Red omnidirectional structural color made from metal and dielectric layers

• US 9,739,917 B2
• Filed: 12/23/2013
• Issued: 08/22/2017
• Est. Priority Date: 08/12/2007
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation), Toyota Motor Engineering & Manufacturing North America Incorporated (Toyota Motor Corporation)
• Inventors: Banerjee, Debasish, Zhang, Minjuan, Ishii, Masahiko, Zhou, Li Qin, Kato, Yumi
• Primary Examiner(s): Chang, Audrey Y
• Application Number:
  US14/138,499
• Publication Number:
  US 20140111861A1
• Time in Patent Office: 1,338 Days
• Field of Search: 359584, 359585, 359586, 359587, 359588, 359589, 359359, 428403, 283 91
• CPC Class Codes: G02B 5/085 at least one of the reflecting layers comprising metal
• CPC Class Codes: G02B 5/0858 the reflecting layers comprising a single metallic layer with one or more dielectric layers
• CPC Class Codes: G02B 5/285 comprising deposited thin solid films G02B5/281 - G02B5/289 take precedence; multilayered film filters for fibre optic multiplexing G02B6/29361
• CPC Class Codes: G02B 5/286 having four or fewer layers, e.g. for achieving a colour effect

Abstract

A multilayer stack displaying a red omnidirectional structural color. The multilayer stack includes a reflector layer, a dielectric layer extending across the reflector layer, and an absorbing layer extending across the dielectric layer. The dielectric layer reflects more than 70% of incident white light that has a wavelength greater than 580 nanometers (nm). In addition, the absorbing layer absorbs more than 70% of the incident white light with a wavelength less than 580 nm. In combination, the reflector layer, dielectric layer, and absorbing layer form an omnidirectional reflector that reflects a narrow band of electromagnetic radiation with a center wavelength between 580-680 nm, has a width of less than 200 nm wide and a color shift of less than 100 nm when the reflector is viewed from angles between 0 and 45 degrees.

Claims

1. A multilayer stack displaying a red omnidirectional structural color comprising:

a reflector layer;

a dielectric layer extending across said reflector layer, said reflector layer and said dielectric layer reflecting more than 70% of incident white light with wavelengths greater than 550 nm; and

a selective absorber layer extending across said dielectric layer, said selective absorber layer absorbing more than 70% of said incident white light with wavelengths less than 550 nm when the multilayer stack is viewed from angles between 0 and 45 degrees;

said reflector layer, dielectric layer and selective absorber layer forming an omnidirectional reflector, said omnidirectional reflector reflecting a single narrow band of visible electromagnetic radiation with a center wavelength between 550-700 nm, a width of less than 200 nm wide and a color shift of less than 60 nm when said omnidirectional reflector is viewed from angles between 0 and 45 degrees, the omnidirectional reflector displaying a red omnidirectional structural color.

2. The multilayer stack of claim 1, wherein said reflector layer has a thickness between 50-200 nm.

3. The multilayer stack of claim 2, wherein said dielectric layer has a thickness between 30-300 nm.

4. The multilayer stack of claim 3, wherein said selective absorber layer has a thickness between 20-80 nm.

5. The multilayer stack of claim 4, wherein said omnidirectional reflector has a total thickness less than 2 microns.

6. The multilayer stack of claim 4, wherein said total thickness is less than 1 micron.

7. The multilayer stack of claim 2, wherein said reflector layer contains a metal selected from the group consisting of Al, Ag, Pt, Cr, Cu, Zn, Au, Sn and alloys thereof.

8. The multilayer stack of claim 1, wherein said center wavelength has a hue shift of less than 30 degrees.

9. The multilayer stack of claim 1, wherein said dielectric layer has an optical thickness greater than 0.1 QW and less than 3.0 QW.

10. The multilayer stack of claim 9, wherein said optical thickness is less than 2.0 QW.

11. The multilayer stack of claim 1, wherein said dielectric layer has a refractive index greater than 1.6 and contains a dielectric material selected from the group consisting of ZnS, TiO2, HfO2, Nb2O5, Ta2O5 and combinations thereof.

12. The multilayer stack of claim 1, wherein said dielectric layer contains a colorful dielectric material selected from the group consisting of Fe2O3, Cu2O and combinations thereof.

13. The multilayer stack of claim 1, wherein said selective absorber layer contains a colorful metal selected from the group consisting of Cu, Au, Zn, Sn and alloys thereof.

14. The multilayer stack of claim 1, wherein said colorful absorber layer contains a colorful dielectric material selected from the group consisting of Fe2O3, Cu2O and combinations thereof.

15. The multilayer stack of claim 1, further comprising a second dielectric layer in addition to said previous mentioned dielectric layer, said second dielectric layer extending across said selective absorber layer and oppositely disposed said dielectric layer about said selective absorber layer;

said reflector layer, dielectric layer, selective absorber layer and second dielectric layer forming said omnidirectional reflector.

16. The multilayer stack of claim 15, wherein said second dielectric layer has a thickness between 30-300 nm.

17. The multilayer stack of claim 16, further comprising a second selective absorber layer in addition to said previously mentioned selective absorber layer, said second selective absorber layer extending across said second dielectric layer and oppositely disposed said selective absorber layer about said second dielectric layer;

said reflector layer, dielectric layer, selective absorber layer, second dielectric layer and second selective absorber layer forming said omnidirectional reflector.

18. The multilayer stack of claim 17, wherein said second selective absorber layer has a thickness between 10-80 nm.

19. The multilayer stack of claim 18, further comprising a third dielectric layer extending across said second absorber layer and oppositely disposed said second dielectric layer about said second selective absorber layer;

said reflector layer, dielectric layer, selective absorber layer, second dielectric layer, second selective absorber layer and third dielectric layer forming said omnidirectional reflector.

20. The multilayer stack of claim 19, wherein said third dielectric layer has a thickness between 10-300 nm.

21. The multilayer stack of claim 1, further comprising a second selective absorber layer in addition to said previously mentioned selective absorber layer, said second selective absorber layer extending between said reflector layer and said dielectric layer;

said reflector layer, dielectric layer, selective absorber layer and second selective absorber layer forming said omnidirectional reflector.

22. The multilayer stack of claim 21, further comprising a second dielectric layer in addition to said previously mentioned dielectric layer, said second dielectric layer extending across said selective absorber layer and oppositely disposed said dielectric layer about said selective absorber layer;

said reflector layer, dielectric layer, selective absorber layer, second selective absorber layer and second dielectric layer forming said omnidirectional reflector.

23. The multilayer stack of claim 22, wherein said omnidirectional reflector has a total thickness less than 2 microns.

24. The multilayer stack of claim 23, wherein said total thickness is less than 1 micron.

25. The multilayer stack of claim 1, wherein said narrow band of visible electromagnetic radiation is a reflection band with a UV-sided edge, said UV-sided edge shifting less than 75 nm when said omnidirectional reflector is viewed from angles between 0 and 45 degrees.

26. The multilayer stack of claim 25, wherein said UV-sided edge of said reflection band shifts less than 50 nm when said omnidirectional reflector is viewed from angles between 0 and 45 degrees.

27. The multilayer stack of claim 26, wherein said UV-sided edge of said reflection band shifts less than 25 nm when said omnidirectional reflector is viewed from angles between 0 and 45 degrees.

28. A paint pigment in the form of a multilayer stack, said paint pigment comprising:

a reflector layer;

a dielectric layer extending across said reflector layer, said reflector layer and said dielectric layer reflecting more than 70% of incident white light with wavelengths greater than 550 nm; and

a selective absorber layer extending across said dielectric layer, said selective absorber layer absorbing more than 70% of said incident white light with wavelengths less than 550 nm when the multilayer stack is viewed from angles between 0 and 45 degrees;

said reflector layer, dielectric layer and selective absorber layer forming an omnidirectional reflector, said omnidirectional reflector reflecting a single narrow band of visible electromagnetic radiation with a center wavelength between 550-700 nm, a width of less than 100 nm wide and a color shift of less than 60 nm when said omnidirectional reflector is viewed from angles between 0 and 45 degrees, the omnidirectional reflector displaying a red omnidirectional structural color.

29. A paint pigment in the form of a multilayer stack, said paint pigment comprising:

a reflector layer;

a dielectric layer extending across said reflector layer, said reflector layer and said dielectric layer reflecting more than 70% of incident white light with wavelengths greater than 550 nm; and

a selective absorber layer extending across said dielectric layer, said selective absorber layer absorbing more than 70% of said incident white light with wavelengths less than 550 nm when the multilayer stack is viewed from angles between 0 and 45 degrees;

said reflector layer, dielectric layer and selective absorber layer forming an omnidirectional reflector, said omnidirectional reflector reflecting a single narrow band of visible electromagnetic radiation with a UV-sided edge and an IR edge of the IR spectrum, said single narrow band of visible electromagnetic radiation having a width of less than 200 nm wide and a shift of said UV-sided edge of less than 75 nm when said omnidirectional reflector is viewed from angles between 0 and 45 degrees, the omnidirectional reflector displaying a red omnidirectional structural color.