Process for the enhanced corrosion protection of valve metals

• US 9,816,188 B2
• Filed: 03/30/2010
• Issued: 11/14/2017
• Est. Priority Date: 04/03/2009
• Status: Active Grant

• Current Assignee: Keronite International Ltd. (Curtiss-Wright Corporation)
• Original Assignee: Keronite International Ltd. (Curtiss-Wright Corporation)
• Inventors: Curran, James, Hutchins, Stephen, Shrestha, Suman
• Primary Examiner(s): Rufo, Louis
• Application Number:
  US13/262,779
• Publication Number:
  US 20120031765A1
• Time in Patent Office: 2,786 Days
• Field of Search: 205188-190
• CPC Class Codes: B05D 2202/20 based on light metals
• CPC Class Codes: B05D 2202/25 based on Al
• CPC Class Codes: B05D 2202/30 based on refractory metals (Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W)
• CPC Class Codes: B05D 3/142 Pretreatment
• CPC Class Codes: C23C 22/78 Pretreatment of the material to be coated
• CPC Class Codes: C23C 22/82 After-treatment
• CPC Class Codes: C25D 11/026 Anodisation with spark discharge
• CPC Class Codes: C25D 11/16 Pretreatment , e.g. desmutting
• CPC Class Codes: C25D 11/24 Chemical after-treatment
• CPC Class Codes: C25D 11/26 of refractory metals or alloys based thereon
• CPC Class Codes: C25D 11/30 of magnesium or alloys based thereon

Abstract

A process for the corrosion protection of metals such as magnesium, aluminium or titanium, where at least two steps are used, including both plasma electrolytic oxidation and chemical passivation. The combination of these two processing steps enhances the corrosion resistance performance of the surface beyond the capability of either of the steps in isolation, providing a more robust protection system. This process may be used as a corrosion protective coating in its own right, or as a protection-enhancing pre-treatment for top-coats such as powder coat or e-coat. When used without an additional top-coat, the treated parts can still retain electrical continuity with and adjoining metal parts. Advantages include reduced cost and higher productivity than traditional plasma-electrolytic oxidation systems, improved corrosion protection, greater coating robustness and electrical continuity.

Claims

1. A process comprising:

a plasma electrolytic oxidation step on a surface of a valve metal that comprises surface asperities;

a chemical passivation step performed on the surface of the valve metal, wherein the combination of the plasma electrolytic oxidation step and the chemical passivation step forms an electrically insulating coating on the surface of the valve metal; and

contacting the electrically insulating coating under high pressure with an adjoining metal component, wherein the electrically insulating coating is sufficiently thin that the surface asperities of the valve metal surface project through the electrically insulating coating to allow galvanic electrical continuity from the surface asperities to the adjoining metal component, and wherein the coating includes an oxide layer impregnated with a chemical passivating agent configured to provide active corrosion protection of the valve metal in an event of physical breach of the oxide layer.

2. A process according to claim 1, wherein the chemical passivation step precedes the plasma electrolytic oxidation step.

3. A process according to claim 1, wherein the plasma-electrolytic oxidation step precedes the chemical passivation step.

4. A process according to claim 1, wherein chemical passivation steps are performed both prior to and after the plasma-electrolytic oxidation step.

5. A process according to claim 3, wherein the plasma-electrolytic oxidation step generates an oxide coating having pores, and wherein the subsequent chemical passivation step does not physically seal the pores of the oxide coating.

6. A process according to claim 1, wherein the chemical passivation step comprises application of a liquid, the liquid not being in the form of a sol gel.

7. A process according to claim 1, wherein some or all of the surface of the valve metal is treated with the plasma-electrolytic oxidation step.

8. A process according to claim 1, wherein some or all of the surface of the valve metal is treated with the chemical passivation step.

9. A process according to claim 1, further comprising a pre-treatment regime of at least one of degreasing, etching or de-smutting to clean the surface of the valve metal prior to the plasma electrolytic oxidation and chemical passivation steps.

10. A process according to claim 1, further comprising a post-treatment regime consisting of at least one of rinses in water, pH-neutralising rinses, primer or sealer solutions.

11. A process according to claim 1, wherein the valve metal comprises at least one of magnesium, aluminium, titanium, tantalum, zirconium, chromium, vanadium, cobalt, hafnium, or molybdenum.