises a thin walled part having a cross-sectional thickness in a range of 5 to 10 mm and a thick walled part having a cross-sectional thickness of more than 30 mm, and a graphite shape constituting the thin walled part is an A+D type.

10. The engine body of claim 8, wherein the engine body has an explosion pressure of more than 220 bar.

11. A method for manufacturing high-strength flake graphite cast iron of claim 1, the method comprising:

(i) manufacturing a cast iron melt including 3.0 to 3.2% of carbon (C), 2.1 to 2.3% of silicon (Si), 1.3 to 1.6% of manganese (Mn), 0.10 to 0.13% of sulfur (S), 0.06% or less of phosphorus (P), 0.6 to 0.8% of copper (Cu), 0.25 to 0.35% of molybdenum (Mo), and the balance iron (Fe) based on a total weight %;

(ii) adding strontium (Sr) to the melted cast iron melt, in which a ratio (Mn/Sr) of the content of manganese (Mn) to the content of strontium (Sr) is adjusted to be in a range of 216 to 515; and

(iii) tapping the cast iron melt into a ladle and injecting the cast iron melt into a prepared mold.

12. The method of claim 11, wherein an amount of strontium added is in a range of 0.003 to 0.006% based on the total weight % of the cast iron melt.

13. The method of claim 11, wherein the cast iron melt in step (i) is manufactured by adding 0.6 to 0.8% of copper (Cu) and 0.25 to 0.35% of molybdenum (Mo) to a cast iron melt manufactured by melting a cast iron material including 3.0 to 3.2% of carbon (C), 2.0 to 2.3% of silicon (Si), 1.3 to 1.6% of manganese (Mn), 0.10 to 0.13% of sulfur (S), 0.06% or less of phosphorus (P), and the balance iron (Fe) based on the total weight % in a furnace.

14. The method of claim 11, wherein an Fe—

Si-based inoculant is added one or more times in step (iii).

15. The method of claim 14, wherein the Fe—

Si-based inoculant is added when the cast iron melt is tapped into the ladle, when the cast iron melt is injected into the mold, or in both of the steps.