Polymer blends

• US 9,738,784 B2
• Filed: 10/11/2011
• Issued: 08/22/2017
• Est. Priority Date: 10/11/2010
• Status: Active Grant

• Current Assignee: Novomer, Inc (Danimer Scientific, Inc.)
• Original Assignee: Novomer, Inc (Danimer Scientific, Inc.)
• Inventors: Allen, Scott D., Naik, Sanjeev
• Primary Examiner(s): Khatri, Prashant J
• Application Number:
  US13/878,582
• Publication Number:
  US 20130209775A1
• Time in Patent Office: 2,142 Days
• CPC Class Codes: B29C 48/0018 combined with shaping by orienting, stretching or shrinking, e.g. film blowing B29C48/0017 takes precedence
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 23/04 Homopolymers or copolymers of ethene
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 67/04 Polyesters derived from hydroxycarboxylic acids, e.g. lactones C08L67/06 takes precedence
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

The present invention provides, among other things, extruded blends of aliphatic polycarbonates and polyolefins. In one aspect, provided blends comprise aliphatic polycarbonates such as poly(propylene carbonate) and a lesser amount of a crystalline or semicrystalline polymer. In certain embodiments, provided blends are characterized in that they exhibit unexpected improvements in their elongation properties. In another aspect, the invention provides methods of making such materials and applications of the materials in applications such as the manufacture of consumer packaging materials.

Claims

1. An extruded polymer blend comprising at least 70 weight percent aliphatic polycarbonate and at least one polyolefin, wherein:

the aliphatic polycarbonate comprises a blend of two or more aliphatic polycarbonates having a different average molecular weight and having greater than 90% carbonate linkages and less than 10% ether linkages;

the aliphatic polycarbonate is selected from the group consisting of poly(propylene carbonate), poly(ethylene carbonate), poly(propylene carbonate)-co-poly(ethylene carbonate), a poly(propylene carbonate) co-polymer with one or more additional aliphatic polycarbonates, a poly(ethylene carbonate) co-polymer with one or more additional aliphatic polycarbonates, a physical blend of any two or more of the above, and a copolymer comprising any of the above.

2. The extrude polymer blend of claim 1, wherein the aliphatic polycarbonate comprises a copolymer of carbon dioxide and one or more epoxides.

3. The extruded polymer blend of claim 1, comprising polypropylene carbonate).

4. The extruded polymer blend from claim 1, comprising poly(ethylene carbonate).

5. The extruded polymer blend of claim 1, wherein the polyolefin is selected from the group consisting of polyethylene, polypropylene, poly(alpha olefins), and mixtures or copolymers of any two or more of these.

6. The extruded polymer blend of claim 1, wherein the polyolefin is selected from the group consisting of LDPE, LLDPE, HDPE, polypropylene, or any combination of the above.

7. The extruded polymer blend of claim 1, wherein the polyolefin comprises polyethylene.

8. The extruded polymer blend of claim 1, wherein the polyolefin comprises polypropylene.

9. The extruded polymer blend of claim 1, further comprising at least one compatibilizer.

10. The extruded polymer blend of claim 1, comprising at least 80 weight percent aliphatic poly carbonate.

11. The extruded polymer blend of claim 1, comprising at least 85 weight percent aliphatic poly carbonate.

12. The extruded polymer blend of claim 1, comprising at least 90 weight percent aliphatic poly carbonate.

13. The extruded polymer blend of claim 1, comprising at least 95 weight percent aliphatic poly carbonate.

14. The extruded polymer blend of claim 10, wherein the polyolefin represents between about 5% and about 30% of the blend.

15. The extruded polymer blend of claim 10, wherein the polyolefin represents between about 10% and about 25% of the blend.

16. The extruded polymer blend of claim 1, wherein the blend has been extruded at a temperature above 160°

C.

17. The extruded polymer blend of claim 16, wherein the blend has been extruded at a temperature above 170°

C.

18. The extruded polymer blend of claim 16, wherein the blend has been extruded at a temperature above 180°

C.

19. The extruded polymer blend of claim 16, wherein the blend has been extruded at a temperature above 200°

C.

20. A plastic film comprising an extruded polymer blend of claim 1.

21. The plastic film of claim 20, wherein the film has been stretched and that the elongation before break value as measured using ASTM D882, prior to stretching is less than 50% and that the elongation before break value as measured using ASTM D882 after stretching is greater than 100%.